Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

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41397 Publications

Development of a F-18-labeled Diaryl-Substituted Dihydropyrrolo[3,2,1-hi]indole as Potential Probe for Functional Imaging of Cyclooxygenase-2 with PET

Gassner, C.; Neuber, C.; Laube, M.; Bergmann, R.; Kniess, T.; Pietzsch, J.

High COX-2 expression is associated with tumor progression and poor treatment response. Imaging of functional COX-2 expression by PET would provide beneficial information for theranostics. Here we describe precursor synthesis and radiolabeling attempts of (dihydro)pyrrolo[3,2,1-hi]indoles [18F]DHPI and [18F]PI, two novel tricyclic COX-2 inhibitors. Contrary to [18F]PI, [18F]DHPI was accessible by [18F]fluorination under mild basic conditions and McMurry cyclization. Radiopharmacological evaluation was performed in vitro by investigating cellular uptake in human COX-2-positive cells, and in vivo in rats and A2058-melanoma xenograft mice, by focusing on metabolic stability and tumor uptake. To assess COX-2 specificity, blocking experiments with celecoxib were performed. Despite of high COX-2 selectivity and metabolic stability, [18F]DHPI did not show COX-2-dependent cell and tissue uptake, in part explained by high unspecific binding. Since appropriate lipophilicity is a prerequisite for targeting intracellularly localized COX-2, future efforts should focus on use of longer-lived radionuclides and/or targeted delivery systems.

Keywords: Cancer; Malignant melanoma; Molecular imaging; Radiochemistry; Selective cyclooxygenase-2 inhibitors; Tumor xenograft models

Permalink: https://www.hzdr.de/publications/Publ-24085
Publ.-Id: 24085


A Guide on Spectral Methods Applied to Discrete Data in One Dimension

Seilmayer, M.; Ratajczak, M.

Spectral analysis in conjunction with discrete data in one and more dimensions can become a challenging task, because the methods are sometimes difficult to understand. This paper intends to provide an overview about the usage of the Fourier transform, its related methods and focuses on the subtleties to which the users must pay attention. Typical questions, which are often addressed to the data, will be discussed. Such a problem can be the issue of frequency or band limitation of the signal. Or the source of artifacts might be of interest, when a Fourier transform is carried out. Another topic is the issue with fragmented data. Here, the Lomb-Scargle method will be explained with an illustrative example to deal with this special type of signal. Furthermore, a challenge encountered very often is the time-dependent spectral analysis, with which one can evaluate the point in time when a certain frequency appears in the signal. The information to solve such problems and to answer this questions is spread over many disciplines ranging from mathematics, electrical engineering, economic science to astrophysics. The goal of the first part of this paper is to collect the important information about the common methods to give the reader a guide on how to use these for application on one-dimensional data. The second part of this paper will then address the two- and more-dimensional data. The introduced methods are supported by the 'spectral' package, which has been published for the statistical environment R prior this article.

Keywords: spectral analysis; Fourier transform; Hilbert transform; R; spectral

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Permalink: https://www.hzdr.de/publications/Publ-24083
Publ.-Id: 24083


Common methods of spectral data analysis

Seilmayer, M.

Fourier and Hilbert transforms are utilized to perform several types of spectral analysis on the supplied data. Also gapped and irregularly spaced data can be processed. A user friendly interface helps to interpret the results.

Keywords: spectral analysis; Fourier transform; Hilbert transform; R

  • Software in external data repository
    Publication year 2016
    Programming language: R
    System requirements: Windows, Linux, MacOS, R (>= 2.15.0)
    License: GPL-2 (Link to license text)
    Hosted on CRAN: Link to location

Permalink: https://www.hzdr.de/publications/Publ-24082
Publ.-Id: 24082


rasterImage

Seilmayer, M.

This is a wrapper function for image(), which makes reasonable raster plots with nice axis and other useful features.

Keywords: plot function; R

  • Software in external data repository
    Publication year 2016
    Programming language: R
    System requirements: Windows, Linux, MacOS, R (>= 2.15.0)
    License: GPL-2 (Link to license text)
    Hosted on CRAN: Link to location

Permalink: https://www.hzdr.de/publications/Publ-24081
Publ.-Id: 24081


Progress of the Felsenkeller shallow-underground accelerator for nuclear astrophysics

Bemmerer, D.; Cavanna, F.; Cowan, T. E.; Grieger, M.; Hensel, T.; Junghans, A. R.; Ludwig, F.; Müller, S. E.; Rimarzig, B.; Reinicke, S.; Schulz, S.; Schwengner, R.; Stöckel, K.; Szücs, T.; Takács, M. P.; Wagner, A.; Wagner, L.; Zuber, K.

Low-background experiments with stable ion beams are an important tool in order to put the understanding of stellar hydrogen, helium, and carbon burning on a solid experimental foundation. The pioneering work in this regard has been done by the LUNA collaboration at Gran Sasso, using a 0.4 MV accelerator. In the present contribution, the status of the project for a higher-energy underground accelerator is reviewed. Two tunnels of the Felsenkeller underground site in Dresden, Germany, are currently being refurbished for the installation of a 5 MV high-current Pelletron accelerator. Construction work is on schedule and expected to complete in August 2017. The accelerator will provide intense, 50μA, beams of 1H+, 4He+, and 12C+ ions, enabling research on astrophysically relevant nuclear reactions with unprecedented sensitivity.

Keywords: Felsenkeller; underground nuclear astrophysics

  • Open Access Logo Contribution to proceedings
    Nuclei in the Cosmos XVI, 20.-24.06.2016, Niigata, Japan
    Proceedings of the 14th International Symposium on Nuclei in the Cosmos (NIC2016) JPS Conf. Proc. 14, 021106 (2017), 021106
    DOI: 10.7566/JPSCP.14.021106
  • Contribution to WWW
    arXiv Preprint-Server: http://arxiv.org/pdf/1609.05819v1.pdf

Permalink: https://www.hzdr.de/publications/Publ-24079
Publ.-Id: 24079


The surface reactions of U(VI) on γ-Al2O3 In situ spectroscopic evaluation of the transition from sorption complexation to surface precipitation

Müller, K.; Foerstendorf, H.; Rossberg, A.

Aluminates, representing an essential component of clay minerals, play a decisive role in regulating the mobility of contaminants in rock and soil formations, in particu-lar due to their tendency to form coatings on mineral surfaces [1].
In this work, U(VI) sorption on γ-Al2O3 is comparatively investigated using in situ vibrational and X-ray absorption spectroscopy. The focus was set to micromolar U(VI) concentrations and a variety of environmentally relevant sorption parameters in order to resolve discrepancies reported earlier [2-4].
Time-resolved (TR) IR spectroscopic sorption experiments at the alumina-water in-terface evidence the formation of three different species as a function of surface loading (c.f. Fig.): a monomeric carbonate complex, an oligomeric surface complex and a surface precipitate. These results are confirmed by IR experiments performed at different flow rates, pH values, ionic strengths, U(VI) concentrations, and in inert gas atmosphere. Results of EXAFS experiments of batch samples are consistent to these findings [5].

Related publications

  • Poster
    3rd International Workshop on Advanced Techniques in Actinide Spectroscopy, 07.-10.11.2016, Richland, USA

Permalink: https://www.hzdr.de/publications/Publ-24078
Publ.-Id: 24078


High resolution x-ray Thomson scattering measurements from cryogenic hydrogen jets using the linac coherent light source

Fletcher, L. B.; Zastrau, U. B.; Galtier, E. A.; Gamboa, E. J. A.; Goede, S. A.; Schumaker, W. A.; Ravasio, A. A.; Gauthier, M. A.; Macdonald, M. J. A.; Chen, Z. A.; Granados, E. A.; Lee, H. J. A.; Fry, A. A.; Kim, J. B. A.; Roedel, C. A.; Mishra, R. A.; Pelka, A. F.; Kraus, D.; Barbrel, B. G.; Döppner, T. H.; Glenzer, S. H. A.

We present the first spectrally resolved measurements of x-rays scattered from cryogenic hydrogenjets in the single photon counting limit. The 120 Hz capabilities of the LCLS, together with a novelhydrogen jet design [J. B. Kimet al., Rev. Sci. Instrum. (these proceedings)], allow for the ability torecord a near background free spectrum. Such high-dynamic-range x-ray scattering measurementsenable a platform to study ultra-fast, laser-driven, heating dynamics of hydrogen plasmas. Thismeasurement has been achieved using two highly annealed pyrolytic graphite crystal spectrometers tospectrally resolve 5.5 keV x-rays elastically and inelastically scattered from cryogenic hydrogen andfocused on Cornell-SLAC pixel array detectors [S. Herrmannet al., Nucl. Instrum. Methods Phys.Res., Sect. A718, 550 (2013)].

Permalink: https://www.hzdr.de/publications/Publ-24077
Publ.-Id: 24077


Phase Shift and Reflection of Spin Waves at Magnetic Domain Walls in Thin Films

Körber, L.; Wagner, K.; Lindner, J.; Fassbender, J.; Schultheiß, H.

Investigating the transmission of magneto-static surface waves through 180° Néel walls using micromagnetic simulations.

Keywords: spin waves; phase shift; micromagnetic simulation; reflection; domain wall

  • Poster
    Spin, Waves and Interactions, 31.08.-02.09.2016, Greifswald, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24076
Publ.-Id: 24076


Magnetic domain walls as reconfigurable spin-wave nano-channels

Wagner, K.; Kakay, A.; Schultheiß, K.; Henschke, A.; Sebastian, T.; Lindner, J.; Fassbender, J.; Schultheiß, H.

Use of magnetic domains as nano channels for spin wave propagation

Related publications

  • Lecture (Conference)
    Spin, Waves and Interaction, 31.08.-02.09.2016, Greifswald, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24075
Publ.-Id: 24075


Modern Measurement Methods of Brillouin Light Scattering

Osten, J.; Schultheiß, H.; Wagner, K.; Körber, L.; Wehrmann, F.; Hula, T.

Explanation of different measurement methods of BLS: phase, time, wavevector, frequency and spacial resolved

Keywords: BLS

  • Poster
    Spins, Waves and Interactions, 31.08.-02.09.2016, Greifswald, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24074
Publ.-Id: 24074


The role of automated mineralogy in geometallurgy: two case studies

Birtel, S.; Kern, M.; Heinig, T.; Gutzmer, J.

SEM-based automated mineralogy is well established as a key tool in geometallurgical assessments, as it provides quantitative data on mineralogy and microstructure. It is widely used to improve the recovery of those constituents (ore minerals) that contain the major products (metals) of existing or planned mining operations and processing plants. Less common, however, is the use of automated mineralogy to study the presence and distribution of possible by-product or even penalty constituents. In this contribution, we present the results of two case studies that reveal the benefit of application of automated mineralogy to define beneficiation potential for economically significant by-products in large operations. Systematic plant surveys were carried out at one fluorite mine and one porphyry copper deposit. For the fluorite deposit, the plant survey was combined with an assessment of the undisturbed feed material.
Case study 1: For the recovery of REE as a potential by-product in a fluorite mine, blocks were sampled before mining, the material was subsequently followed through the flotation plant, sampling all crucial steps. Samples illustrate that the material from the tailings stream, i.e., the material being considered as waste, is strongly enriched in the two dominant REE-bearing minerals contained in the ore: monazite and xenotime. These REE-bearing minerals are well liberated, thus leading to the conclusion that it may be feasible to produce a REE concentrate as a by-product by only slight modification of the current flow sheet.
Case study 2 focused on the improvement of Mo recovery of a world-class porphyry copper deposit. Samples were taken systematically from the flotation plant also considering residence times. Particular flotation stages accounting for significant Mo losses due to bad molybenite liberation were identified. Lab-scale flotation tests were carried out to improve Mo recovery. Results indicate a clear influence of grain shape, grain size and residence time on the recovery.

Keywords: automated mineralogy; by products; REE; process optimization

  • Contribution to proceedings
    3rd international Seminar on geometallurgy, Editors: Regina Baumgartner, Adam Johnston, 11.-13.12.2016, Lima, Peru
    GEOMET 2016, 3rd International Seminar on Geometallurgy, Santiago, Chile: Gecamin, 978-956-9393-68-6, 58-59
  • Lecture (Conference)
    3rd international Seminar on Geometallurgy, 11.-13.12.2016, Lima, Peru

Permalink: https://www.hzdr.de/publications/Publ-24073
Publ.-Id: 24073


An Electrochemical and Photoelectron Spectroscopy Study of a Low Temperature Liquid Metal Battery Based on an Ionic Liquid Electrolyte

Lalau, C.-C.; Dimitrova, A.; Himmerlich, M.; Ispas, A.; Weier, T.; Krischok, S.; Bund, A.

We report the design of a low-temperature liquid metal battery (LMB). Li and Ga as the negative and positive electrode, respectively, are used in combination with a room temperature ionic liquid as an electrolyte. 1 mol/L lithium bis(trifluoromethylsulfonyl)imide (Li[TFSI]) in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl)imide ([BMP][TFSI]) is chosen as electrolyte. The battery operates at 220 °C which is a relatively low temperature for a LMB and shows good electrochemical performance at low current density. The cells were cycled for more than 600 h and achieved a round-trip Coulombic efficiency close to 100% and an average voltage efficiency of 66% resulting in an overall energy efficiency of 65%. At higher current densities, however, the system showed up to 75% irreversible capacity loss after three cycles. To understand the origin of this strong deterioration, we characterized the surface and the bulk properties of the Ga cathode using X-ray Photoelectron Spectroscopy. Especially at higher current densities a decomposition of the electrolyte was found. The chemical changes that occurred and the elemental distribution at the Ga cathode are analyzed based on XPS measurements at different stages of the battery charge/discharge cycling.

Keywords: liquid metal battery; ionic liquids

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Permalink: https://www.hzdr.de/publications/Publ-24072
Publ.-Id: 24072


Depth profiled ion implantation doping using an energy filter based on Si membrane

Akhmadaliev, S.; Krippendorf, F.; Bezerra, E. B. D.; von Borany, J.; Csato, C.; Rüb, M.; Zowalla, A.

An important step during fabrication of modern semiconductor devices is doping of the material by means of ion implantation. For some applications in power or optoelectronics also special non-Gaussian shaped buried implantation profiles are required. The conventional way to create accurate shaped doping profiles by using multiple implantations of mono-energetic ions with subsequent thermal annealing is quite time consuming. An alternative approach is the application of an ion beam exhibiting the desired energy and flux distribution. For applications of less accuracy metallic foils with various thicknesses have been applied as energy filters (EF). A relatively new method is a filter made of micro-mechanically manufactured silicon membranes with modulated thickness which changes the energy of the initially mono-energetic ion beam from an accelerator and converts quasi-Gaussian shaped implantation profile into the specified one [1]. An example of such an EF shown in Fig.1 which can be used for homogeneous buried box-like doping profiles covering a doping depth of several micrometers. The ions with equal energies Eo will have different energies after the filter depending on the local thickness of the material and the resulting ion ranges are in different depth in the substrate.
There are some challenges by using this technique. Besides the reliable and reproducible fabrication of the energy filter, aspects like thermal stability, ion beam sputtering or geometrical constrains have to be considered. Another difficulty of this method is the monitoring of the ion flux after the EF in order to control the implanted dose. A Faraday cup setup cannot be directly applied because of the recharging of the ions by the EF and their undefined charge state after the filter, so the process needs precise calibration for each ion type and energy. A Si EF fabricated at Ernst-Abbe Hochschule was calibrated and taken for the doping of 4” wafers using the wafer-handler with the mechanical scanning system at 3 MV tandem accelerator at HZDR [2]. The experiments deliver promising results and demonstrate the possibility of application this method for doping purposes.
References
[1] M. Rüb, DE Patent App, 2012, DE102011075350 A1
[2] C. Csato et al., Nucl. Instr. Meth. B 365 (2015) 182

Keywords: SiC; energy filter; ion implantation

Related publications

  • Lecture (Conference)
    ECAART-12, The 12th European Conference on Accelerator in Applied Research and Technology, 03.-08.07.2016, Jyväskylä, Finnland

Permalink: https://www.hzdr.de/publications/Publ-24071
Publ.-Id: 24071


Kommissionierung von Bestrahlungsplanungsalgorithmen und -systemen mittels eines Systemtestphantoms

Geyer, P.; Schellhammer, S.; Feiks, S.; Debbih, Y. D.

Fragestellungen: Die Empfehlungen der Strahlenschutzkommission „Physikalisch-technische Qualitätssicherung in der Strahlentherapie – Vorschläge zur Prüfung des gesamten Behandlungssystems“ aus dem Jahr 2010 fanden inzwischen ihren Eingang in die novellierten Fassungen der Strahlenschutzverordnung und der Richtlinie Strahlenschutz in der Medizin. Allerdings gibt es bisher eine Vorgaben zum Umfang zu prüfender Parameter, deren Toleranzen und für entsprechende Phantome. Ein solches Phantom für den Test des Gesamtsystems sollte auch für Teilaufgaben im Rahmen der Kommissionierung von Bestrahlungsplanungssystemen geeignet sein.

Material und Methoden: Das in der Klinik entwickelte und gefertigte Phantom ist modular aufgebaut (Abb. 1). Ein PMMA-Grundkörper enthält Strukturen für geometrische Messungen und beinhaltet vier quaderförmige Inhomogenitäten (Lungenmaterial Gammex 455, RW-3, Wasser und PMMA) mit jeweils dem Querschnitt 5 x 5 cm2. Mittels Bohrungen können Dosismessungen im Grundkörper und den Inhomogenitäten erfolgen. Das Phantom wurde mit einem CT-Thoraxprotokoll (130 kV, 90 eff. mAs) am Somatom Emotion (Siemens) mit 3 mm Schichtdicke untersucht. Die Bestrahlungsplanung erfolgte einmal im OTP Masterplan (Version 4.3.0.410, Elekta) mit dem bereits früher implementierten Collapsed-Cone-Algorithmus (Dichtematrix 1x1x1 mm3, Dosismatrix 1x2x1 mm3). Parallel wurde im Rahmen der Kommissionierung des Monte-Carlo-Algorithmus im IPlan RTDose (Version 4.1.4, BrainLab) geplant (Varianz 1 %, dose to water, accuracy optimiert, 2,4x2,4x2,0 mm3 Ortsauflösung). Berechnet wurden rechteckige Felder von anterior der Abmessungen 2x30 cm2, 4x30 cm2 und 5x30 cm2 für jeweils X6 und X15 des Oncor-160 (Siemens), die sich über alle Inhomogenitäten erstrecken. Die Messungen erfolgten mit den Ionisationskammern Semiflex 31006 (0,3 cm3) und PinPoint 31003 (0,015 cm3, beide PTW). Die Ankopplung der PinPoint an die Semiflex, sowie erforderliche Korrekturen erfolgten gemäß den DIN 6809-8 (Entwurf 03/2014) und 6800-2 (2008). Verglichen werden die in den zwei Planungssystemen berechneten Dosiswerte mit den gemessenen Dosen in den Inhomogenitäten und im PMMA-Grundkörper (Isozentrumsmesspunkt), wobei die Feldbreiten 4 und 5 cm mit der Semiflex und die 2-cm-breiten Felder mit der PinPoint gemessen wurden. Die PinPoint-Messungen im Lungeneinsatz wurden bezüglich des abweichenden Materials des Differenzvolumens zur Semiflex korrigiert.
Hier nicht dargestellt werden die Ergebnisse für eine Vielzahl anderer Felder und Berechnungen von Dosis-Volumen-Histogrammen
für die konturierten inhomogenen Einsätze.

Ergebnisse: Für Messpunkte in der Isozentrumsebene (alle in Abb.2 oder 3 nicht mit fokusnah oder fokusfern bezeichneten Punkte) weichen alle gemessenen und berechneten Dosiswerte maximal um 1 % voneinander ab, eine Ausnahme bildet das Lungenmaterial, wo feldgrößen-, energieabhängig und abhängig vom Planungssystem bis zu 5 % Abweichungen gefunden wurden (Abb. 2, 3). Vor allem für einen fokusfernen Messpunkt im RW-3 wird für das schmalste Feld die Dosis von beiden Planungssystemen um bis zu 4 % überschätzt. Ursachen hierfür können Artefakte durch Metallmarker im Phantom sein. Die gefundenen Dosisabweichungen in der Isozentrumsebene (außer für Lunge) liegen innerhalb des Messunsicherheitsbudgets von ≤ 2 %.
Für die (nahezu) Punktdosismessungen zeigte sich kein Genauigkeitsvorteil für einen der zwei Rechenalgorithmen bzw. eines der Planungssysteme.

Zusammenfassung: Das verwendete Phantom ermöglicht die Bestimmung von Datensätzen, die parallel für die Kommissionierung von Planungssystemen und den Systemtest verwendet werden können. Dabei sind auch Bewertungen in Grenzbereichen des Anwendungsspektrums, hier z. B. zur Applikation kleiner Felder in Inhomogenitäten möglich. Die gefundenen Abweichungen bilden die Grundlage für die Toleranzbereiche in unserem Systemtest.

  • Lecture (Conference)
    47. Jahrestagung der Deutschen Gesellschaft für Medizinische Physik (DGMP) e. V., 07.-10.09.2016, Würzburg, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24070
Publ.-Id: 24070


Resistive switching behavior in single crystal SrTiO3 annealed by laser

Pan, X.; Shuai, Y.; Wu, C.; Luo, W.; Sun, X.; Yuan, Y.; Zhou, S.; Ou, X.; Zhang, W.

Single crystal SrTiO3 (STO) wafers were annealed by XeCl laser (λ = 308 nm) with different fluences of 0.4 J/cm2, 0.6 J/cm2 and 0.8 J/cm2, respectively. Ti/Pt electrodes were sputtered on the surface of STO wafer to form co-planar capacitor-like structures of Pt/Ti/STO/Ti/Pt. Current-Voltage measurements show that the leakage current is enhanced by increasing laser fluence. Resistive switching behavior is only observed in the sample annealed by laser with relatively high fluence after an electro-forming process. The X-ray photoelectron spectroscopy measurements indicate that the amount of oxygen vacancies increases with the increase of laser fluence. This work indicates resistive switching appears when enough oxygen vacancies are generated by the laser, which form conductive filaments under an external electric field.

Keywords: Resistive switching; Laser annealing; SrTiO3

Related publications

Permalink: https://www.hzdr.de/publications/Publ-24069
Publ.-Id: 24069


Probing chemical bonding in uranium dioxide by means of high-resolution x-ray absorption spectroscopy

Butorin, S.; Modin, A.; Vegelius, J.; Kvashnina, K.; Shuh, D.

A systematic x-ray absorption study at the U 3d, 4d and 4f edges of UO2 was performed and the data were analyzed within framework of the Anderson impurity model. By applying the highenergy-resolution uorescence-detection (HERFD) mode of x-ray absorption spectroscopy (XAS) at the U 3d3/2 edge and by doing the XAS measurements at the shallower U 4f levels, fine details of the XAS spectra were resolved due to reduced core-hole lifetime broadening. These allowed for more efficient analysis of the electronic structure at the U sites and characterization of the chemical bonding and degree of the 5f localization in UO2. The results support the covalent character of UO2 and refute the claims about rather ionic bonding in this compound, made in some publications.

Permalink: https://www.hzdr.de/publications/Publ-24068
Publ.-Id: 24068


Direct measurement of low-energy 22Ne(p,γ)23Na resonances

Depalo, R.; Cavanna, F.; Aliotta, M.; Anders, M.; Bemmerer, D.; Best, A.; Boeltzig, A.; Broggini, C.; Bruno, C. G.; Caciolli, A.; Ciani, G. F.; Corvisiero, P.; Davinson, T.; Di Leva, A.; Elekes, Z.; Ferraro, F.; Formicola, A.; Fülöp, Z.; Gervino, G.; Guglielmetti, A.; Gustavino, C.; Gyürky, G.; Imbriani, G.; Junker, M.; Menegazzo, R.; Mossa, V.; Pantaleo, F. R.; Piatti, D.; Prati, P.; Straniero, O.; Strieder, F.; Szücs, T.; Takács, M. P.; Trezzi, D.

Background: The 22Ne(p,γ)23Na reaction is the most uncertain process in the neon-sodium cycle of hydrogen burning. At temperatures relevant for nucleosynthesis in asymptotic giant branch stars and classical novae, its uncertainty is mainly due to a large number of predicted but hitherto unobserved resonances at low energy.
Purpose: A new direct study of low energy 22Ne(p,γ)23Na resonances has been performed at the Laboratory for Underground Nuclear Astrophysics (LUNA), in the Gran Sasso National Laboratory, Italy.
Method: The proton capture on 22Ne was investigated in direct kinematics, delivering an intense proton beam to a 22Ne gas target. γ rays were detected with two high-purity germanium detectors enclosed in a copper and lead shielding suppressing environmental radioactivity.
Results: Three resonances at 156.2 keV (ωγ = (1.48 ± 0.10) · 10−7 eV), 189.5 keV (ωγ = (1.87±0.06)·10−6 eV) and 259.7 keV (ωγ = (6.89±0.16)·10−6 eV) proton beam energy, respec- tively, have been observed for the first time. For the levels at Ex = 8943.5, 8975.3, and 9042.4 keV excitation energy corresponding to the new resonances, the γ-decay branching ratios have been precisely measured. Three additional, tentative resonances at 71, 105 and 215 keV proton beam energy, respectively, were not observed here. For the strengths of these resonances, experimental upper limits have been derived that are significantly more stringent than the upper limits reported in the literature.
Conclusions: Based on the present experimental data and also previous literature data, an updated thermonuclear reaction rate is provided in tabular and parametric form. The new reaction rate is significantly higher than previous evaluations at temperatures of 0.08-0.3 GK.

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Permalink: https://www.hzdr.de/publications/Publ-24067
Publ.-Id: 24067


Origin of stardust unveiled by the new LUNA rate of the 17O(p,α)14N reaction

Lugaro, M.; Karakas, A. I.; Bruno, C. G.; Aliotta, M.; Nittler, L. R.; Bemmerer, D.; Best, A.; Boeltzig, A.; Broggini, C.; Caciolli, A.; Cavanna, F.; Ciani, G. F.; Corvisiero, P.; Davinson, T.; Depalo, R.; Di Leva, A.; Elekes, Z.; Ferraro, F.; Formicola, A.; Fülöp, Z.; Gervino, G.; Guglielmetti, A.; Gyürky, C. G. G.; Imbriani, G.; Junker, M.; Menegazzo, R.; Mossa, V.; Pantaleo, F. R.; Piatti, D.; Prati, P.; Scott, D. A.; Straniero, O.; Strieder, F.; Szücs, T.; Takács, M. P.; Trezzi, D.

Stardust grains recovered from meteorites provide high-precision snapshots of the isotopic compositions resulting from nuclear reactions in the stars in which they formed. Establishing their stellar sites of origin, however, often proves difficult. One long-standing problem is that a large fraction of meteoritic stardust is predicted to have originated from the late evolutionary phase of stars with initial mass between roughly 4 and 8 solar masses, however, no grains have been found with an isotopic composition that matches that expected in these stars. This problem points to serious gaps in our understanding of the lifecycle of stars and dust in the Galaxy. Here we show that the new, increased rate of the 17O + p → 14N + α nuclear reaction, based on a recent underground experiment, produces 17O/16O isotopic ratios that match those observed in a population of stardust grains, provided that the burning occurs at relatively high temperatures (60–80 million K). These are the temperatures achieved at the base of the convective envelope during the late evolutionary phase of 4 to 8 solar mass stars, which reveals them as the site of origin of the grains. This result provides the first direct evidence that these stars contributed to the dust inventory from which the Solar System formed.

Related publications

Permalink: https://www.hzdr.de/publications/Publ-24066
Publ.-Id: 24066


Scalable, multi-GPU photon tracing for the interaction of X-Rays with solid density plasmas

Grund, A.; Huebl, A.; Kluge, T.; Widera, R.; Fortmann-Grote, C.; Bussmann, M.

We present the scientific workflow using our performance portable, open source, 3D3V particle-in-cell (PIC) code PIConGPU and its X-Ray tracing prototype ParaTAXIS to model the interaction of XFEL type X-Rays with solid density plasmas. With an open and modern software environment, our infrastructure is already suited for the largest available supercomputers today and key numerical and methodical challenges have been solved towards first simulations of upcoming pump-probe experiments at the European XFEL.

Keywords: EUCALL; SIMEX; XFEL; GPU; photon beamline; ParaTAXIS; PIConGPU; x-ray scattering

  • Poster
    EUCALL Annual Meeting 2016, 31.08.-02.09.2016, Dresden, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24065
Publ.-Id: 24065


Plasmas, Photons, Open Standards: PIConGPU meets simex_platform through openPMD

Huebl, A.; Kluge, T.; Grund, A.; Fortmann-Grote, C.; Widera, R.; Bussmann, M.

Technische Aspekte des Datenaustauschs SIMEX XFEL Wavefronts -> XRT/PIConGPU via openPMD, die wir zusammen erstellt haben und aktueller Stand der Photon-Plasma Streuung der dann anschließenden HPC Simulation auf unserer Seite.

Topics:

- SIMEX Platform: Short intro functional parts, PIConGPU = interaction
- SIMEX Platform: Wavefronts to Photon Picture
- openPMD: why, what, how
- status XRT (PIConGPU photon scattering code prototype)
- typical HPC size of a PIConGPU simulation for dense targets
- continuous integration (simex platform & PIConGPU)
- maybe some future ideas such as successful docker-ization of
PIConGPU for our "relatively fixed" beamline

Keywords: PIConGPU; GPU; EUCALL; SIMEX; openPMD; XFEL

  • Lecture (Conference)
    EUCALL Annual Meeting, 31.08.-02.09.2016, Dresden, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24064
Publ.-Id: 24064


Induced conductivity in sol-gel ZnO films by passivation or elimination of Zn vacancies

Winarski, D. J.; Anwand, W.; Wagner, A.; Saadatkia, P.; Selim, F. A.; Allen, M.; Wenner, B.; Leedy, K.; Allen, J.; Tetlak, S.; Look, D. C.

Undoped and Ga- and Al- doped ZnO films were synthesized using sol-gel and spin coating methods and characterized by X-ray diffraction, high-resolution scanning electron microscopy (SEM), optical spectroscopy and Hall-effect measurements. SEM measurements reveal an average grain size of 20 nm and distinct individual layer structure. Measurable conductivity was not detected in the unprocessed films; however, annealing in hydrogen or zinc environment induced significant conductivity (~10^-2 Ohm cm) in most films. Positron annihilation spectroscopy measurements provided strong evidence that the significant enhancement in conductivity was due to hydrogen passivation of Zn vacancy related defects or elimination of Zn vacancies by Zn interstitials which suppress their role as deep acceptors. Hydrogen passivation of cation vacancies is shown to play an important role in tuning the electrical conductivity of ZnO, similar to its role in passivation of defects at the Si/SiO2 interface that has been essential for the successful development of complementary metal–oxide–semiconductor (CMOS) devices. By comparison with hydrogen effect on other oxides, we suggest that hydrogen may play a universal role in oxides passivating cation vacancies and modifying their electronic properties.

Keywords: ZnO conductivity sol-gel hydrogen passivation defects positron annihilation

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Permalink: https://www.hzdr.de/publications/Publ-24063
Publ.-Id: 24063


Magnetic functionalities for flexible interactive electronics

Makarov, D.

The flourishing and eagerness of portable consumer electronics necessitates functional elements to be lightweight, flexible, and even wearable [1,2]. Next generation flexible appliances aim to become fully autonomous and will require ultra-thin and flexible navigation modules, body tracking and relative position monitoring systems. Such devices fulfill the needs of soft robotics [3], functional medical implants [4] as well as epidermal [5], imperceptible [6] and transient [7] electronics. Key building blocks of navigation and position tracking devices are the magnetic field sensors.
We developed the technology platform allowing us to fabricate high-performance shapeable, namely, flexible [8-10], printable [11-13], stretchable [14-16] and even imperceptible [17] magnetic sensorics. The technology relies on smart combination of thin inorganic functional elements prepared directly on flexible or elastomeric supports. The unique mechanical properties open up new application potentials for smart skins, allowing to equip the recipient with a “sixth sense” providing new experiences in sensing and manipulating the objects of the surrounding us physical as well as digital world [10,17].
Combining large-area printable and flexible electronics paves the way towards commercializing the active intelligent packaging, post cards, books or promotional materials that communicate with the environment and provide the respond to the customer. Realization of this vision requires fabrication of printable electronic components that are flexible and can change their properties in the field of a permanent magnet [12]. For this concept, we fabricated high performance magnetic field sensors relying on the giant magnetoresistive (GMR) effect, which are printed at pre-defined locations on flexible circuitry and remain fully operational over a temperature range from -10°C up to +95°C, well beyond the requirements for consumer electronics [13]. Our work potentially enables commercial use of high performance magneto-sensitive elements in conventional printable electronic industry, which, although highly demanded, had not yet been possible.
In this talk, I will review the recent advances in the field of shapeable magnetic sensorics and emergent applications of this novel technology.

Keywords: flexible electronics; magnetic field sensorics

Related publications

  • Invited lecture (Conferences)
    Special seminar, Institute of Physics, Johannes Gutenberg-Universität Mainz, 29.08.2016, Mainz, Germany

Permalink: https://www.hzdr.de/publications/Publ-24062
Publ.-Id: 24062


Evidence of trivalent Am substitution into U3O8

Caisso, M.; Roussel, P.; Den Auwer, C.; Picart, S.; Hennig, C.; Scheinost, A. C.; Delahaye, T.; Ayral, A.

U3O8 is considered to be the most stable phase for uranium oxide. Its structural properties must be accurately understood in order to foresee and manage aspects such as its leaching behavior when spent nuclear fuel is stored in an oxidative environment. Moreover, as fuel irradiation causes the formation of fission products and activation products such as plutonium and minor actinides, it is probable that U3O8 will be mixed with other chemical elements under real conditions of oxidation. The storage issue can be extended to americium transmutation, where the irradiated compounds are mixed oxides composed of uranium and americium. This study thus focused on determining the structural properties of a solid solution containing uranium and trivalent americium (U/Am ratio = 90/10), and synthetized so as to obtain conventional U3O8 oxide. This paper presents the possibility of combining trivalent americium with uranium in a U3O8 mixed oxide for the first time, despite the high valence and atomic ratio differences, and proposes novel structural arrangements. XRD measurements reveal americium substitution in U3O8 uranium cationic sites, leading to phase transformation into a U3O8 high temperature structure and general lattice swelling. XANES and EXAFS experiments highlight an excess of U+VI organized in uranyl units as the main consequence of accommodation.

Keywords: americium; transmutation; U3O8

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Permalink: https://www.hzdr.de/publications/Publ-24061
Publ.-Id: 24061


In-situ X-ray observations of dendritic solidification under the influence of natural and forced convection

Eckert, S.; Shevchenko, N.; Kepplinger, O.; Sokolova, O.

The directional solidification of Ga–25wt%In alloys within a Hele-Shaw cell was investigated by means of X-ray radioscopy. This diagnostic technique offers a visual access to opaque metal alloys and enables a basic, intuitional understanding of the complex interplay between melt flow and dendritic growth. Natural convection occurs during a bottom up solidification because lighter solute is rejected at the solid-liquid interface leading to an unstable density stratification. Forced convection was produced by a rotating wheel with two parallel disks containing at their inner sides a set of permanent NdFeB magnets with alternating polarization. The direction of forced melt flow is almost horizontal at the solidification front whereas local flow velocities in the range between 0.1 and 1.0 mm/s were achieved by controlling the rotation speed of the magnetic wheel.
Melt flow induces various effects on the grain morphology primarily caused by the convective transport of solute. Our observations show a facilitation of the growth of primary trunks or lateral branches, suppression of side branching, dendrite remelting and fragmentation. The manifestation of all phenomena depends on the dendrite orientation, local direction and intensity of the flow.
The forced flow eliminates the solutal plumes and damps the local fluctuations of solute concentration. It provokes a preferential growth of the secondary arms at the upstream side of the primary dendrite arms, whereas the high solute concentration at the downstream side of the dendrites can inhibit the formation of secondary branches completely. Moreover, the flow changes the inclination angle of the dendrites and the angle between primary trunks and secondary arms.

Keywords: solidification; melt flow; dendritic growth; fragmentation; segregation

  • Invited lecture (Conferences)
    16th International Conference on Liquid and Amorphous Metals (LAM-16), 05.-09.09.2016, Bonn-Bad Godesberg, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24060
Publ.-Id: 24060


Reactive transport modelling based on velocity fields obtained on drill core scale

Lippmann-Pipke, J.; Karimzadeh, L.; Blanc, P.; Eichelbaum, S.; Schymura, S.; Rogóż, T.; Frühwirt, K.; Kulenkampff, J.

The objective of the EU project BioMOre is the development of new technological concepts for in situ recovering metals from deep European Kupferschiefer deposits using controlled stimulation of pre-existing fractures in combination with in-situ bioleaching. Considerable parts of the project are leaching experiments on lab scale and on small field scale at a selected location in an existing copper mine, as well as the related reactive transport odelling tasks including the required backcoupling from chemical reactions on the hydrodynamics as well as the upscaling. These tasks shall assist in the optimization of the bio-leaching efficiency, stimulating processes, as well as the environmental impact and sustainability assessment. Here we introduce our most recent technical advancement. It allows us to accomplish two tasks in one line of action: The extraction of effective hydrodynamic parameters in 3D for downstram modelling, and the upscaling from molecular process observations to reactive transport simulations on drill core scale.
For more than a decade a spatiotemporal visualization tool for transport process observations in dense material by means of PET (positron emission tomography) was developed [1-5]. Such quantitative GeoPET images are xceptionally sensitive to displacements of pico molar tracer quantities detected within 1 mm grids on laboratory/drill core scale. Now we reached a strategic milestone: A custom made image analysis algorithm is capable of quantitatively extracting velocity and porosity fields from such GeoPET image time series, even if the 4D image information includes discontinuous flow patterns (due to bottle neck effect related detection limits) and localized image artifacts. We present our approach with the aid of a) the data set with which the algorithm was validated, and b) provide an outlook for its application in the context of this EU project: the bio-leaching of Kupferschiefer.
From an observed fluid flow process in a dense core material by means of GeoPET (Fig. 1 left) the effective porosity and velocity field is extracted by our image analyis algorithm and this data is used in a forward numerical transport simulation and compared with the original fluid flow process (Fig. 1 right). Next steps will be the evaluation of non-reactive flow process observations in fractured calciferous sandstone from the Kupferschiefer ore deposit (Fig. 2), and the respective porosity and velocity field extraction for 3D reactive transport modelling in fracture and porous matrix by means of iCP [6] - an interface coupling the finite element based code COMSOL Multiphysics® with the geochemical code PhreeqC.

  • Lecture (Conference)
    IMWA 2016 - Annual Conference of the International Mine Water Association, 14.07.2016, Leipzig, Germany
  • Contribution to proceedings
    IMWA 2016 - Annual Conference of the International Mine Water Association, 14.07.2016, Leipzig, Germany
    Mining Meets Water – Conflicts and Solutions, Freiberg: Medienzentrum of TU Bergakademie Freiberg, 978-3-86012-533-5, 1219-1220

Permalink: https://www.hzdr.de/publications/Publ-24059
Publ.-Id: 24059


Analysis of the characteristics of hot particles related to environmental fate and interaction with living organisms

Johansen, M. P.; Child, D. P.; Collins, R. N.; Hotchkis, M. A. C.; Howell, N. A.; Payne, T. E.; Mokhber-Shahin, L.; Ikeda-Ohno, A.

The radiological residues at the former British weapons testing sites at Maralinga, Emu and the Monte Bello Islands often occur in particulate form (so called hot particles). Large numbers of these particles were emitted from nuclear and non-nuclear tests. For example each square meter in a plume that extends for tens of kilometres at the Taranaki site (Maralinga) can contain more than 3000 readily identifiable particles. The physical and chemical characteristics of these particles affect their mobility and availability for uptake into living organisms. When they contain long-lived radionuclides (e.g. 239Pu) these particles may slowly weather, and thus provide a persistent source of ionic forms, or smaller particles, for many thousands of years.

Here we present a status on a range of methods being used at ANSTO to evaluate the physical and chemical characteristics of particles gathered from Australian sites. Methods include gamma spectrometry, autoradiography, high sensitivity Accelerator Mass Spectrometry analysis (AMS), leaching studies, and synchrotron-based X-ray fluorescence microscopy/spectroscopy. We focus on some of the practical issues involved when gathering and working with hot particles, as well as challenges in determining speciation and its influence on radioecological outcomes. We discuss data gaps and recommendations for current and future use of analysis methods in radioecological studies in Australia and the wider international community.

Keywords: Actinides; plutonium; environmental fate; bioavailability; nuclear weapons tests; Australia

  • Lecture (Conference)
    The South Pacific Environmental Radioactivity Association (SPERA) Conference 2016, 07.09.2016, Sanur, Indonesia

Permalink: https://www.hzdr.de/publications/Publ-24058
Publ.-Id: 24058


Improved direct measurement of the 64.5 keV resonance strength in the 17O(p,alpha)14N reaction at LUNA

Bruno, C. G.; Scott, D. A.; Aliotta, M.; Formicola, A.; Best, A.; Boeltzig, A.; Bemmerer, D.; Broggini, C.; Caciolli, A.; Cavanna, F.; Ciani, G. F.; Corvisiero, P.; Davinson, T.; Depalo, R.; Di Leva, A.; Elekes, Z.; Ferraro, F.; Fülöp, Z.; Gervino, G.; Guglielmetti, A.; Gustavino, C.; GyÜrky, G.; Imbriani, G.; Junker, M.; Menegazzo, R.; Mossa, V.; Pantaleo, F. R.; Piatti, D.; Prati, P.; Somorjai, E.; Straniero, O.; Strieder, F.; SzÜcs, T.; Takács, M. P.; Trezzi, D.

The 17O(p,α)14N reaction plays a key role in various astrophysical scenarios, from asymptotic giant branch stars to classical novae. It affects the synthesis of rare isotopes such as 17O and 18F, which can provide constraints on astrophysical models. A new direct determination of the ER = 64.5 keV resonance strength performed at the Laboratory for Underground Nuclear Astrophysics accelerator has led to the most accurate value to date, ωγ = 10.0 ± 1.4stat ± 0.7syst neV, thanks to a significant background reduction underground. The (bare) proton partial width of the corresponding state at Ex = 5672 keV in 18F is Γp = 35±5stat ±3syst neV. This width is about a factor of 2 higher than previously estimated thus leading to a factor of 2 increase in the 17O(p,α)14N reaction rate at astrophysical temperatures relevant to shell hydrogen-burning in red giant and asymptotic giant branch stars. The new rate implies lower 17O/16O ratios, with important implications on the interpretation of astrophysical observables from these stars.

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Permalink: https://www.hzdr.de/publications/Publ-24057
Publ.-Id: 24057


A mineral liberation study of grain boundary fracture based on measurements of the surface exposure after milling

Leißner, T.; Hoang, D.; Rudolph, M.; Heinig, T.; Bachmann, K.; Gutzmer, J.; Schubert, H.; Peuker, U. A.

Minerals can be liberated by random fracture of particles into smaller fragments or by detachment along phase boundaries. These two mechanisms represent borderline cases. When ores get comminuted the liberation of minerals is achieved to some extent by both mechanisms. This article describes a method to determine the extent of transgranular and intergranular fracture based on 2-dimensional analysis of surface exposure of minerals.
The approach uses the unbiased surface information like of phase specific surface area (PSSA), phase specific free surface (PSFS) and phase specific locked surface (PSLS) of minerals and their change with comminution. The parameters are discussed related to the normalized grain size, which is the ratio of mineral grain size in the product to mineral grain size in the unbroken material. Finally, the amount of transgranular and intergranular fracture on surface exposure can be calculated using the phase specific surface parameters.
A sedimentary rock (apatite ore), an igneous rock (nepheline-syenite) and an artificial material (copper slags) were ground to different fineness. Based on the mineral liberation analysis (MLA) of feed and products, the extent of phase boundary fracture on the surface exposure of the minerals is studied.

Keywords: Mineral liberation Analysis; preferential breakage; transgranular fracture; intergranular fracture; random fracture; grain boundary fracture

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Permalink: https://www.hzdr.de/publications/Publ-24056
Publ.-Id: 24056


JEMS2016: Magnetism in curved geometries

Makarov, D.

While conventionally magnetic films and structures are fabricated on flat surfaces, the topology of curved surfaces has only recently started to be explored and leads to new fundamental physics as well as applied device ideas. In particular, novel effects occur when the magnetization is modulated by curvature providing a new degree of freedom that leads to new magnetization configurations (see for instance [1,2]) and is predicted to have major implications on the spin dynamics due to topological constraints for instance in circular tubes and rolls [3].
Advances in this novel field solely rely on the understanding of the fundamentals behind the modifications of magnetic responses of 3D-curved magnetic thin films. The lack of an inversion symmetry and the emergence of a curvature induced effective anisotropy and Dzyaloshinskii-Moriya interaction are characteristic of curved surfaces [4-6], leading to curvature-driven magnetochiral effects [7-9] and topologically induced magnetization patterning [6, 10], including unlimited domain wall velocities in hollow tubes [3], chirality symmetry breaking [6-9] and Cherenkov-like effects for magnons [11]. In addition to these rich physics, the application potential of 3D-shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications [12], spin-wave filters [13], magneto-encephalography devices [14] and high-speed racetrack memory devices [3]. To this end, the initially fundamental topic of the magnetism in curved geometries strongly benefited from the input of the application-oriented community, which among others explores the shapeability aspect of the curved magnetic thin films. These activities resulted in the development of the family of shapeable magnetoelectronics [15], which already includes flexible [16], printable [17], stretchable [18] and even imperceptible [19] magnetic field sensorics.
These recent developments starting from the theoretical predictions to the fabrication and characterization of 3D-curved magnetic thin films and their application potential are in the focus of this talk.

Keywords: Curved magnetic thin films; rolled technology

Related publications

  • Invited lecture (Conferences)
    The 8th Joint European Magnetic Symposia (JEMS2016), 21.-26.08.2016, Glasgow, United Kingdom

Permalink: https://www.hzdr.de/publications/Publ-24055
Publ.-Id: 24055


Validation of the DYN3D-Serpent code system for SFR cores using selected BFS experiments. Part I: Serpent calculations.

Rachamin, R.; Kliem, S.

A comparative study has been performed to evaluate the prediction capability of the DYN3D-Serpent code system for sodium fast reactor (SFR) cores. In this study, the calculation system was tested against the BFS-73-1 and BFS-62-3A experiments conducted at the Russian Institute of Physics and Power Engineering (IPPE). These experiments were designed for full-scale modeling of SFR cores, and for validation of codes and nuclear data. The study was performed in two parts. The first part is aimed at developing and validating a 3D full-core heterogeneous model of each of the experiments using the Serpent Monte-Carlo code (MC) code. This part meant as a first step towards the use of the Serpent MC code as a tool for preparation of homogenized group constants, and as a reference solution for code-to-code comparison with the DYN3D code. The second part is devoted to the homogenized group constants generation procedure and the DYN3D steady-state calculations. This paper covers the first part of the study. The experiments were simulated using the Serpent MC code, and the basic neutronic characteristics were evaluated and compared against experimental values. The calculated results agreed well with the measured values on most of the neutronic characteristics. It suggests that the Serpent MC code can reliably be used for the preparation of homogenized group constants and as a reference solution for code-to-code verification with the DYN3D code.

Keywords: SFR; critical assembly; BFS experiments; validation; Serpent and DYN3D

Permalink: https://www.hzdr.de/publications/Publ-24054
Publ.-Id: 24054


Tuning the fabrication of nanostructures by low-energy highly charged ions

El-Said, A. S.; Wilhelm, R. A.; Heller, R.; Sorokin, M.; Facsko, S.; Aumayr, F.

Slow highly charged ions were utilized recently for the creation of monotype surface nanostructures (craters, calderas or hillocks) in different materials. In the present study, we report on the ability of slow highly charged xenon ions (129XeQ+) to form three different types of nanostructures on LiF (100) surface. By increasing the charge state from Q = 15 to Q = 36, the shape of the impact induced nanostructures changes from craters to hillocks crossing an intermediate stage of caldera structures. The dimensional analysis of the nanostructures reveals an increase of the height up to 1.5 nm as a function of the potential energy of the incident ions. Based on the evolution of both the geometry and size of the created nanostructures, defect-mediated desorption and the development of a thermal spike are utilized as creation mechanisms of the nanostructures at low and high charge states, respectively.

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Permalink: https://www.hzdr.de/publications/Publ-24053
Publ.-Id: 24053


Reactivity of t-butyl hydroperoxide and t-butyl peroxide towards reactor materials measured by a microcalorimetric method at 30 °C.

Willms, T.; Kryk, H.; Oertel, J.; Lu, X.; Hampel, U.

To investigate the oxidation of isobutane to t-butyl hydroperoxide (TBHP) for the first time as a two-phase process in a micro reactor in a broad range of flow rates (isobutane flow rate: 15 to 188 µl/min, oxygen: 0.1 to 1.5 ml/min), temperatures (75 to 150 °C) and pressures (25 to 100 bar), a study has been performed to select the most appropriate construction materials for the experimental facility, especially for the microreactor but also for fittings, sealings, sensors, pumps, tubes, the sampling unit etc. TBHP, as most hydroperoxides, is quite reactive and reacts with most metals, polymers, acids and bases. Therefore, the most suitable materials had to be determined to minimize losses of TBHP in the initiator pump and in the reaction mixture of the sample at ambient temperature. As TBHP ¬¬decom¬poses very slowly under such conditions, a microcalorimetric method (TAM) has been used to measure the heat production of TBHP in contact with selected materials at 30 °C. Among those materials various metals e.g. copper, gold, silver, zinc, aluminum, titanium, tantalum, normal steel, hastelloy C276, hastelloy C-2000, V4A steel as well as semiconductors like silicon and silicon carbide have been tested. Furthermore, several polymers like nitrile butyl rubber, PEEK, silicone, Chemraz® and PTFE have been studied. Moreover, the role of metals and metal ions as catalysts for the decomposition of TBHP and DTBP is discussed. The experiments showed that silver and copper are the most reactive metals of the investigated substances and silicon the most suitable coating material for the reactor. The most stable polymers were found to be PEEK, Tedlar, Chemraz® and PTFE.

Keywords: Reactivity; reactor materials; micro calorimetry; t-butyl hydroperoxide; di-t-butyl peroxide

  • Lecture (Conference)
    GEFTA-Jahrestagung 2016 - Polymeranwendungen der ultraschnellen Kalorimetrie, 14.-16.09.2016, Halle, Deutschland
  • Open Access Logo Journal of Thermal Analysis and Calorimetry 128(2017)1, 319-333
    Online First (2016) DOI: 10.1007/s10973-016-5860-5
    Cited 7 times in Scopus
  • Contribution to proceedings
    GEFTA-Jahrestagung 2016 - Polymeranwendungen der ultraschnellen Kalorimetrie,, 14.-16.09.2016, Halle (Saale), Deutschland
    Proceedings der GEFTA-Jahrestagung 2016

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Permalink: https://www.hzdr.de/publications/Publ-24052
Publ.-Id: 24052


ZnO Luminescence and scintillation studied via photoexcitation, X-ray excitation, and gamma-induced positron spectroscopy

Ji, J.; Colosimo, A. M.; Anwand, W.; Boatner, L. A.; Wagner, A.; Stepanov, P. S.; Trinh, T. T.; Liedke, M. O.; Krause-Rehberg, R.; Cowan, T. E.; Selim, F. A.

The luminescence and scintillation properties of ZnO single crystals were studied by photoluminescence and X-ray-induced luminescence (XRIL) techniques. XRIL allowed a direct comparison to be made between the near-band emission (NBE) and trap emissions providing insight into the carrier recombination efficiency in the ZnO crystals. It also provided bulk luminescence measurements that were not affected by surface states. The origin of a green emission, the dominant trap emission in ZnO, was then investigated by gamma-induced positron spectroscopy (GIPS) - a unique defect spectroscopy method that enables positron lifetime measurements to be made for a sample without contributions from positron annihilation in the source materials. The measurements showed a single positron decay curve with a 175 ps lifetime component that was attributed to Zn vacancies passivated by hydrogen. Both oxygen vacancies and hydrogen-decorated Zn vacancies were suggested to contribute to the green emission. By combining scintillation measurements with XRIL, the fast scintillation in ZnO crystals was found to be strongly correlated with the ratio between the defect luminescence and NBE. This study reports the first application of GIPS to semiconductors, and it reveals the great benefits of the XRIL technique for the study of emission and scintillation properties of materials.

Keywords: luminescence; scintillation; ZnO; photoluminescence; X-ray-induced luminescence XRIL; gamma-induced positron spectroscopy GIPS; defect spectroscopy

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Permalink: https://www.hzdr.de/publications/Publ-24051
Publ.-Id: 24051


Insights into the structure and thermal stability of uranyl aluminate nanoparticles

Chave, T.; Le Goff, X.; Scheinost, A. C.; Nikitenko, S. I.

Ultrasonically assisted hydrolytic precipitation of U(VI) in the presence of mesoporous alumina followed by thermal treatment of solid precursor allowed to obtain crystallized uranyl aluminate (URAL) nanoparticles (NPs) dispersed in alumina matrix. Effect of U(VI) concertation and calcination temperature on the yield of URAL NPs was studied using XRD, XAFS and HRTEM techniques. At 800°C, URAL NPS (d≈5 nm) are formed only for low uranium loading of about 5 wt% whereas for higher content of uranium, larger U3O8 NPs (d≈20 nm) were identified as a principal uranium specie. At 500°C, URAL NPs are formed even for 25 wt% of uranium. U LIII edge EXAFS spectra pointed out that uranyl cation in URAL is coordinated by bidentate aluminate groups. Presumably URAL is formed during the heating of 2UO3·NH3·2H2O/AlO(OH) precursor. However, high temperature and larger content of uranium promote URAL transformation to more thermodynamically stable U3O8 oxide. This process is accompanied by uranium NPs growing via Ostwald ripening mechanism.

Keywords: uranium oxide; nanoparticles; EXAFS; HRTEM

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Permalink: https://www.hzdr.de/publications/Publ-24050
Publ.-Id: 24050


Proteine als neue Bausteine für funktionalisierte Textilverbunde

Sallat, M.; Raff, J.

Ziel eines Forschungsvorhabens war es, neue Möglichkeiten der Oberflächenfunktionalisierung textiler Fasern bzw. Flächengebilde durch die Applikation bakterieller Hüllproteine, sogenannter S-Layer-Proteine, zu erarbeiten. Aufgrund der intrinsischen Eigenschaft dieser Proteine, sich auch nach Isolation in Abhängigkeit von den Randbedingungen in äußerst regelmäßiger Form auf Oberflächen verschiedenster Materialien zu reorganisieren, eröffnen sich neue Wege bei der Nano- und Mikrostrukturierung von Textilien. Auf Basis dieser Strukturierung wurde untersucht, ob und in welcher Form sich prinzipiell ausgewählte Funktionalitäten (antimikrobielle Wirksamkeit, katalytische Aktivitäten, Hydrophilie/Hydrophobie) auf Vliesstoffen erzielen lassen und ob ausgewählte Effekte (Hydrophilie/Hydrophobie, Oleophobie) intensiviert werden können.

Im Rahmen der Arbeiten wurden Vliesstoffe unterschiedlicher chemischer Basis (PP, PE/PP, PET, PA/PET) mit S-Layer-Proteinen beschichtet und anschließend

  • mit Silbernanopartikeln antimikrobiell ausgerüstet,
  • mit Palladiumnanopartikeln katalytisch aktiviert,
  • mit Carbonsäure- bzw. Polyurethanverbindungen chemisch hydrophiliert,
  • mit Fluorcarbonen oleophobiert und
  • mit wasserbasierten Polyurethan-Dispersionen beschichtet.

Aus den im Beitrag dargestellten Ergebnissen dieser Grundlagenarbeiten lassen sich nun weitere erfolgversprechende Entwicklungsarbeiten im Hinblick auf mögliche industrielle Anwendungen ableiten. Erwähnt seien in diesem Zusammenhang z. B. die Verbesserung der Verklebbarkeit textiler Oberflächen (Hotmelt-Kaschierung) oder die Funktionalisierung textiler Filtermedien zur Adsorption von Schadstoffen (Atemluftfiltration, Wasseraufbereitung).

Keywords: Textil; S-Layer; Funktionalisierung

  • Lecture (Conference)
    24. Neues Dresdner Vakuumtechnisches Kolloquium, 29.-30.09.2016, Dresden, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24049
Publ.-Id: 24049


Bacterial S-layer proteins and their interaction with radionuclides

Raff, J.; Vogel, M.; Drobot, B.; Schmoock, C.; Moll, H.; Barkleit, A.; Börnick, H.; Worch, E.; Stumpf, T.

Bacterial surface-layer (S-layer) proteins form the outermost cell envelope of many bacteria and all archaea. These proteins are able to self-assemble in highly regular layers forming an oblique, square or hexagonal lattice on the entire cell. This layer protects especially bacteria living in extreme habitats against diverse harmful environmental influences. In case of uranium mining waste pile isolates belonging to the genera Lysinibacillus and Bacillus it was proven that the S-layers act as scavenger for reactive oxygen species probably formed by either radiolysis of water or Fenton reaction. The inactivation of the radicals is achieved by intermolecular crosslinking of tyrosine residues of the protein monomers. Furthermore, these S-layers have a variety of free functional groups such as carboxyl, hydroxyl and amino groups determined by potentiometric titration. These groups form at least two different calcium binding sites being important for the self-assembly of the protein and are responsible for the selective binding of toxic elements. Additionally, S-layer proteins are posttranslationally modified with sugar residues, phosphate, sulfate or sulfoxide groups. While hexavalent uranium is bound by several surface exposed functional groups, it is easily released at acidic pH and thusly do not affect strongly cell metabolism. However, the trivalent curium substitutes calcium and is only released at pH 2.0 or below. Interestingly, metabolism relevant metals such as Mn, Fe, Co, Ni, Cu, Zn were not bound by the proteins. These examples demonstrate that radionuclides can specifically interact with the biosphere affecting significantly their behaviour even in natural environments.

Keywords: Radionuclides; S-layer

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  • Invited lecture (Conferences)
    Frontiers in Environmental Radioactivity, 06.-07.01.2016, London, United Kingdom

Permalink: https://www.hzdr.de/publications/Publ-24048
Publ.-Id: 24048


Investigating the removal of particles from the air/water-interface – Modelling detachment forces using an energetic approach

Knüpfer, P.; Fritzsche, J.; Leistner, T.; Rudolph, M.; Peuker, U. A.

and removing a particle from an interface requires a high force. The capillary force affects at the particle and causes an interfacial deformation during detachment. In this study the detachment force of hydrophilic and hydrophobic particles is measured via CP-AFM. In order to calculate the detachment force, a simple analytical model is developed and compared with the classical capillary force model. The new model is grounded on an energetic approach in compliance to the interfacial deformation and wetting of the particle. A model spring is assumed for both sub-processes and the force affects onto these two springs. The calculated force in the new model referred to goes better with experimental values than the capillary force model which does not consider interfacial deformation.

Keywords: AFM; capillary force; detachment force; energy of adhesion; interfacial deformation; spring model

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Permalink: https://www.hzdr.de/publications/Publ-24047
Publ.-Id: 24047


WissKom2016: Der Schritt zurück als Schritt nach vorn – Macht der Siegeszug des Open Access Bibliotheken arbeitslos? 7. Konferenz der Zentralbibliothek, Forschungszentrum Jülich

Reschke, E.

Vom 14. bis 16. Juni 2016 fand die nunmehr siebente WissKom statt. Die Zentralbibliothek des Forschungszentrum Jülich hatte wieder eingeladen und in gewohnter Perfektion die Tagung organisiert. An drei Tagen wurde zum Themenfeld Modernes Bibliothekswesen und zeitgemäße Informationsversorgung unter besonderem Augenmerk auf den Open Access Transformationsprozess im wissenschaftlichen Publikationswesen vorgetragen und diskutiert. Neue Aufgabenfelder für wissenschaftliche Bibliotheken im vielgestaltigen Prozess der Neuorientierung wurden vorgestellt. Das umfasste den Wandel im Publikationsprozess selbst, Nachweissysteme für Publikationen, Repositorien, Open Access Grün und Zweitveröffentlichung, Forschungsdaten und Fragen der Wissenschaftsevaluierung.

Keywords: Wisskom; Open Access; Libray

  • b.i.t.online 19(2016)5, 459-460
  • Open Access Logo b.i.t.online 19(2016)5, 458-466
    ISSN: 1435-7607

Permalink: https://www.hzdr.de/publications/Publ-24046
Publ.-Id: 24046


Physicochemical Properties of Aminated Butyl-Nanocrystals in Correlation to the Flotation Response of Quartz

Hartmann, R.; Rudolph, M.; Laitinen, O.; Sirviö, J. A.; Liimatainen, H.; Illikainen, M.

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to environmental regulations, biodegradability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile preparation routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystals (BAC) and quartz are used as standard model to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the particle size and size distribution, surface charge distribution and electrophoretic mobility of BAC and quartz are measured. Based on this, the adsorption isotherm of BAC on quartz is established. For the determination of the surface free energy, the inverse gas chromatography (iGC) technique as well as the contact angle method are applied and compared. Finally, flotation experiments in bench-scale prove the efficiency of BAC to be used in flotation processes.

Keywords: cellulose nanocrystals; quartz; surface charge distribution; electrophoretic mobility; adsorption; surface free energy; flotation

  • Contribution to proceedings
    IMPC 2016 - XXVIII International Mineral Processing Congress, 11.-15.09.2016, Quebec, Canada
    IMPC 2016 - Conference Proceedings, Quebec: CIM/ICM, 978-1-926872-29-2

Permalink: https://www.hzdr.de/publications/Publ-24045
Publ.-Id: 24045


Treatment of once rejected material – investigating the recovery of cassiterite from tailings disposals using different flotation methods

Leistner, T.; Leißner, T.; Möckel, R.; Osbahr, I.; Rudolph, M.; Peuker, U. A.

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until the late 1980s. For long times, gravity separation processes used to be the main beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. Since for fine and very fine particles these approaches might not represent effective techniques, much valuable material could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles.

In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods. The material used is previously classified into different size ranges. Conventional froth flotation is applied to the fine particles (20µm – 100µm). For the very fine particle (< 20µm), special emphasis is put on oil-assisted flotation methods, including oil agglomeration flotation and two-liquid flotation. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (e.g. sulphosuccinamates, phosphonic acids) and depressants (e.g. sodium fluorosilicate, oxalic acid) regime, oil dosage, oil/pulp agitation time and pulp density. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements, zeta potential analysis and infrared spectroscopy. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Keywords: tailing reprocessing; flotation methods; cassiterite; very fine particle processing; oil-assisted flotation

  • Contribution to proceedings
    IMPC 2016 - XXVIII International Mineral Processing Congress, 11.-15.09.2016, Quebec, Canada
    IMPC 2016 - Conference Proceedings, Quebec: CIM/ICM, 978-1-926872-29-2

Permalink: https://www.hzdr.de/publications/Publ-24044
Publ.-Id: 24044


Investigations on Mineral Liberation by Transgranular and Intergranular Fracture after Milling

Leißner, T.; Hoang, D. H.; Rudolph, M.; Heinig, T.; Bachmann, K.; Schubert, H.; Peuker, U. A.

In comminution minerals can be liberated by random fracture of particles into smaller fragments or by detachment along phase boundaries. These two mechanisms represent borderline cases. When ores get crushed and milled the liberation of minerals is achieved to some extent by both mechanisms. This article describes a method to determine the extent of transgranular and intergranular fracture of minerals based on 2-dimensional liberation analysis from automated mineralogy.
The approach uses the non-biased surface information like phase specific surface area (PSSA), phase specific free surface (PSFS) and phase specific locked surface (PSLS) of minerals and their change through comminution. The parameters are discussed related to the normalized grain size, which is the ratio of mineral grain size of the milled product to mineral grain size of the feed material. Finally the amount of transgranular and intergranular fracture can be calculated using the phase specific surface parameters.
An apatite ore (sedimentary origin), a rare earth mineral containing nepheline-syenite and a porphyry-copper ore (both igneous origin) were ground to different fineness using a ball mill. Based on the mineral liberation analysis (MLA, device FEI Quanta 650 MLA-FEG) of feed and products, the extent of phase boundary fracture on the surface exposure of the minerals is studied.
It is found, that the extent of transgranular and intergranular fracture on surface exposure differs for different types of ores. For sedimentary rocks, intergranular fracture (detachment) plays a major role in the liberation of the minerals (cf. Fig. 1 a). Surface exposure of minerals from the nepheline-syenite (cf. Fig. 1, b) has to be discussed more differentiated. Feldspar shows a small percentage of detachment on surface exposure whereas the aegirine is liberated in equal proportions by both mechanisms.
The presented method of liberation analytical calculations using phase specific surface information will be useful for the better understanding of ore specific fracture events with different comminution strategies. Consequently, it will lead to a more economical way to successfully liberate minerals by the energy intense processes of comminution.

Keywords: Mineral liberation analysis; preferential breakage; transgranular fracture; intergranular fracture; random fracture; grain boundary fracture

  • Contribution to proceedings
    IMPC 2016 - XXVIII International Mineral Processing Congress, 11.-15.09.2016, Quebec, Canada
    IMPC 2016 - Conference Proceedings, Quebec: CIM/ICM, 978-1-926872-29-2

Permalink: https://www.hzdr.de/publications/Publ-24043
Publ.-Id: 24043


Activation cross sections of longer-lived radionuclides produced in germanium by alpha particle irradiation

Takács, S.; Takács, M. P.; Ditrói, F.; Aikawa, M.; Haba, H.; Komori, Y.

The cross sections of alpha particles induced nuclear reactions on natural germanium were investigated by using the standard stacked foil target technique, the activation method and high resolution gamma spectrometry. Targets with thickness of about 1 μm were prepared from natural Ge by vacuum evaporation onto 25 μm thick polyimide (Kapton) backing foils. Stacks were composed of Kapton-Ge-Ge-Kapton sandwich target foils and additional titanium monitor foils with nominal thickness of 11 μm to monitor the beam parameters using the natTi(α,x)51Cr reaction. The irradiations were done with Eα = 20.7 and Eα = 51.25 MeV, Iα = 50 nA alpha particle beams for about 1 h. Direct or cumulative activation cross sections were determined for production of the 72,73,75Se, 71,72,74,76,78As, and 69Ge radionuclides. The obtained experimental cross sections were compared to the results of theoretical calculations taken from the TENDL data library based on the TALYS computer code. A comparison was made with available experimental data measured earlier. Thick target yields were deduced from the experimental cross sections and compared with the data published before.

Keywords: Alpha particle irradiation; Natural germanium target; Cross sections; 72,73,75Se,71,72,74,76,78As and 69Ge excitation functions; TENDL comparison

Permalink: https://www.hzdr.de/publications/Publ-24042
Publ.-Id: 24042


Incorporation of thorium in the zircon structure type through the Th1-xErx(SiO4)1-x(PO4)x thorite-xenotime solid solution

Mesbah, A.; Clavier, N.; Lozano-Rodriguez, J.; Szenknect, S.; Dacheux, N.

Pure powdered compounds with a general formula Th1-xErx(SiO4)1-x(PO4)x belonging to the zircon-xenotime were successfully synthesized under hydrothermal conditions (250°C, 7 days) as recently reported for the preparation of coffinite. Therefore a thorough combined PXRD, EDS, EXAFS, μ-Raman and FTIR analyses showed the formation of solid solution in agreement with the Vergard’s law. Moreover, the examination of the local structure shows that the Th-O distances remain close to those found in ThSiO4. Whereas, the Er-O distances show big decrease from 2.38(14) Å to 2.34(7) Å when increasing the erbium content from x = 0.2 to x = 1. The variation of the local structure also affects the PO4 3- groups that are surely distorted in the structure.

Keywords: xenotime; monazite; EXAFS; actinides; phosphate

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Permalink: https://www.hzdr.de/publications/Publ-24041
Publ.-Id: 24041


Thermodynamics Behavior of Germanium During Equilibrium Reactions between FeOx-CaO-SiO2-MgO Slag and Molten Copper

Reuter, M. A.; Shuva, M. A. H.; Rhamdhani, M. A.; Brooks, G. A.; Masood, S.

The distribution ratio of germanium (Ge), (Formula presented.) during equilibrium reactions between magnesia-saturated FeOx-CaO-SiO2 (FCS) slag and molten copper has been measured under oxygen partial pressures from 10−10 to 10−7 atm and at temperatures 1473 to 1623 K (1200 to 1350 °C). It was observed that the Ge distribution ratio increases with increasing oxygen partial pressure, and with decreasing temperature. It was also observed that the distribution ratio is strongly dependent on slag basicity. The distribution ratio was observed to increase with increasing optical basicity. At fixed CaO concentration in the slag, the distribution ratio was found to increase with increasing Fe/SiO2 ratio, tending to a plateau at (Formula presented.) = 0.8. This behavior is consistent with the assessment of ionic bond fraction carried out in this study, and suggested the acidic nature of germanium oxide (GeO2) in the slag system studied. The characterisation results of the quenched slag suggested that Ge is present in the FeOx-CaO-SiO2-MgO slag predominantly as GeO2. At 1573 K (1300 °C) and (Formula presented.) = 10−8 atm, the activity coefficient of GeO2 in the slag was calculated to be in the range of 0.24 to 1.50. The results from the current study suggested that less-basic slag, high operating temperature, and low oxygen partial pressure promote a low Ge distribution ratio. These conditions are desired for maximizing Ge recovery, for example, during pyrometallurgical processing of Ge-containing e-waste through secondary copper smelting. Overall, the thermodynamics data generated from this study can be used for process modeling purposes for improving recovery of Ge in primary and secondary copper smelting processes.

Keywords: Engineering controlled terms: Copper; Germanium; Germanium oxides; Iron oxides; Magnesia; Oxygen; Partial pressure; Pyrometallurgy; Secondary recovery; Slags; Temperature; Thermodynamics; Distribution ratio; Equilibrium reactions; High operating temperature; Low oxygen partial pressure; Oxygen partial pressure; Pyrometallurgical processing; Secondary copper smelting; Thermodynamics data

Permalink: https://www.hzdr.de/publications/Publ-24040
Publ.-Id: 24040


Hydrodynamic modeling of a pure-glue initial scenario in high-energy hadron and heavy-ion collisions

Vovchenko, V.; Pang, L.-G.; Niemi, H.; Karpenko, I. A.; Gorenstein, M. I.; Satarov, L. M.; Mishustin, I. N.; Kämpfer, B.; Stoecker, H.

Partonic matter produced in the early stage of ultrarelativistic nucleus-nucleus collisions is assumed to be composed mainly of gluons, and quarks and antiquarks are produced at later times. The comparable hydrodynamic simulations of heavy-ion collisions for (2+1)-flavor and Yang-Mills equations of state performed by using three different hydrodynamic codes are presented. Assuming slow chemical equilibration of quarks, the spectra and elliptic flows of thermal dileptons and photons are calculated for central Pb+Pb collisions at the LHC energy of √sNN=2.76 TeV. It is shown that a suppression of quarks at early times leads to a significant reduction of the yield of the thermal dileptons, but only to a rather modest suppression of the pT-distribution of direct photons. It is demonstrated that an enhancement of photon and dilepton elliptic flows might serve as a promising signature of the pure-glue initial state. Calculations based on Bjorken hydrodynamics suggest that collisions of small systems at intermediate energies available at RHIC or future FAIR facilities may show stronger effects associated with initial pure gluodynamic evolution.

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Permalink: https://www.hzdr.de/publications/Publ-24039
Publ.-Id: 24039


Vacuum particle-antiparticle creation in strong fields as a field induced phase transition

Smolyansky, S. A.; Panferov, A. D.; Blaschke, D. B.; Juchnowski, L.; Kämpfer, B.; Otto, A.

The features of vacuum particle creation in an external classical field are studied for simplest external field models in 3+1 dimensional QED. The investigation is based on a kinetic equation that is a nonperturbative consequence of the fundamental equations of motion of QED. The observed features of the evolution of the system apply on the qualitative level also for systems of other nature and therefore are rather general. Examples from cosmology and condensed matter physics illustrate this statement. The common basis for the description of these systems are kinetic equations for vacuum particle creation belonging to the class of integro-differential equations of non-Markovian type with fastly oscillating kernel. This allows to characterize processes of this type as belonging to the class of field induced phase transitions.

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Permalink: https://www.hzdr.de/publications/Publ-24038
Publ.-Id: 24038


Holographically emulating sequential versus instantaneous disappearance of vector mesons in a hot environment

Zöllner, R.; Kämpfer, B.

Descent extensions of the soft-wall model are used to accommodate two variants of Regge trajectories of vector meson excitations. At non-zero temperatures, various options for either sequential or instantaneous disappearance of vector mesons as normalisable modes are found, thus emulating deconfinement at a certain temperature in the order of the (pseudo-) critical temperature of QCD. The crucial role of the blackness function, which steers the thermodynamic properties of the considered system, is highlighted.

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Permalink: https://www.hzdr.de/publications/Publ-24037
Publ.-Id: 24037


The Link Between the Local Bubble and Radioisotopic Signatures on Earth

Feige, J.; Breitschwerdt, D.; Wallner, A.; Schulreich, M. M.; Kinoshita, N.; Paul, M.; Dettbarn, C.; Fifield, K. L.; Golser, R.; Honda, M.; Linnemann, U.; Matsuzaki, H.; Merchel, S.; Rugel, G.; Steier, P.; Tims, S. G.; Winkler, S. R.; Yamagata, T.

Traces of 2-3 Myr old 60Fe were recently discovered in a manganese crust and in lunar samples. We have found that this signal is extended in time and is present in globally distributed deep-sea archives. A second 6.5-8.7 Myr old signature was revealed in a manganese crust. The existence of the Local Bubble hints to a recent nearby supernova-activity starting 13 Myr ago. With analytical and numerical models generating the Local Bubble, we explain the younger 60Fe-signature and thus link the evolution of the solar neighborhood to terrestrial anomalies.

Keywords: supernova; AMS; radionuclide; local bubble; deep-sea samples; interstellar medium; accelerator mass spectrometry

Related publications

  • Open Access Logo Contribution to proceedings
    14th International Symposium on Nuclei in the Cosmos XIV, 19.-24.06.2016, Toki Messe, Niigata, Japan
    Proceedings of the 14th International Symposium on Nuclei in the Cosmos XIV, JPS Conf. Proc. 14 (2017): JPS (Japan Physical Society) Conference Proceeding, 010304
    DOI: 10.7566/JPSCP.14.010304

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Permalink: https://www.hzdr.de/publications/Publ-24036
Publ.-Id: 24036


Moments-based ultrasound visual servoing: from mono to multi-plane approach

Nadeau, C.; Krupa, A.; Petr, J.; Barillot, C.

This paper presents a new image-based visual servoing approach to control a robotic system equipped with an ultrasound imaging device. The presented method allows an automatic positioning of the probe with respect to an object of interest. Moments-based image features are computed from three orthogonal ultrasound images to servo in-plane and out-of plane motions of the system. An efficient segmentation method, based on graph cut strategy, is proposed to extract the object contour in each image plane. Simulation results demonstrate that this approach improves upon techniques based on a single 2D US image in terms of probe positioning. Our method was also validated from robotic experiments performed on an ultrasound phantom with the use of a motorized 3D probe that provides the three US images.

Keywords: Visual servoing; ultrasound images; graph cut segmentation; moment features

Permalink: https://www.hzdr.de/publications/Publ-24035
Publ.-Id: 24035


Magnetic properties and giant reversible magnetocaloric effect in the GdCoC2 compound

Meng, L.; Xu, C.; Yuan, Y.; Qi, Y.; Zhou, S.; Li, L.

The crystal structure, magnetic properties and magnetocaloric effect (MCE) of GdCoC2 have been studied. The compound crystallizes in an orthorhombic CeNiC2-type structure which belongs to Amm2 space group. A giant reversible MCE is observed in GdCoC2 accompanied by a second-order paramagnetic to ferromagnetic (PM-FM) phase transition around the Curie temperature ~15 K. For the magnetic field change of 0-5 T, the maximum values of the magnetic entropy change (-ΔSMmax), relative cooling power (RCP), and refrigerant capacity (RC) are 28.4J/kg K, 566 J/kg and 369 J/kg, respectively. The present results indicate that the GdCoC2 compound is a promising candidate for low temperature magnetic refrigeration.

Keywords: GdCoC2 compound; magnetocaloric effect; magnetic properties; magnetic refrigeration

Permalink: https://www.hzdr.de/publications/Publ-24034
Publ.-Id: 24034


Raman scattering at terahertz frequencies enabled by an infrared free electron laser

Pavlov, S.; Dessmann, N.; Zhukavin, R. K.; Shastin, V.; Hübers, H.-W.; Pohl, A.; Redlich, B.; van der Meer, A. F. G.; Winnerl, S.; Schneider, H.; Ortega, J.-M.; Prazeres, R.; Abrosimov, N. V.

In the last decade the use of infrared free electron laser facilities enabled observation of inelastic light (Raman) scattering in THz frequency range. Raman-active intracenter donor transitions in silicon fall into the THz range and serve as outgoing resonances in electronic Stokes scattering. At photon fluxes above 1E24 photon/cm2/s donor-related Raman stimulated emission occurs in the range 4.2-6.5 THz from natural and isotopically enriched silicon crystals with various dopants while the free electron laser wavelength was varied between 18 and 41 mkm (7.5-16.5 THz). Study of dynamics of the observed emission shows a transient picosecond-micropulse mode that indicates on significantly larger Raman gain realized in THz Raman silicon lasers. This research has been partly supported by the EC CALIPSO project for the Transnational access to the European FELs and Synchrotron facilities as well as joint German-Russian program "Research on technological advances of radiation sources of photons and neutrons based on accelerators and neutron sources in cooperation with research organizations and universities of the Federal Republic of Germany" (InTerFEL project, BMBF No. 05K2014 and the Russian Ministry of Science and Education (No. RFMEFl61614X0008).

Keywords: terahertz; infrared; free-electron laser; Raman scattering

Related publications

  • Lecture (Conference)
    2016 International Conference "Synchrotron and Free electron laser Radiation: generation and application" (SFR-2016), 04.-07.07.2016, Novosibirsk, Russia

Permalink: https://www.hzdr.de/publications/Publ-24033
Publ.-Id: 24033


Exciton dynamics in semiconductor quantum wells and single quantum dots studied with a THz free-electron laser

Schneider, H.; Stephan, D.; Zybell, S.; Winnerl, S.; Bhattacharyya, J.; Eßer, F.; Helm, M.

Excitons in III-V semiconductors are Coulomb-bound electron-hole pairs which are analogous to two-dimensional hydrogen atoms with terahertz (THz) binding energies. In semiconductor quantum wells (QW), confinement into the plane of the QW gives rise to essentially two-dimensional excitons, thus giving rise to a different symmetry and higher binding energy. In quantum dots (QD), three-dimensional confinement leads to discrete electronic and excitonic states, such that the system becomes similar to a trapped atom.
Using intense, spectrally narrow terahertz (THz) pulses from the free-electron laser (FEL) facility FELBE in Dresden, Germany, we have investigated the population dynamics between exciton states in III-V QWs and single QDs. To this end, carriers are optically injected by picosecond near-infrared optical pulses, which leads to a population of the lowest excitonic level. Using narrowband THz pulses provided by the free-electron laser at HZDR, excitons are resonantly excited into higher levels. Time-dependent photoluminescence (TDPL) measurements based on a streak camera system and on time-correlated photon counting, respectively, then allow us to study the transient population of dipole-allowed higher excitonic levels and to access the relaxation dynamics of these quasi-particles.
In QWs, the most prominent transition is from the 1s ground state into the 2p excited state (using hydrogen notation). While the 2p state is "optically dark", rapid scattering from the 2p into the 2s state occurs. TDPL originating from the 1s and 2s exciton states thus provides a unique signature which allows us to explore the relaxation dynamics involving 1s, 2s, and 2p excitons. Now turning to QDs, single QDs rather than QD ensembles should be investigated in order to prevent strong inhomogeneous broadening. We have therefore developed a micro-TDPL setup with a probe volume significantly below 1 µm^3 and high quantum efficiency to become sensitive to one single QD. In particular, we investigate the dynamics of the s-to-p inter-sublevel transition, which occurs in the range 13-20 meV for the QDs under study. Resonant excitation with a THz pulse, which is applied at about 0.7 ns time delay after interband excitation, causes an instantaneous reduction of the ground state TDPL. The signal recovers within about 100 ps towards a value which depends on the near-infrared excitation energy. In particular, qualitatively different behavior has been observed and analyzed using a phenomenological rate equation for interband excitation of the GaAs matrix, the InGaAs wetting layer, and quasi-resonant excitation of the QD.
Acknowledgements: We thank L. Schneebeli, C.N. Böttge, M. Kira, and S.W. Koch (Marburg, Germany) for fruitful discussions and collaboration.

Keywords: quantum well; exciton; terahertz; free-electron laser

Related publications

  • Invited lecture (Conferences)
    International Workshop on "Terahertz Science, Nanotechnologies and Applications", 16.-22.07.2016, Erice, Italien

Permalink: https://www.hzdr.de/publications/Publ-24032
Publ.-Id: 24032


Semiconductor spectroscopy with infrared and THz free-electron lasers

Schneider, H.

This talk reviews some recent spectroscopic studies on semiconductor structures carried out using the mid-infrared and terahertz (THz) free-electron laser facility FELBE in Dresden, Germany. Its intense, nearly transform-limited picosecond pulses, which can also be combined with synchronous pico- or femtosecond pulses from near-infared tabletop lasers, provide unique research opportunities to advance our knowledge on the interaction of intense mid-infrared and THz fields with materials and devices.

Keywords: Semiconductor spectroscopy; infrared; terahertz; free-electron laser

Related publications

  • Invited lecture (Conferences)
    2016 International Conference on "Synchrotron and Free electron laser Radiation: generation and application" (SFR-2016), 04.-07.07.2016, Novosibirsk, Russia

Permalink: https://www.hzdr.de/publications/Publ-24031
Publ.-Id: 24031


Overcoming the diffraction limit with a GaAs-based plasmonic superlens

Fehrenbacher, M.; Winnerl, S.; Döring, J.; Kehr, S. C.; Eng, L. M.; Huo, Y. H.; Schmidt, O. G.; Yao, K.; Liu, Y.; Helm, M.; Schneider, H.

We report a semiconductor-based superlens for sub-diffraction-limited near-field imaging at mid-infrared wavelengths. The superlens is based on a sequence of intrinsic and doped GaAs layers. Resonant enhancement of evanescent waves is accomplished here by exploiting the Drude response of a highly doped n-GaAs layer. Operation as a near-field superlens is validated by utilizing an aperture-less scattering near-field optical microscope (s-SNOM), which allows us to probe the image plane of the superlens with sub-wavelength resolution.
In our experiments, gold stripes underneath the GaAs superlens are imaged by the s-SNOM. The s-SNOM comprises an atomic-force microscope (AFM), the tip of which is illuminated by mid-infrared radiation from a free-electron laser (FEL). Imaging results reveal sub-wavelength resolution better than λ/6 at the resonant wavelength of λ = 22.0 µm. In excellent accordance with the Drude-Lorentz model, the resonant wavelength for superlensing can easily be adjusted by changing the doping concentration. Our approach thus reveals a simple and versatile superlens implementation for infrared nanospectroscopy. Detector issues specific for s-SNOM will also be addressed.
[1] M. Fehrenbacher, S. Winnerl, H. Schneider, J. Döring, S. C. Kehr, L. M. Eng, Y. Huo, O. G. Schmidt, K. Yao, Y. Liu, M. Helm, Nano Lett. 15, 1057 (2015)

Keywords: Scattering near-field optical microscopy; s-snom; superlens; GaAs; sub-diffraction-limited

Related publications

  • Lecture (Conference)
    Quantum Structured Infrared Photodetector International Conference (QSIP 2016), 12.-17.06.2016, Tel Aviv, Israel

Permalink: https://www.hzdr.de/publications/Publ-24030
Publ.-Id: 24030


The South Um Mongul Cu-Mo-Au prospect in the Eastern Desert of Egypt: From a mid-Cryogenian continental arc to Ediacaran post-collisional appinite-high Ba-Sr monzogranite

Abd El-Rahman, Y.; Gutzmer, J.; Said, A.; Hofmann, M.; Gärtner, M.; Linnemann, U.

The South Um Mongul prospect is a Cu-Mo-Au porphyry system. It is covered by porphyritic dacite and hornblende gabbro. Both units are intruded by monzogranite, which encloses xenoliths of both units. Using LA-ICP-MS U-Pb zircon method, the dacite is dated at ca. 773 ± 6.9 Ma, while the gabbro and the monzogranite are dated at 603 ± 3.5 and 558 ± 4.6 Ma, respectively. The dacite age is consistent with the mid-Cryogenian subduction-related magmatic stage and the gabbro-monzogranite age is comparable to the Ediacaran post-collisional magmatic stage during the evolution of the Arabian-Nubian Shield. The dacite is akin to high-K I-type granitoids and its primitive mantle-normalized trace element patterns show negative Nb anomalies and enrichment in LILE (large ion lithophile elements), Th and U over HFSE. These geochemical characteristics are similar to those of felsic magma formed in a subduction-related tectonic setting. The high La/Ybcn (7.2–30.9), Nb/Yb (2.63–4.41) and Th/Yb (2.07–3.04) ratios of the dacite are comparable to continental rather than oceanic arc systems. Its low Sm/Yb ratios (1.84–3.13) support the primitive nature of the crust beneath the continental arc and derivation from a garnet-free lower crustal source. The dacite has low Sr/Y ratios (5–9) and its Eu/Eu⁎ ratios range from 0.66 to 0.83. Similar to dacite, the primitive mantle-normalized trace element patterns of the post-collisional suite show a subduction-related geochemical signature. However, the gabbro is characterized by Th/Ta ratios (3.4–14.8), which are comparable with the within-plate tectonic setting. The subduction-related geochemical signature is inherited from long subduction history beneath the Arabian-Nubian Shield. Both the gabbro and monzogranite are characterized by high Ba (404–590 ppm and 936–1590 ppm, respectively) and Sr (611–708 ppm and 624–793 ppm, respectively) contents, which make them analogous to the Caledonian appinite-high Ba-Sr granite assemblage. The formation of these rocks is related to the Ediacaran lithospheric erosion accompanying slab break-off. This process induced asthenospheric upwelling, which led to partial melting of the lithosphere previously metasomatised by subducted sediments involving carbonates impregnated by hydrothermal barite. Melting of this lithosphere led to the formation of the hornblende gabbro. Underplating by the mafic magma led to melting of the lower crust and the formation of high Ba-Sr monzogranite in the area. The high Sm/Yb (2.94–4.19) and Sr/Y (52–74) ratios of the monzogranite may indicate the presence of garnet in the melted amphibolitic lower crust. The higher Sr/Y ratios, lower HFSE (high field strength elements) contents and the absence of pronounced Eu anomalies in monzogranite relative to dacite suggest the productive nature of the post-collisional magma relative to the continental arc magma in this prospect.

Keywords: Appinite; Arabian-Nubian Shield; Continental arc; High Ba-Sr granite; Neoproterozoic; Post-collisional porphyry copper

Permalink: https://www.hzdr.de/publications/Publ-24029
Publ.-Id: 24029


Long-term diffusion of U(VI) in bentonite: Dependence on density

Joseph, C.; Mibus, J.; Trepte, P.; Müller, C.; Brendler, V.; Park, D. M.; Jiao, Y.; Kersting, A. B.; Zavarin, M.

As contribution to the safety assessment of nuclear waste repositories, U(VI) diffusion through the potential buffer material MX-80 bentonite was investigated at three clay dry densities over 6 years. Synthetic MX 80 model pore water was used as background electrolyte. Speciation calculations showed that Ca2UO2(CO3)3(aq) was the main U(VI) species. The in- and out-diffusion of U(VI) was investigated separately. U(VI) diffused about 3 mm, 1.5 mm, and 1 mm into the clay plug at ρ = 1.3, 1.6, and 1.9 g/cm3, respectively. No through-diffusion of the U(VI) tracer was observed. However, leaching of natural uranium contained in the clay occurred and uranium was detected in all receiving reservoirs. As expected, the effective and apparent diffusion coefficient, De and Da, decreased with increasing dry density. The Da values for the out-diffusion of natural U(VI) were in good agreement with previously determined values. Surprisingly, Da values for the in-diffusion of U(VI) were about two orders of magnitude lower than values obtained in short-term in-diffusion experiments reported in the literature. As potential reasons for this behavior, changes of the U(VI) speciation within the clay (precipitation, reduction) or changes of the clay porosity and pore connectivity with time were evaluated. By application of Archie’s law and extended Archie’s law, it was estimated that a significantly smaller effective porosity must be present for the long-term in-diffusion of U(VI). The results suggest that long-term studies of key transport phenomena may reveal additional processes that can directly impact long-term repository safety assessments.

Keywords: nuclear waste repository; MX-80; clay; uranium; speciation; extended Archie’s law

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Permalink: https://www.hzdr.de/publications/Publ-24028
Publ.-Id: 24028


The effect of microstructural heterogeneity on pore size distribution and permeability in Opalinus Clay (Mont Terri, CH): insights from an integrated study of laboratory fluid flow and pore morphology from BIB-SEM images

Philipp, T.; Amann-Hildenbrand, A.; Laurich, B.; Desbois, G.; Littke, R.; Urai, J. L.

Opalinus Clay (OPA) is considered as potential host rock for the deep-geological disposal of radioactive waste. One key-parameter in long-term storage prediction is permeability. In this study we investigated microstructural controls on permeability for the different facies of OPA. Permeability and porosity were determined under controlled pressure conditions. In addition, the pore space was investigated by SEM, using high quality surfaces prepared by Broad Ion Beam milling (BIB). Water permeability coefficients range from 1.6×10-21 to 5.6×10 20 m². Helium pycnometer porosities range between ~21% and ~12%. The sample with the highest helium porosity (shaly facies) is characterized by the lowest permeability, and vice versa (carbonate-rich sandy facies). This inverse behavior deviates from the generally reported trend of increasing permeability with increasing porosity, indicating that parameters other than porosity affect permeability. Visible porosities from SEM images revealed that 67-95% of the total porosity resides within pores smaller than the SEM detection limit. Pore sizes follow a power law distribution with characteristic power law exponents (D), strongly differing among the facies. The carbonate-rich sandy facies contains a network of much larger pores (D(shaly)~2.4, D(carbonate-rich)~2.0), because of the presence of load-supporting sand grains that locally prevent clay compaction, being responsible for a higher permeability.

Keywords: Opalinus Clay; permeability; porosity; BIB-SEM; microstructure; pore size distribution

Permalink: https://www.hzdr.de/publications/Publ-24027
Publ.-Id: 24027


The asphericity of the metabolic tumour volume in NSCLC: correlation with histopathology and molecular markers

Apostolova, I.; Ego, K.; Steffen, I. G.; Buchert, R.; Wertzel, H.; Achenbach, J.; Riedel, S.; Schreiber, J.; Schultz, M.; Furth, C.; Derlin, T.; Amthauer, H.; Hofheinz, F.; Kalinski, T.

Purpose

Asphericity (ASP) is a tumour shape descriptor based on the PET image. It quantitates the deviation from spherical of the shape of the metabolic tumour volume (MTV). In order to identify its biological correlates, we investigated the relationship between ASP and clinically relevant histopathological and molecular signatures in non-small-cell lung cancer (NSCLC).

Methods

The study included 83 consecutive patients (18 women, aged 66.4 ± 8.9 years) with newly diagnosed NSCLC in whom PET/CT with 18F-FDG had been performed prior to therapy. Primary tumour resection specimens and core biopsies were used for basic histopathology and determination of the Ki-67 proliferation index. EGFR status, VEGF, p53 and ALK expression were obtained in a subgroup of 44 patients. The FDG PET images of the primary tumours were delineated using an automatic algorithm based on adaptive thresholding taking into account local background. In addition to ASP, SUVmax, MTV and some further descriptors of shape and intratumour heterogeneity were assessed as semiquantitative PET measures.

Results

SUVmax, MTV and ASP were associated with pathological T stage (Kruskal-Wallis, p = 0.001, p < 0.0005 and p < 0.0005, respectively) and N stage (p = 0.017, p = 0.003 and p = 0.002, respectively). Only ASP was associated with M stage (p = 0.026). SUVmax, MTV and ASP were correlated with Ki-67 index (Spearman’s rho = 0.326/p = 0.003, rho = 0.302/p = 0.006 and rho = 0.271/p = 0.015, respectively). The latter correlations were considerably stronger in adenocarcinomas than in squamous cell carcinomas. ASP, but not SUVmax or MTV, showed a tendency for a significant association with the extent of VEGF expression (p = 0.058). In multivariate Cox regression analysis, ASP (p < 0.0005) and the presence of distant metastases (p = 0.023) were significantly associated with progression-free survival. ASP (p = 0.006), the presence of distant metastases (p = 0.010), and Ki-67 index (p = 0.062) were significantly associated with overall survival.

Conclusion

The ASP of primary NSCLCs on FDG PET images is associated with tumour dimensions and molecular markers of proliferation and angiogenesis.

Keywords: Non-small cell lung cancer; FDG PET/CT; Asphericity; Intratumour heterogeneity; Histopathology; Molecular markers

Permalink: https://www.hzdr.de/publications/Publ-24026
Publ.-Id: 24026


Dynamics of nonequilibrium electrons on neutral center states of interstitial magnesium donors in silicon

Pavlov, S. G.; Deßmann, N.; Pohl, A.; Shuman, V. B.; Portsel, L. М.; Lodygin, А. N.; Astrov, Y. A.; Winnerl, S.; Schneider, H.; Stavrias, N.; van der Meer, A. F. G.; Tsyplenkov, V. V.; Kovalesky, K. A.; Zhukavin, R. K.; Shastin, V. N.; Abrosimov, N. V.; Hübers, H.-W.

Subnanosecond dynamics of optically excited electrons bound to excited states of neutral magnesium donor centers in silicon has been investigated. Lifetimes of nonequilibrium electrons have been derived from the decay of the differential transmission at photon energies matching the intracenter and the impurity–to–conduction band transitions. In contrast to hydrogen-like shallow donors in silicon, significantly longer lifetimes have been observed. This indicates weaker two-phonon and off-resonant interactions dominate the relaxation processes in contrast to the single-intervalley-phonon assisted impurity-phonon interactions in the case of shallow donors in silicon.

Keywords: Extrinsic semiconductors; dynamics of electrons from impurities; magnesium doping of silicon

Related publications

Permalink: https://www.hzdr.de/publications/Publ-24025
Publ.-Id: 24025


An Evaluation of Hydroxamate Collectors for Malachite Flotation

Marion, C.; Jordens, A.; Li, R.; Rudolph, M.; Waters, K. E.

Copper oxide minerals, such as malachite, do not often respond well to traditional copper sulphide collectors, and require alternative flotation schemes. Hydroxamic acid collectors have been suggested as a means to directly float malachite, however, there is limited information on the effect of reagent structure on the performance of these collectors. This paper investigates the effect of five alkyl hydroxamates and two aromatic hydroxamates on the flotation of a synthetic ore composed of malachite and quartz. Zeta potential measurements were used to aid in understanding reagent adsorption onto the surface of the two minerals. The collectors were then evaluated using bench scale flotation results. While zeta potential measurements suggested that all the collectors investigated selectively adsorb onto the surface of malachite, only benzohydroxamic acid and C8 ¬alkyl hydroxamates were effective collectors in the flotation of malachite. Benzohydroxamic acid was the most selective, however, significantly lower dosages of C8¬ alkyl hydroxamates were required to obtain similar malachite recoveries, with minimal increases in quartz recovery. Benzo and octylhydroxamic acid were further examined for the flotation of fine (-38 µm) particles. For fine particle flotation experiments the effect of temperature was also investigated as a means to improve the flotation performance.

Keywords: Hydroxamates; Malachite; Flotation; Surface Chemistry

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Permalink: https://www.hzdr.de/publications/Publ-24024
Publ.-Id: 24024


Volumetrical Laser Ion Acceleration of Spherical Mass Limited Solid Density Targets

Huebl, A.; Hilz, P.; Schreiber, J.; Kluge, T.; Widera, R.; Bussmann, M.

Invited presentation at the LMU group of Jörg Schreiber about the results of the large scale 3D3V simulations for their experiments.

Keywords: Mass Limited Target; Paul Trap; PIConGPU; Simulation; 3D3V; GPGPU; OpenSource

  • Invited lecture (Conferences)
    LMU/MPI QO Munich: Prof. Schreiber Group Meeting (Laser-driven ion acceleration), 18.-20.07.2016, München, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-24023
Publ.-Id: 24023


Scalable and Modular Online Data Processing for Ultrafast Computed Tomography Using CUDA Pipelines

Frust, T.; Juckeland, G.; Bieberle, A.

For investigations of rapidly moving structures in opaque technical devices ultrafast electron beam X-ray computed tomography (CT) scanners are available at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR). Currently, CT data must be downloaded initially after each CT scan from the scanner to a data processing machine. Afterwards, cross-sectional images are reconstructed.
This limits the application fields of the scanners. For on-line observations and even automated process control of scanned objects a new modular data processing tool is presented consisting of user-definable pipeline stages that work independently together in a so called data processing pipeline that can keep up with the frame rate of up to 8 kHz. The stages are arbitrarily programmable and combinable and are connected by a fast custom memory pool to optimize data transfer processes. As a result, this processing structure is not limited to CT application only. In order to achieve highest processing performances for the electron beam CT scanners all relevant data processing steps are individually implemented in separate stages using graphic processing units (GPUs) and NVIDIA's CUDA programming language. Data processing performance tests on two different high-end GPUs (Tesla K20c, GeForce GTX 1080) offer a slice image reconstruction performance that is well-suited for the required on-line application.

Keywords: Electron beam X-ray computed tomography; CUDA; data pipeline; real-time processing; in-situ visualization

  • Contribution to proceedings
    ISAV 2016: In Situ Infrastructures for Enabling Extreme-scale Analysis and Visualization, 13.11.2016, Salt Lake City, Utah, USA
    Proceedings of ISAV 2016
    DOI: 10.1109/ISAV.2016.007
  • Lecture (Conference)
    ISAV 2016: In Situ Infrastructures for Enabling Extreme-scale Analysis and Visualization, 13.11.2016, Salt Lake City, Utah, USA

Permalink: https://www.hzdr.de/publications/Publ-24022
Publ.-Id: 24022


Trivalent f-elements in human saliva: A comprehensive speciation study by time-resolved laser-induced fluorescence spectroscopy and thermodynamic calculations

Barkleit, A.; Wilke, C.; Heller, A.; Stumpf, T.; Ikeda-Ohno, A.

In the case of oral ingestion of radioactive contaminants, the first contact medium is saliva in the mouth. To gain a first insight into the interaction of radioactive contaminants in human saliva, the speciation of curium (Cm(III)) and europium (Eu(III)), i.e., trivalent f-elements, was investigated in different salivary media with time-resolved laser-induced fluorescence spectroscopy (TRLFS). The results indicate that these metal cations are primarily complexed with carbonates and phosphates, forming the ternary complexes with a possible stoichiometry of 1:1:2 (M(III) : carbonate : phosphate). For charge compensation, calcium is also involved in these ternary complexes. In addition to these inorganic components, organic substances, namely α-amylase, show a significant contribution to the speciation of the trivalent f-elements in saliva. This protein is the major enzyme in saliva and catalyzes the hydrolysis of polysaccharides. In this context, the effect of Eu(III) on the activity of α-amylase was investigated to reveal the potential implication of these metal cations for the in vivo functions of saliva. The results indicate that the enzyme activity is strongly inhibited by the presence of Eu(III), which is suppressed by an excess of calcium.

Keywords: Actinides; lanthanides; curium; europium; speciation; body fluids; fluorescence spectroscopy

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Permalink: https://www.hzdr.de/publications/Publ-24021
Publ.-Id: 24021


Test of Lorentz invariance in β decay of polarized 20Na

Sytema, A.; van den Berg, J. E.; Böll, O.; Chernowitz, D.; Dijck, E. A.; Grasdijk, J. O.; Hoekstra, S.; Jungmann, K.; Mathavan, S. C.; Meinema, C.; Mohanty, A.; Müller, S. E.; Noordmans, J. P.; Nunez Portela, M.; Onderwater, C. J. G.; Pijpker, C.; Timmermans, R. G. E.; Vos, K. K.; Willmann, L.; Wilschut, H. W.

Background: Lorentz invariance is key in our understanding of nature, yet relatively few experiments have tested Lorentz invariance in weak interactions.

Purpose: Our goal is to obtain limits on Lorentz-invariance violation in weak interactions, in particular rotational invariance in β decay.

Method: We search for a dependence of the lifetime of 20Na nuclei on the nuclear spin direction. Such directional dependence would be evidence for Lorentz-invariance violation in weak interactions. A difference in lifetime between nuclei that are polarized in the east and west direction is searched for. This difference is maximally sensitive to the rotation of the Earth, while the sidereal dependence is free from most systematic errors.

Results: The experiment sets a limit of 2×10-4 at 90% C.L. on the amplitude of the sidereal variation of the relative lifetime differences, an improvement by a factor 15 compared to an earlier result.

Conclusions: No significant violation of Lorentz invariance is found. The result sets limits on parameters of theories describing Lorentz-invariance violation.

Keywords: Lorentz violation; beta-decay

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Permalink: https://www.hzdr.de/publications/Publ-24020
Publ.-Id: 24020


Fractionated irradiation influences uptake of near-infrared-labeled Cetuximab: preliminaries on combination with radioimmunotherapy

Dietrich, A.; Koi, L.; Severin, J.; Baumann, M.; Krause, M.

External beam irradiation (EBRT) can precisely target the solid tumor mass but is limited by the surrounding normal tissue. Radioimmunotherapy mediates additional internal irradiation with the potential to strike also distant metastases. The combination of internal and external radiotherapy (CIERT) is a promising treatment strategy as it potentially combines the advantages of both modalities without increasing toxicity. In addition, patients could be stratified via a corresponding PET-tracer (1). We previously showed that CIERT using Y-90-Cetuximab (Y-90-Cet) massively increased tumor control probability compared to EBRT alone in a head and neck squamous cell carcinoma xenograft model (2). In the presented project, we investigated CIERT using clinical relevant fractionated EBRT with 30 fractions (fx) over 6 weeks. To study the best application timing, subcutaneous xenograft bearing mice were intravenously injected with near-infrared-labeled Cetuximab (NIR-Cet) at different time points during fxEBRT to model Y-90-Cet uptake. In addition, different dose groups were used for fxEBRT. NIR-Cet uptake was longitudinally followed by in-vivo optical imaging. Signal intensity was highest at day 3-4 post-injection in controls and was not altered by subsequent fxEBRT. In contrast, tumor uptake of NIR-Cet was increased if applied during fxEBRT. From these results, we concluded that low to moderate doses of fxEBRT can enhance Cet uptake but the effect is diminished if a certain threshold dose is exceeded. The interdependency of the total dose and the injection timing is not linearly and needs to be studied in more detail. However, based on the preliminary data, we injected Y-90-Cet after 10 fx of EBRT in ongoing CIERT tumor control probability experiments.

(1) Dietrich et al. Br J Radiol. 2015 Jul;88(1051):20150042
(2) Koi et al. Radiother Oncol. 2014 Feb;110(2):362-9.

  • Contribution to proceedings
    DKTK Retreat in Heidelberg, 11.-12.10.2016, Heidelberg, Deutschland
    Proceedings of DKTK Retreat

Permalink: https://www.hzdr.de/publications/Publ-24019
Publ.-Id: 24019


Laser proton acceleration from liquid crystal films of different thicknesses with ultra-high laser contrast

Obst, L.; Poole, P.; Metzkes, J.; Zeil, K.; Cochran, G.; Kluge, T.; Schlenvoigt, H.-P.; Kraft, S.; Prencipe, I.; Rehwald, M.; Schumacher, D.; Schramm, U.

We present results of our experimental campaign on laser proton acceleration, in which liquid crystal film targets of tunable thickness were irradiated with plasma mirror cleaned laser pulses. The data show a significant increase in proton cut-off energy up to 25 MeV for a target thickness of 10 nm as compared to the few- micron scale reference for this target configuration yielding roughly 12 MeV.

The performance of laser based ion acceleration strongly depends on the laser temporal contrast and its effect on the target plasma scale length. Plasma mirror setups have proven to be a valuable tool to improve the temporal contrast by several orders of magnitude, reducing the intensity of pre-pulses that emanate from the laser chain and steepening the rising edge of the main laser pulse. We present recent results obtained at the Titanium Sapphire laser system Draco, delivering 30 fs long laser pulses at an intensity exceeding 10^20 W/cm^2. Our recently commissioned single plasma mirror improves the contrast by four orders of magnitude while reflecting 80% of the initial pulse energy. Its influence on the laser proton acceleration process was studied in a campaign in collaboration with the High Energy Density Physics Group of Ohio State University using their tunable liquid crystal film target source. This device allows an on-demand variation of the target thickness from tens of micrometers down to 10 nm while keeping the target composition constant. The target was positioned under 45 degrees with respect to the incoming laser beam while accelerated protons and ions were monitored in both laser- and target normal direction by means of Thomson Parabolas and Radiochromic Film stacks. Hence, being sensitive to the identification of acceleration regimes beyond the well-known Target Normal Sheath Acceleration, preliminary results display a significant increase in proton cut-off energy when reaching thin targets. Up to 25 MeV could be observed for an optimum target thickness of 10 nm as compared to the few- micron scale reference for this target configuration yielding roughly 12 MeV.

Keywords: laser-driven proton acceleration; high-intensity lasers

  • Lecture (Conference)
    Advanced Accelerator Concepts Workshop 2016, 2.8.2016, National Harbor, Maryland, USA

Permalink: https://www.hzdr.de/publications/Publ-24018
Publ.-Id: 24018


Superconductivity in Weyl semimetal candidate MoTe2

Qi, Y.; Naumov, P. G.; Ali, M. N.; Rajamathi, C. R.; Schelle, W.; Barkalov, O.; Hanfland, M.; Wu, S.-C.; Shekhar, C.; Sun, Y.; Süß, V.; Schmidt, M.; Schwarz, U.; Pippel, E.; Werner, P.; Hillebrand, R.; Förster, T.; Kampert, E.; Parkin, S.; Cava, R. J.; Felser, C.; Yan, B.; Medvedev, S. A.

Transition metal dichalcogenides have attracted research interest over the last few decades due to their interesting structural chemistry, unusual electronic properties, rich intercalation chemistry and wide spectrum of potential applications. Despite the fact that the majority of related research focuses on semiconducting transition-metal dichalcogenides (for example, MoS2), recently discovered unexpected properties of WTe2 are provoking strong interest in semimetallic transition metal dichalcogenides featuring large magnetoresistance, pressure-driven superconductivity and Weyl semimetal states. We investigate the sister compound of WTe2, MoTe2, predicted to be a Weyl semimetal and a quantum spin Hall insulator in bulk and monolayer form, respectively. We find that bulk MoTe2 exhibits superconductivity with a transition temperature of 0.10 K. Application of external pressure dramatically enhances the transition temperature up to maximum value of 8.2 K at 11.7 GPa. The observed dome-shaped superconductivity phase diagram provides insights into the interplay between superconductivity and topological physics.

Permalink: https://www.hzdr.de/publications/Publ-24017
Publ.-Id: 24017


Commensurate and incommensurate magnetic order in spin-1 chains stacked on the triangular lattice in Li2NiW2O8

Ranjith, K. M.; Nath, R.; Majumder, M.; Kasinathan, D.; Skoulatos, M.; Keller, L.; Skourski, Y.; Baenitz, M.; Tsirlin, A. A.

We report the thermodynamic properties, magnetic ground state, and microscopic magnetic model of the spin-1 frustrated antiferromagnet Li2NiW2O8, showing successive transitions at TN1 similar or equal to 18 K and TN2 similar or equal to 12.5 K in zero field. Nuclear magnetic resonance and neutron diffraction reveal collinear and commensurate magnetic order with the propagation vector k = (1/2,0,1/2) below TN2. The ordered moment of 1.8 µB at 1.5 K is directed along [0.89(9), - 0.10(5), - 0.49(6)] and matches the magnetic easy axis of spin-1 Ni2+ ions, which is determined by the scissor-like distortion of the NiO6 octahedra. Incommensurate magnetic order, presumably of spin-density-wave type, is observed in the region between TN2 and TN1. Density-functional band-structure calculations put forward a three-dimensional spin lattice with spin-1 chains running along the [01-1] direction and stacked on a spatially anisotropic triangular lattice in the ab plane. We show that the collinear magnetic order in Li2NiW2O8 is incompatible with the triangular lattice geometry and thus driven by a pronounced easy-axis single-ion anisotropy of Ni2+.

Permalink: https://www.hzdr.de/publications/Publ-24016
Publ.-Id: 24016


Spin transport in tantalum studied using magnetic single and double layers

Montoya, E.; Omelchenko, P.; Coutts, C.; Lee-Hone, N. R.; Hübner, R.; Broun, D.; Heinrich, B.; Girt, E.

We report on spin transport in sputter-grown Ta films measured by ferromagnetic resonance. Spin diffusion length and spin mixing conductance are determined from magnetic damping measurements for a varying thickness of Ta layer 0 <= dTa <= 10 nm. The different boundary conditions of single- and double-magnetic-layer heterostructures Py|Ta and Py|Ta|[Py|Fe] allow us to significantly narrow down the parameter space and test various models.We showt hat a common approach of using bulk resistivity value in the analysis yields inconsistent spin diffusion length and spin mixing conductance values for magnetic single- and double-layer structures. X-ray diffraction shows that bulk Ta is a combination of β-Ta and bcc-Ta. However, in the region of significant spin transport, <~ 2 nm, there is an intermediate region of growth where the Ta lacks long-range structural order, as observed by transmission electron microscopy. Thickness-dependent resistivity measurements confirm that the bulk and intermediate regions have significantly different resistivity values. We find that the data can be well represented if the intermediate region resistivity value is used in the analysis. Additionally, the data can be fit if resistivity has the measured thickness dependence and spin diffusion length is restricted to be inversely proportional to resistivity. Finally, we rule out a model in which spin diffusion length is a constant, while the resistivity has the measured thickness dependence.

Related publications

  • Physical Review B 94(2016), 054416

Permalink: https://www.hzdr.de/publications/Publ-24015
Publ.-Id: 24015


TEM investigation of barrier-like anodic oxide films on aluminum

Schneider, M.; Lämmel, C.; Hübner, R.; Gierth, U.; Michaelis, A.

The present study focuses mainly on non-electrochemical investigation of thin barrier-like oxide films formed under different pulse frequencies. The TEM investigation principally shows amorphous oxide films, which are dense and free of pores. The various pulse experiments have no influence on these film properties. The oxide growth factor was calculated to 1.06 nmV-1 in all cases. The microstructure (crystallographic orientation, grain boundaries) of the underlying substrate does not affect the oxide films. Independent of the pulse frequency, electrolyte species are not incorporated into the oxide films. The evidenced differences in the filmthickness are caused by intrinsic peculiarities of the high-field mechanism of growing oxide.

Keywords: pulse anodizing; high field mechanism; anodic oxide; aluminum

Related publications

  • Surface and Interface Analysis 48(2016), 906-912

Permalink: https://www.hzdr.de/publications/Publ-24014
Publ.-Id: 24014


Who will benefit most from hydrogel rectum spacer implantation in prostate cancer radiotherapy? A model-based approach for patient selection

Vanneste, B. G. L.; Hoffmann, A. L.; van Lin, E. N.; van de Voorde, L.; Pinkawa, M.; Lambin, P.

Background and Purpose
Previous studies confirmed that implantable rectum spacers (IRS) decreased acute gastro-intestinal (GI) toxicity in a significant percentage of prostate cancer patients undergoing intensity modulated radiation therapy (IMRT). We developed decision rules based on clinical risk factors (CRFs) to select those patients who are expected to benefit most from IRS implantation.

Materials and Methods
For 26 patients dose distributions with (IMRT+IRS) and without (IMRT-IRS) IRS were calculated. Validated nomograms based on CRFs and dosimetric criteria (anorectal V40Gy and V75Gy) were used to predict probabilities for grade 2-3 (G2-3) acute GI toxicity, G2-3 late rectal bleeding (LRB), G3 LRB, and G2-3 fecal incontinence (FI) for IMRT+IRS and IMRT-IRS. All permutations of CRFs were generated to identify most benefit scenarios (MBS) in which a predicted toxicity reduction of ≥5% points in ≥25% of the cohort was present due to IRS implantation.

Results
IMRT+IRS revealed a significant reduction in V40Gy (p = 0.0357) and V75Gy (p < 0.0001) relative to IMRT-IRS. For G2-3 acute GI toxicity and G2-3 LRB, the predicted toxicity rates decreased in 17/26 (65%) and 20/26 (77%) patients, and decision rules were derived for 22/32 (69%) and 12/64 (19%) MBS, respectively. From the decision rules, it follows that diabetes status has no impact on G2-3 acute toxicity, and in absence of pre-RT abdominal surgery, the implantation of an IRS is predicted to show no clinically relevant benefit for G2-3 LRB.

Conclusions
Prostate cancer patients who are expected to benefit most from IRS implantation can be identified prior to IMRT based on their CRFs profile.

Keywords: Prostate cancer; Radiotherapy; Rectum spacer; Patient selection; Toxicity prediction

Permalink: https://www.hzdr.de/publications/Publ-24013
Publ.-Id: 24013


Measuring error estimation of the ultrasound array flow mapping system by means of numerical simulations

Franke, S.; Eckert, S.

A new two-dimensional ultrasound Doppler flow mapping system based on the application of linear arrays has been developed recently. A main feature involves a multi-beam operation facilitating a high frame rate.
Previously, the effect of crosstalk between the beams was investigated in a rotational flow by comparing the results of multi- and single-beam operation with each other. However, due to slight variations in the flow conditions and the scattering particle distribution the determined systematic error of measurement was not very reliable. Likewise, flow phantoms suffer from a number of shortcomings as fluctuations of rotational speed of the phantom drive or inadequate parameters of scattering particles. For this reason, we developed a numerical model of our flow mapping system providing the echo signals of the particle motion in a model flow being similar to our typical small scale experiments. For each particle the scattering signal is calculated by solving the Rayleigh integral by means of systems theory and summed to the total echo signal. This task was performed by the FieldII toolbox for MATLAB. In our paper we will present a detailed analysis of the systematic error depending on the flow structure. The error of the multi-beam mode in comparison to the single beam operation will be estimated.

Keywords: Ultrasound array; flow mapping; numerical simulation of ultrasound systems; FIELD II

  • Lecture (Conference)
    10th International Symposium on Ultrasonic Doppler Methods for Fluid Mechanics and Fluid Engineering (ISUD 10), 28.-30.09.2016, Tokyo, Japan
  • Contribution to proceedings
    10th International Symposium on Ultrasonic Doppler Methods for Fluid Mechanics and Fluid Engineering (ISUD 10), 28.-30.09.2016, Tokyo, Japan

Permalink: https://www.hzdr.de/publications/Publ-24011
Publ.-Id: 24011


Entwicklung, Synthese und biologische Evaluierung von 18F-markierten Imidazopyridotriazinderivaten zur molekularen Bildgebung der Phosphodiesterase 2A im Gehirn mittels Positronen-Emissions-Tomographie

Schröder, S.

Die Phosphodiesterase 2A (PDE2A) wird in bestimmten Hirnregionen exprimiert, die bei neuropsychiatrischen und neurodegenerativen Erkrankungen, wie Depressionen, Angstzuständen und der Alzheimerkrankheit, betroffen sind. Die Entwicklung eines spezifischen 18F-markierten PDE2A-Radioliganden würde die molekulare Bildgebung dieses Enzyms im Gehirn mittels Positronen-Emissions-Tomographie (PET) ermöglichen.
Basierend auf einer Imidazopyridotriazin-Leitstruktur wird in der vorliegenden Arbeit die mehrstufige Synthese von vier neuen, fluoralkylierten Derivaten beschrieben, deren inhibitorische Wirksamkeit für die PDE2A und die PDE10A in einem Enzym-Assay getestet wurde. Die potentesten und selektivsten PDE2A-Liganden wurden für eine 18F-Markierung ausgewählt und geeignete Vorläufermoleküle dargestellt. Basierend auf einer einstufigen, nukleophilen 18F-Radiomarkierung erfolgte die Synthese von drei neuen Radioliganden, deren Potential zur PET-Bildgebung der PDE2A im Gehirn untersucht wurde.
In-vitro-autoradiographische Untersuchungen an Rattenhirnschnitten zeigten für zwei 18F-markierte Derivate eine spezifische Aktivitätsverteilung, die mit dem immunhistochemisch nachgewiesenen Expressionsmuster der PDE2A übereinstimmt. In KleintierPET-Studien mit einem dieser Radioliganden wurde jedoch in vivo eine unspezifische Aktivitätsverteilung im Maushirn beobachtet, die auf eine Akkumulation von Radiometaboliten hindeutet. In-vivo-Stabilitätsuntersuchungen zeigten einen schnellen metabolischen Abbau der Radioliganden in Mäusen sowie die Bildung hirngängiger Radiometabolite. Demnach erfüllt keines der 18F-markierten Imidazopyridotriazinderivate die Voraussetzungen zur In-vivo-Bildgebung der PDE2A im Gehirn mittels PET.
In weiterführenden Arbeiten könnte die metabolische Stabilität der entwickelten PDE2A-Liganden durch strukturelle Modifikationen erhöht werden. Die inhibitorische Potenz und Selektivität für das PDE2A-Protein sowie die Hirngängigkeit der resultierenden Derivate wären zu prüfen.

Keywords: Phosphodiesterase (2A/10A); Imidazopyridotriazin; Selektivität; molekulare Bildgebung im Gehirn; Positronen-Emissions-Tomographie

  • Doctoral thesis
    Universität Leipzig, Fakultät für Chemie und Mineralogie, 2016
    Mentor: Prof. Dr. Christoph Schneider, Prof. Dr. Peter Brust
    210 Seiten

Permalink: https://www.hzdr.de/publications/Publ-24010
Publ.-Id: 24010


Theoretical prediction of mass transfer coefficients in both gas-liquid and slurry bubble columns

Nedeltchev, S.

The gas-liquid contact time has been defined in a new way (bubble surface-to-rate of surface formation) and the range of applicability of the penetration theory in both gas-liquid and slurry bubble columns has been examined. In both reactors, the mass transfer coefficients were predicted successfully not only in the homogeneous regime but also in the heterogeneous regime (superficial gas velocities up to 0.08 ms-1).
The results in the article demonstrate the importance of the geometrical characteristics (length and height) of the oblate ellipsoidal bubbles for the accurate calculation of the contact time and thus the volumetric liquid-phase mass transfer coefficient kLa. The gas-liquid interfacial area has been calculated in both reactors in the classical way, i.e. as a function of the gas holdup and inversely proportional to the Sauter-mean bubble diameter. It was found that in the gas-liquid bubble column (0.095 m in ID) the modified penetration theory was applicable to tap water, 9 organic liquids (decalin, nitrobenzene, 2-propanol, 1,4-dioxane, ethanol (99 %), tetralin, xylene, 1,2-dichloroethane, ethylene glycol) and two liquid mixtures (water-glycol and tetralin-ethanol). Tetralin was aerated with both nitrogen and helium, whereas xylene was aerated with hydrogen and helium. The correction factor introduced by Calderbank (1967) was found useful for improving the kLa predictions in 1,2-dichloroethane, ethanol (99 %), xylene(-hydrogen) and toluene-ethanol 97.2 %. In the case of a slurry bubble column, the new approach was found applicable (at low solids concentrations) to four different gas-liquid-solid systems: air-tetralin-Al2O3, air-water-Al2O3, air-water-activated carbon and air-Na2SO4-kieselguhr. It is noteworthy that in some cases (air-water-Al2O3) the new definition of the contact time was found applicable up to solids concentrations of 6.29 %. In the case of a slurry bubble column, it was found that when the theoretical kLa value is multiplied by the inverse value of the correction factor the predictions improve with about 5 %.
Finally, in the slurry bubble column the contact time was defined on the basis of the length of the micro-eddies and the kLa values in both air-water-alumina and air-water-activated carbon systems were successfully predicted. This is also a potentially good approach.

Keywords: New definition of contact time; Penetration theory applicability; Prediction of mass transfer coefficients; Organic liquids; Gas-liquid bubble columns; Slurry bubble columns

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Permalink: https://www.hzdr.de/publications/Publ-24009
Publ.-Id: 24009


Ab initio description of the thermoelectric properties of heterostructures in the diffusive limit of transport

Hinsche, N. F.; Rittweger, F.; Hölzer, M.; Zahn, P.; Ernst, A.; Mertig, I.

The scope of this review is to present the recent progress in the understanding of the microscopic origin of thermoelectric transport in semiconducting heterostructures and to identify and elucidate mechanisms which could lead to enhanced thermoelectric conversion efficiency. Based on first-principles calculations a consistent and convenient method is presented to fully describe the thermoelectric properties in the diffusive limit of transport for bulk systems and their associated heterostructures. While fundamentals of the functionality of phonon-blocking and electron-transmitting superlattices could be unveiled, we provide also distinct analysis and ideas for thermoelectric enhancement for two archetypical thermoelectric heterostructures based on inline image and Si/Ge. A focus was on the influence of bulk and interfacial strain, varying charge carrier concentration, temperature, and superlattice periods on the thermoelectric transport properties.

Keywords: super lattices; electronic structure; first principles; transport theory; Boltzmann theory; electric transport; heat transport; thermoelectric transport; uniaxial strain; biaxial strain

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Permalink: https://www.hzdr.de/publications/Publ-24008
Publ.-Id: 24008


Tests of a Compton imaging prototype in a monoenergetic 4.44 MeV photon field—a benchmark setup for prompt gamma-ray imaging devices

Golnik, C.; Bemmerer, D.; Enghardt, W.; Fiedler, F.; Hueso-González, F.; Pausch, G.; Römer, K.; Rohling, H.; Schöne, S.; Wagner, L.; Kormoll, T.

The finite range of a proton beam in tissue opens new vistas for the delivery of a highly conformal dose distribution in radiotherapy. However, the actual particle range, and therefore the accurate dose deposition, is sensitive to the tissue composition in the proton path. Range uncertainties, resulting from limited knowledge of this tissue composition or positioning errors, are accounted for in the form of safety margins. Thus, the unverified particle range constrains the principle benefit of proton therapy. Detecting prompt gamma-rays, a side product of proton-tissue interaction, aims at an on-line and non-invasive monitoring of the particle range, and therefore towards exploiting the potential of proton therapy. Compton imaging of the spatial prompt gamma-ray emission is a promising measurement approach. Prompt gamma-rays exhibit emission energies of several MeV. Hence, common radioactive sources cannot provide the energy range a prompt gamma-ray imaging device must be designed for. In this work a benchmark measurement-setup for the production of a localized, monoenergetic 4.44MeV gamma-ray source is introduced. At the Tandetron accelerator at the HZDR, the proton-capture resonance reaction 15N(p , alpha gamma4.439)12C is utilized. This reaction provides the same nuclear de-excitation (and gamma-ray emission) occurrent as an intense prompt gamma-ray line in proton therapy. The emission yield is quantitatively described. A two-stage Compton imaging device, dedicated for prompt gamma-ray imaging, is tested at the setup exemplarily. Besides successful imaging tests, the detection efficiency of the prototype at 4.44MeV is derived from the measured data. Combining this efficiency with the emission yield for prompt gamma-rays, the number of valid Compton events, induced by gamma-rays in the energy region around 4.44MeV, is estimated for the prototype being implemented in a therapeutic treatment scenario. As a consequence, the detection efficiency turns out to be a key parameter for prompt gamma-ray Compton imaging limiting the applicability of the prototype in its current realization.

Keywords: Comptonimaging; Dosimetryconceptsandapparatus; Imagereconstructioninmedicalimaging; Instrumentation for hadron therapy

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Permalink: https://www.hzdr.de/publications/Publ-24007
Publ.-Id: 24007


Experimental investigations of rotary electromagnetic mould stirring in continuous casting using a cold liquid metal model

Willers, B.; Barna, M.; Reiter, J.; Eckert, S.

This paper presents the experimental study of an electromagnetically stirred mould flow using a 1:3 scale acrylic glass model of the round bloom caster from voestalpine Stahl Donawitz GmbH. An electromagnetic stirrer was installed at the strand producing a rotating magnetic field (RMF). Flow measurements were performed in the eutectic alloy GaInSn at room temperature by means of the ultrasound Doppler velocimetry (UDV). Up to 10 ultrasonic transducers were employed simultaneously in order to obtain a two-dimensional reconstruction of the flow structure. The experiments contribute to a better understanding of electromagnetically stirred mould flows and provide an extensive and valuable data base for the validation of numerical methods. The flow measurements reveal a distinct influence of the secondary flow on the distribution of the angular velocity in various regions of the mould. The submerged jet intensifies this secondary motion in the upper part of the mould and thus causes a strong deformation of the free surface of the melt. The jet is deflected, bent and rotates around the strand axis.

Keywords: continuous round bloom casting; eutectic alloy GaInSn; experiments; electromagnetic stirring; rotating magnetic field; ultrasound Doppler flow measurements

Permalink: https://www.hzdr.de/publications/Publ-24006
Publ.-Id: 24006


Coulomb dissociation of N-20,N-21

Röder, M.; Adachi, T.; Aksyutina, Y.; Alcantara, J.; Altstadt, S.; Alvarez-Pol, H.; Ashwood, N.; Atar, L.; Aumann, T.; Avdeichikov, V.; Barr, M.; Beceiro, S.; Bemmerer, D.; Benlliure, J.; Bertulani, C.; Boretzky, K.; Borge, M.; Burgunder, G.; Caamano, M.; Caesar, C.; Casarejos, E.; Catford, W.; Cederkall, J.; Chakraborty, S.; Chartier, M.; Chulkov, L.; Cortina-Gil, D.; Crespo, R.; Pramanik, U.; Diaz-Fernandez, P.; Dillmann, I.; Elekes, Z.; Enders, J.; Ershova, O.; Estrade, A.; Farinon, F.; Fraile, L.; Freer, M.; Freudenberger, M.; Fynbo, H.; Galaviz, D.; Geissel, H.; Gernhauser, R.; Gobel, K.; Golubev, P.; Diaz, D.; Hagdahl, J.; Heftrich, T.; Heil, M.; Heine, M.; Heinz, A.; Henriques, A.; Holl, M.; Ickert, G.; Ignatov, A.; Jakobsson, B.; Johansson, H.; Jonson, B.; Kalantar-Nayestanaki, N.; Kanungo, R.; Kelic-Heil, A.; Knobel, R.; Kroll, T.; Krucken, R.; Kurcewicz, J.; Kurz, N.; Labiche, M.; Langer, C.; Le Bleis, T.; Lemmon, R.; Lepyoshkina, O.; Lindberg, S.; Machado, J.; Marganiec, J.; Caro, M.; Movsesyan, A.; Najafi, M.; Nilsson, T.; Nociforo, C.; Panin, V.; Paschalis, S.; Perea, A.; Petri, M.; Pietri, S.; Plag, R.; Prochazka, A.; Rahaman, M.; Rastrepina, G.; Reifarth, R.; Ribeiro, G.; Ricciardi, M.; Rigollet, C.; Riisager, K.; Rossi, D.; Saez, J.; Savran, D.; Scheit, H.; Simon, H.; Sorlin, O.; Stoica, V.; Streicher, B.; Taylor, J.; Tengblad, O.; Terashima, S.; Thies, R.; Togano, Y.; Uberseder, E.; van de Walle, J.; Velho, P.; Volkov, V.; Wagner, A.; Wamers, F.; Weick, H.; Weigand, M.; Wheldon, C.; Wilson, G.; Wimmer, C.; Winfield, J.; Woods, P.; Yakorev, D.; Zhukov, M.; Zilges, A.; Zuber, K.

Neutron-rich light nuclei and their reactions play an important role in the creation of chemical elements. Here, data from a Coulomb dissociation experiment on N-20,N-21 are reported. Relativistic
N-20,N-21 ions impinged on a lead target and the Coulomb dissociation cross section was determined in a kinematically complete experiment.
Using the detailed balance theorem, the N-19(n,gamma)N-20 and
N-20(n,gamma)N-21 excitation functions and thermonuclear reaction rates have been determined. The N-19(n,gamma)N-20 rate is up to a factor of 5 higher at T < 1 GK with respect to previous theoretical calculations, leading to a 10% decrease in the predicted fluorine abundance.

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Permalink: https://www.hzdr.de/publications/Publ-24005
Publ.-Id: 24005


Transversal Kerr effect of In1− x Mn x As layers prepared by ion implantation followed by pulsed laser annealing

Gan'Shina, E.; Golik, L.; Kun'Kova, Z.; Bykov, I.; Novikov, A.; Rukovishnikov, A.; Yuan, Y.; Zykov, G.; Böttger, R.; Zhou, S.

In1− x Mn x As (x = 6.9%) layers prepared by ion implantation and subsequent pulsed laser annealing have been studied using the magnetooptical transversal Kerr effect (TKE) and spectral ellipsometry. Ellipsometry data reveal the good crystal quality of the layers. The samples show ferromagnetic behaviour below 77 K. Near the absorption edge of the parent InAs semiconductor, large TKE values are observed. In the energy regions of the transitions in the Γ and L critical points of the InAs Brillouin zone, there are several clearly defined structures in the low-temperature TKE spectra. We have calculated the spectral dependences of the diagonal and nondiagonal components of the permittivity tensor (PT), as well as the spectrum of magnetic circular dichroism (MCD) for our samples. A number of extrema in the obtained MCD and PT spectra are close to the energies of transitions in the critical points of the parent semiconductor band structure, which confirms the intrinsic ferromagnetism of the Mn-doped InAs layers.

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Permalink: https://www.hzdr.de/publications/Publ-24004
Publ.-Id: 24004


Magnetocaloric Effect with Very Small Magnetic Hysteresis Losses of CoMn1-xTixGe Alloys

Yildirim, O.; Tozkoparan, O.; Yuzuak, E.; Elerman, Y.; Dincer, I.

The effects of Ti substitution for Mn and heat treatment on structural, magnetic and magnetocaloric properties of CoMnGe alloy have been investigated by electron microscopy, X-ray diffraction, calorimetric and magnetic measurements. According to X-ray diffraction measurements, the CoMn1-xTixGe alloys are in a single phase, hexagonal structure at room temperature. It is found that the as-cast CoMn0:95Ti0:05Ge alloy shows a magnetostructural phase transition close to room temperature. The transition shows a large magnetic entropy change and a small hysteresis in the isothermal magnetic field dependent magnetization measurements. Upon annealing, the transition temperature decreases slightly. The decrease in temperature is accompanied by a significant increase in the magnetic entropy change, i.e., magnetic entropy change at 1T field change was increased from -3.3 J/Kg.K to -6.3 J/Kg.K. Moreover, after annealing, hysteresis losses reduced significantly for delH=7 T. Accordingly, we report that the heat treatment has a significant effect on magnetocaloric properties of the CoMn0:95Ti0:05Ge alloy.

Keywords: giant magnetocaloric effect; hysteresis losses

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Permalink: https://www.hzdr.de/publications/Publ-24003
Publ.-Id: 24003


Thermodynamics data of valuable elements relevant to e-waste processing through primary and secondary copper production: a review

Shuva, M. A. H.; Rhamdhani, M. A.; Brooks, G. A.; Masood, S.; Reuter, M. A.

Waste of electronics and electrical equipment (WEEE or e-waste) can be viewed as a resource for metals, as it does not only contain the common metals like iron (Fe), aluminium (Al), lead (Pb) and copper (Cu) but also traces of precious and rare elements such as gold (Au), silver (Ag), tin (Sn), selenium (Se), tellurium (Te), platinum (Pt), palladium (Pd), tantalum (Ta), cobalt (Co) and indium (In). The recovery of these trace elements is vital, not just because it has high commercial values, but also for resources efficiency. One of the existing industrial routes for processing of e-waste is through the primary and secondary Cu smelting processes. During these processes, the trace elements are distributed in different phases, i.e. in metal/matte, slag and gas.
Different elements have different thermodynamic properties that govern the partitioning behaviour during the process. There has been a number of studies on the distribution behaviour of the trace elements relevant to primary Cu smelting (extraction of metals from virgin ores). However, there are only limited thermodynamics data relevant to secondary Cu smelting (extraction of metals from secondary/recycled sources). This paper reviews the thermodynamics data relevant for recovering the trace valuable elements from the primary Cu as well as secondary Cu smelting.
These data and knowledge provide the basis for determining the optimum conditions favourable for recovering the trace valuable elements in e-waste through the industrial Cu pyrometallurgical processing.

Keywords: E-Waste; E-Waste processing; WEEE recycling; precious metals; secondary copper

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Permalink: https://www.hzdr.de/publications/Publ-24002
Publ.-Id: 24002


Gelatin-based hydrogel degradation and tissue interaction in vivo: insights from multimodal preclinical imaging in immunocompetent nude mice

Tondera, C.; Ullm, S.; Krüger-Genge, A.; Jung, F.; Neffe, A. T.; Lendlein, A.; Klopfleisch, R.; Steinbach, J.; Neuber, C.; Pietzsch, J.

Hydrogels based on gelatin have evolved as promising multifunctional biomaterials. Gelatin is crosslinked with lysine diisocyanate ethyl ester (LDI) and the molar ratio of gelatin and LDI in the starting material mixture determines elastic properties of the resulting hydrogel. In order to investigate the clinical potential of these biopolymers, hydrogels with different ratios of gelatin and diisocyanate (3-fold (G10_LNCO3) and 8-fold (G10_LNCO8)) molar excess of isocyanate groups) were subcutaneously implanted in mice (uni- or bilateral implantation). Degradation and biomaterial tissue interaction were investigated in vivo (MRI, optical imaging, PET) and ex vivo (autoradiography, histology, serum analysis). Multimodal imaging revealed that the number of covalent net points correlate well with degradation time, which allows for targeted modification of hydrogels based on properties of the tissue to be replaced. Importantly, the degradation time was also dependent on the number of implants per animal. Despite local mechanisms of tissue remodeling no adverse tissue responses could be observed neither locally nor systemically. Finally, this preclinical investigation in immunocompetent mice clearly demonstrated a complete restoration of the original healthy tissue.

Keywords: Autoradiography ex vivo; Biomaterials; Computed tomography; Magnetic resonance imaging; Optical imaging; Positron emission tomography

Permalink: https://www.hzdr.de/publications/Publ-24001
Publ.-Id: 24001


Specific Surface Free Energy Component Distributions and Flotabilities of Mineral Microparticles in Flotation – An Inverse Gas Chromatography Study

Rudolph, M.; Hartmann, R.

In fundamental flotation studies often the contact angle with water is used to describe wettability of a mineral surface and it is correlated with flotability. A more fundamental parameter however is the specific surface free energy related to the contact angle via Young’s equation. Inverse gas chromatography (iGC) has recently been proven to be a suitable method to determine specific surface free energy components and their distributions of particulate surfaces. In this study the pure minerals quartz (SiO2), fluoro-apatite (Ca5[F,(PO4)3]), and magnetite (Fe3O4) are examined for flotabilities and surface energy component distributions considering different methods of sample treatment and the effect of the collectors sodium oleate and dodecyl ammonium acetate. The parameter of specific net free energy of interaction between bubbles and particles immersed in water ΔGpwb resulting from the complex surface energy analyses is introduced and used to evaluate the hydrophobicity of the mineral surface in correlation to microflotation recoveries. The results lead to the hypothesis that only small fractions of the surface and their change of wettability by flotation reagent adsorption will inherently define the flotability of minerals. Consequently, the main purpose of the amphiphilic collector molecules seems to be the reduction of high specific surface free energies of small fractions of the surface that lead to a strong attraction between particle surface sites and water molecules rather than the hydrophobization of the entire mineral surface, a new paradigm in flotation science.

Keywords: flotation; inverse gas chromatography; hyrophobicity; wettability; surface free energy; heterocoagulation

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Permalink: https://www.hzdr.de/publications/Publ-24000
Publ.-Id: 24000


Utility of established cell lines as in vivo models for (radio)-biological research on glioblastoma

Dietrich, A.; Jakob, A.; von Neubeck, C.; Fursov, A.; Tillner, F.; Baumann, M.; Krause, M.; Bütof, R.

On the translational axis from bench to bedside, it is important to have glioblastoma (GBM) models which closely reflect the clinical situation. Such models should be suitable for investigation of clinically relevant endpoints as well as reasonable regarding costs and feasible regarding statistically necessary animal numbers. Established cell lines are comprehensively characterized and can be efficiently engrafted in large cohorts of animals. In this project, a panel of five human GBM cell lines (U 87 MG, U 251 MG, A7, LN 229, HGL21) is characterized after subcutaneous and orthotopic xenograft transplantation (take rate, radiosensitivity, histology, putative stem cell markers (SM)) to investigate their potential as suitable GBM models.
Limiting dilution assays were performed using subcutaneous injection of decreasing cell numbers and take dose 50% (TD50) was low for the five GBM models. Intrinsic radiosensitivity and effectiveness of combined radiochemotherapy was studied by irradiation of subcutaneous tumors with different dose levels. Although high amounts of cancer initiating cells are indicated by the low TD50 values the surprisingly low tumor control dose 50% (TCD50) values are in contrast to the remarkable radioresistance of GBM in patients. Intracranial transplantation of mCherry- or luciferase-positive cell variants was performed with a stereotactic frame. Weekly optical imaging and contrast-enhanced magnetic resonance imaging revealed no tumor growth for one of four investigated models. After excision, tumors were analysed histologically (Haematoxylin/Eosin, SM). Three models grew within 30-60 days to end size but the histological phenotypes generally showed weak analogy to GBM patients. Although xenograft models from established cell lines of other entities very closely mirror the clinical situation, this remains questionable for GBM.

  • Lecture (Conference)
    Summer School in Translational Cancer Research, 24.-28.10.2016, Albufeira, Portugal

Permalink: https://www.hzdr.de/publications/Publ-23999
Publ.-Id: 23999


Synchronized helicity oscillations: A link between planetary tides and the solar cycle?

Stefani, F.; Giesecke, A.; Weber, N.; Weier, T.

Recent years have seen an increased interest in the question of whether the gravitational action of planets could have an influence on the solar dynamo. Without discussing the observational validity of the claimed correlations, we ask for a possible physical mechanism that might link the weak planetary forces with solar dynamo action. We focus on the helicity oscillations that were recently found in simulations of the current-driven, kink-type Tayler instability, which is characterized by an m=1 azimuthal dependence. We show how these helicity oscillations can be resonantl excited by some m=2 perturbation that reflects a tidal oscillation. Specifically, we speculate that the 11.07 years tidal oscillation induced by the Venus-Earth-Jupiter system may lead to a 1:1 resonant excitation of the oscillation of the alpha-effect. Finally, in the framework of a reduced, zero-dimensional alpha-Omega dynamo model we recover a 22.14-year cycle of the solar dynamo.

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Permalink: https://www.hzdr.de/publications/Publ-23998
Publ.-Id: 23998


Multiphase Imaging Techniques

Hampel, U.

Flow analysis and validation of computational fluid dynamics models and simulations requires experiments with proper instrumentation. Especially the validation of CFD codes calls for experimental data with high spatial and temporal resolution. This chapter will introduce the reader to imaging techniques, which may be used to obtain field parameters in multiphase flow.

Keywords: multiphase flow measurement; imaging techniques

  • Book chapter
    G. H. Yeoh: Handbook of Multiphase Flow Science and Technology, Singapore: Springer, 2020, 978-981-4585-86-6
    DOI: 10.1007/978-981-4585-86-6_14-1

Permalink: https://www.hzdr.de/publications/Publ-23997
Publ.-Id: 23997


Pressure-tank technology for steam-water two-phase flow experiments at elevated pressure and temperature

Hampel, U.; Seidel, T.; Beyer, M.; Szalinski, L.; Lucas, D.

In this contribution we describe the TOPFLOW pressure tank as an experimental facility for thermal hydraulics experiments in pressure equilibrium. The facility has been designed for studying steam-water two-phase flows at pressures of up to 50 bar. It enables to run experiments in flow domains of complex shape without paying attention to high difference pressures across the wall. The concept therefore allows us to use thin metal walls or even glass windows to observe flows in complex geometry domains with the help of IR or video camera and to considerably reduce cost and complexity of experimental settings. Several experimental studies have been performed with this technology so far. This includes counter-current flow in a reactor hot-leg mock-up, an experimental study on the thermal hydraulics of emergency core-cooling injection as well as investigations of direct contact condensation phenomena. In the following we give an introduction to the technology, details of design and operation and demonstrate its applicability to fundamental experimental studies on the direct steam condensation at jets and free surfaces.

Keywords: pressure tank technology; high pressure steam-water experiments; pressurized two-phase flow; high-speed videometry; falling jet; contact condensation

  • Contribution to proceedings
    Specialist Workshop on Advanced Instrumentation and Measurement Techniques for Nuclear Reactor Thermal Hydraulics (SWINTH), 15.-17.06.2016, Livorno, Italy
    Proceedings of SWINTH
  • Lecture (Conference)
    Specialist Workshop on Advanced Instrumentation and Measurement Techniques for Nuclear Reactor Thermal Hydraulics (SWINTH), 15.-17.06.2016, Livorno, Italy

Permalink: https://www.hzdr.de/publications/Publ-23996
Publ.-Id: 23996


Ultrafast X-ray tomography for two-phase flow experiments

Hampel, U.; Banowski, M.; Krepper, E.; Szalinski, L.; Beyer, M.; Lucas, D.; Barthel, F.; Wagner, M.; Bieberle, M.

Non-invasive tomographic imaging techniques are appropriate tools for the study of two-phase flow in nuclear thermal hydraulic experiments. Ultrafast X-ray tomography developed at Helmholtz-Zentrum Dresden-Rossendorf can scan two-phase flows both fast and with good spatial resolution. In this paper we introduce the tomography scanner system ROFEX and discuss its application to the study of two-phase flow in pipes – a benchmark problem for two-fluid CFD code development.

Keywords: two-phase flow; ultrafast X-ray tomography; gas holdup measurement; image processing; bubble size measurement; CFD code validation

  • Contribution to proceedings
    Specialist Workshop on Advanced Instrumentation and Measurement Techniques for Nuclear Reactor Thermal Hydraulics (SWINTH), 15.-17.06.2016, Livorno, Italy
    Proceedings of SWINTH
  • Lecture (Conference)
    Specialist Workshop on Advanced Instrumentation and Measurement Techniques for Nuclear Reactor Thermal Hydraulics (SWINTH), 15.-17.06.2016, Livorno, Italy

Permalink: https://www.hzdr.de/publications/Publ-23995
Publ.-Id: 23995


Millisecond thermal processing using flash lamps for the advancement of thin layers and functional coatings

Skorupa, W.; Schumann, T.; Rebohle, L.

Thermal processing in the millisecond range provides advanced, non-equilibrium annealing techniques which allow dedicated material modifications at the surface without affecting the substrate volume below. The process called flash lamp annealing (FLA) is one of the most diverse methods of short time annealing with applications ranging from the classical field of semiconductor doping to the treatment of layers on glass, polymers and other flexible substrates. It still continues to extend to other material classes and applications, and becomes of interest for an increasing number of users. Other phrases for FLA used throughout the literature are intense pulsed light sintering (IPL) or photonic curing. This review presents a short and comprehensive view of the current state of the art of FLA with a focus on functional coatings. After an introduction including historical aspects a look is taken to equipment issues as well as to the pioneering role which semiconductor processing in the framework of advanced chip technology played for the development of short time annealing. Mostly, examples of processing for photovoltaics, including doping aspects, hydrogen engineering, copper indium gallium diselenide (CIGS), silicon crystallisation on glass, and transparent conductive oxides (TCO), including indium tin oxide (ITO), zinc oxide (also Al-doped AZO) as well as inkjet printing for flexible electronics will be presented.

Keywords: flash lamp annealing (FLA); intense pulsed light sintering (IPL); semiconductors; silicon; indium tin oxide (ITO); ink jet printing

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Permalink: https://www.hzdr.de/publications/Publ-23994
Publ.-Id: 23994


A combined EXAFS spectroscopic and quantum chemical study on the complex formation of Am(III) with formate

Froehlich, D. R.; Kremeleva, A.; Rossberg, A.; Skerencak-Frech, A.; Koke, C.; Krüger, S.; Roesch, N.; Panack, P. J.

The complexation of Am(III) with formate in aqueous solution is studied as a function of the pH value using a combination of extended X-ray absorption fine structure (EXAFS) spectroscopy, iterative transformation factor analysis (ITFA), and quantum chemical calculations. The Am LIII-edge EXAFS spectra are analyzed to determine the molecular structure (coordination numbers; Am −O and Am −C distances) of the formed Am(III) −formate species and to track the shift of the Am(III) speciation with increasing pH.
The experimental data are compared to predictions from density functional calculations. The results indicate that formate binds to Am(III) in a monodentate fashion, in agreement with crystal structures of lanthanide formates. Furthermore, the investigations are complemented by thermodynamic speciation calculations to verify further the results obtained.

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Permalink: https://www.hzdr.de/publications/Publ-23993
Publ.-Id: 23993


A small animal tumour model for in vivo studies with low energy laser accelerated particles

Beyreuther, E.; Brüchner, K.; Krause, M.; Leßmann, E.; Schmidt, M.; Pawelke, J.

Introduction: The long-term aim of developing laser based acceleration of protons and ions towards clinical application requires not only substantial technological progress, but also the radiobiological characterization of the resulting ultra-short and ultra-intensive particle beam pulses. Recent in vitro data showed similar effects of laser-accelerated versus “conventional” protons on clonogenic cell survival and DNA double-strand breaks. As the proton energies currently achieved for radiobiological experiments by laser driven acceleration are too low to penetrate standard tumour models on mouse legs, a small animal tumour model allowing for the penetration of low energy protons (~20 MeV) was developed to further verify the effects in vivo.

Methods: The originally for human HNSCC FaDu established mouse ear tumour model was adapted for LN229 human glioblastoma cells. For this, cells were injected subcutaneously in the right ear of NMRI nude mice and the growing tumours were characterized with respect to growth parameters and histology. After optimizing the number of injected cells and used medium (PBS, Matrigel) the radiation response was studied by 200 kV X-ray irradiation. Furthermore, a proof-of-principle full scale experiment with laser accelerated electrons was performed to validate the FaDu tumour model under realistic, i.e. harsh, conditions at experimental laser accelerators.

Results: Both human tumour models showed a high take rate and continuous tumour growth after reaching a volume of ~5 – 10 mm3. Moreover, immunofluorescence analysis revealed that already the small tumours interact with the surrounding tissue and activate endothelial cells to form vessels. By analysing the dose dependent tumour growth curves after 200 kV X-ray treatment a realistic dose range, i.e. for inducing tumour growth delay but not tumour control, was defined for both tumour entities under investigation.
Beside this basic characterization, the comparison of the influence of laser driven and conventional (clinical Linac) electrons on the growth of FaDu tumours reveal no significant difference in the radiation induced tumour growth delay.

Conclusion: The already established mouse ear tumour model was successfully upgraded now providing stable tumour growth with high take rate for two tumour entities (HNSCC, glioblastoma) that are of interest for future proton treatment. Experiments comparing laser driven and conventional proton beams in vivo as the next step towards clinical application of laser driven particle acceleration are under way.

Acknowledgement: The work was supported by the German Government, Federal Ministry of Education and Research, grant nos. 03ZIK445 and 03Z1N511.

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  • Poster
    19. Jahrestagung der Gesellschaft für Biologische Strahlenforschung e.V., 26.-28.09.2016, Erlangen, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-23991
Publ.-Id: 23991


Radiobiology of pulsed particle beams

Beyreuther, E.

Current radiotherapy treatment modalities like Intensity Modulated Radiation Therapy (IMRT) and gated irradiation and new technological developments like laser-driven particle accelerators include the dose delivery by short radiation pulses of high dose rate that overlap in the tumor region. The doses are accumulated over sequent radiation pulses that vary in dose fraction and time structure, which might influence the radiation response of the irradiated tissue.
In order to understand the temporal and fractionation influence of sequent beam delivery basic radiobiological experiments and translational studies to the point of clinical implementation are necessary. Starting with fundamental radiobiological principles, like radiation action and the induction of DNA damage, the lecture will also introduce some standard methods in radiobiological research. On cellular level this includes the colony formation assay as so called “golden standard” to measure the cellular survival and the quantification of molecules involved in the recognition and repair of DNA damage. One step further in the translational research chain, the observation of the radiation induced tumor growth delay on small animals will be explained.
In the second part of the lecture preceding and recent radiobiological experiments with pulsed particle beams will be presented. Beginning in the 1950s, first experiments were carried out mainly to understand the mechanism of radiation action revealing that the radiobiological effect is influenced by dose rates below 1 Gy/min, but not by higher ones. In continuation of these experiments, several studies focusing on different aspects of pulsed radiation were performed during the last two decades.
Parallel to their clinical implementation the radiobiological consequences of the sequent pulse delivery of gating and IMRT techniques were investigated highlighting the overall fraction time as critical parameter. Contrary to the dose rates of < 104 Gy/min applied for these current clinical dose delivery techniques, the laser driven techniques are characterized by pulse dose rates higher than 109 Gy/min. Taking the ultra-high pulse dose rate and other specific properties of laser driven particle beams into account the replacement of conventional accelerators for particle radiotherapy was investigated by several groups worldwide. To sum up, the hitherto performed cell and animal studies disclose that the radiobiological response to laser driven particle beams is not influenced by their ultra-high pulse dose rate.

Related publications

  • Invited lecture (Conferences)
    Lasers in Medicine and Life Sciences - Lamelis Summerschool, 07.07.2016, Szeged, Hungary
  • Invited lecture (Conferences)
    Lasers in Medicine and Life Sciences - Lamelis Summerschool, 18.-21.07.2017, Szeged, Hungary

Permalink: https://www.hzdr.de/publications/Publ-23990
Publ.-Id: 23990


Magnetic-field and composition-dependent Fermiology in correlated metals

Wosnitza, J.

es hat kein Abstract vorgelegen

  • Invited lecture (Conferences)
    Workshop on "Fermi-surface topology and emergence of novel electronic states in strongly correlated systems", 18.07.-01.08.2016, Natal, Brasilien

Permalink: https://www.hzdr.de/publications/Publ-23989
Publ.-Id: 23989


How To Analyze The Electronic Density - An Introduction To Some Useful Tools

Patzschke, M.

Understanding a molecular system is not possible by only doing an electronic structure calculation. The results have to be analysed. In this presentation we will show some useful tools to do that.

Keywords: computational chemistry; ELF/ELI; AIM; NCI

  • Invited lecture (Conferences)
    CSC Spring School 2016, 11.03.2016, Helsinki, Finnland
  • Invited lecture (Conferences)
    CSC Spring School in Theoretical Chemistry, 17.03.2017, Helsinki, Finnland

Permalink: https://www.hzdr.de/publications/Publ-23988
Publ.-Id: 23988


Understanding and advancing the coordination and redox chemistry of the actinides

Woodall, S.; Natrajan, L.; Kaden, P.; Kerridge, A.

Sean Woodall, Louise Natrajan, Peter Kaden and Andrew Kerridge highlight recent advances in the chemistry of actinide elements that have been made possible through the collaborative efforts of industry and academia

Keywords: uranyl; neptunyl; TPIP; NMR; emmission; spectroscopy; theory; Single-crystal; x-ray; Uranium; Neptunium

  • Contribution to external collection
    in: Nuclear Future, Volume 11 issue 6, London: The Nuclear Institute CK International House, 2015, 1745 2058, 21-26

Permalink: https://www.hzdr.de/publications/Publ-23987
Publ.-Id: 23987


Monitoring Redox Behaviour of Actinide Ions by a Combination of Emission and NMR Spectroscopy

Natrajan, L. S.; Woodall, S. D.; Swinburne, A. N.; Randall, S.; Banik, N.; Adam, C.; Di Pietro, P.; Kaden, P.; Kerridge, A.

Europe currently holds a substantial nuclear legacy arising from fission activities, with a large proportion of high activity wastes that pose a radiological threat to natural and engineered environments. The decision to dispose of these high level wastes (following separation) in a suitable geological disposal facility (GDF) has provided some of the most demanding technical, and environmental challenges facing the EU in the coming century. In order to address these issues, we have begun a programme of work to establish a comprehensive understanding of the electronic properties and physical and chemical properties of the radioactive actinide metals using state of the art emission spectroscopic techniques in combination with NMR and computational methods.[1,2]
Our approach to this is to firstly use coordination chemistry to synthesise uranium compounds with ligands that model environmentally complexed species and use optical spectroscopy to understand and map both the chemical and physical behaviour of these species (Figure 1). We have recently established that U(IV) complexes are emissive and will demonstrate that uranium in the +IV and +VI oxidation states can be detected simultaneously at relatively low concentrations. Time gating techniques enable the long lived uranyl(VI) species to be separated from the shorter lived uranium(IV) species. Furthermore, the form of the emission spectra of uranyl(VI) compounds are extremely sensitive to the nature of the ligand bound in the equatorial plane and the complex nuclearity (extent of aggregation), potentially giving a sensitive method of assessing the solution forms of uranium in environmental conditions. We will next discuss how the optical properties of these model compounds can be extended to the trans-uranics and applied to disproportionation reactions and redox events in solution.
Financial support for this research was provided by the UK Engineering and Physical Sciences Research Council (EPSRC) and The Leverhulme Trust. The authors thank the European Commission Euratom FP7 funded project
(no. 269923) EURACT-NMR for support.
1. L.S. Natrajan, Coord. Chem. Rev., 2012, 256, 1583; Coord. Chem. Rev., 2014, 266–267, 171.
2. S.D. Woodall, A.N. Swinburne, N. lal Banik, A. Kerridge, P. Di Pietro, C. Adam, P. Kaden and L.S. Natrajan, Chem. Commun., 2015, 51, 5402.

Keywords: redox; actinide; emission; NMR; spectroscopy; uranium; U(IV); U(VI); uranyl

  • Lecture (Conference)
    Second Joint Student workshop on f-Element Chemistry, 09.-10.06.2015, Karlsruhe, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-23986
Publ.-Id: 23986


Luminescence spectroscopy of uranium

Steudtner, R.; Drobot, B.; Haubitz, T.; Lehmann, S.; Vogel, M.

Luminescence spectroscopy is a powerful tool to study the chemistry of f-elements (actinides – An, lanthanides – Ln) in trace concentration. Manifold operating mode, e.g. steady-state, time-resolved, laser-induced, site-selective, cryogenic, etc. were used to investigate the environmental behavior of An/Ln in various geological and biological systems.

  • Lecture (others)
    Institutskolloquium, 27.07.2016, Karlsruhe, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-23985
Publ.-Id: 23985


Comparison of Model-free Methods for Paramagnetic Chemical Shifts in Lanthanide and Americium(III) Complexes

Adam, C.; Kaden, P.; Beele, B. B.; Müllich, U.; Geist, A.; Panak, P. J.

NMR spectroscopy on paramagnetic compounds is a sensitive and versatile method for structural investigations of metal-organic complexes. Furthermore, separation of the overall observed paramagnetic chemical shift into parts due to covalently transferred electron spin density (Fermi contact shift, FCS) and distance- and angle-dependent dipolar electron-nucleus spin coupling (pseudo contact shift, PCS) yields insights into metal-ligand bonding. The evaluation of the pure FCS allows to determine the share of covalance in this bond. Covalence is thought to be the reason for some ligands’ selectivity for the selective complexation of actinide over lanthanide ions in potential partitioning processes.[1,2]
Since the advent of chemical shift reagents in NMR spectroscopy in 1969, several methods for the separation of FCS and PCS have been developed.[3-6] Modell-free methods rely on calculated values like spin expectation values, geometrical constants and crystal field parameters. All these values are still unknown for actinide compounds. On the other hand, the application of methods requiring a structural modell of the complex is only possible for metal ions with a large magnetic anisotropy, like the heavy lanthanides. As Am(III) has a low magnetic anisotropy, only modell-free methods can be applied to separate the observed paramagnetic shift and to elucidate the bonding in Am(III)-N-donor complexes.
Currently, we evaluate the applicability of several approaches for separation of FCS and PCS in lanthanide complexes and their transferability to actinide compounds. This includes methods based on calculated values as well
as temperature-dependent methods. We will report on our studies on a complete set of 15N-labeled lanthanide nPr-BTP and C5-BPP complexes and discuss the applicability of the methods on actinide complexes.
This work is supported by the German Federal Ministry of Education and Research (BMBF) under contract numbers 02NUK020A and 02NUK020D.
1. C. Adam, B. B. Beele, A. Geist, U. Mullich, P. Kaden and P. J. Panak, Chemical Science, 2015, 6, 1548-1561.
2. C. Adam, P. Kaden, B. B. Beele, U. Müllich, S. Trumm, A. Geist, P. J. Panak and M. A. Denecke, Dalton Trans.,
2013, 42, 14068-14074.
3. C. F. G. C. Geraldes, S. Zhang and A. D. Sherry, Inorg. Chim. Acta, 2004, 357, 381-395.
4. C. Piguet and C. F. G. C. Geraldes, in Handbook on the Physics and Chemistry of Rare Earths, eds. J. K.A. Gschneidner,
J. C. G. Bünzli and V. K. Pecharsky, Elsevier, 2003, vol. Volume 33, pp. 353-463.
5. S. Di Pietro, S. L. Piano and L. Di Bari, Coord. Chem. Rev., 2011, 255, 2810-2820.
6. A. G. Martynov, Y. G. Gorbunova and A. Y. Tsivadze, Dalton Trans., 2011, 40, 7165-7171.

Keywords: NMR; paramagnetic; lanthanide; Americium; chemical shift; BTP; BPP

  • Lecture (Conference)
    Second Joint Student Workshop on f-Element Chemistry, 09.06.-10.07.2015, Karlsruhe, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-23984
Publ.-Id: 23984


Two-phase Flow Pattern Measurements with a Wire Mesh Sensor in a Direct Steam Generating Solar Thermal Collector

Berger, M.; Mokhtar, M.; Zahler, C.; Willert, D.; Neuhäuser, A.; Schleicher, E.

At Industrial Solar’s test facility in Freiburg (Germany), two phase flow patterns have been measured by using a wire mesh sensor from Helmholtz-Zentrum Dresden-Rossendorf (HZDR). Main purpose of the measurements was to compare observed two-phase flow patterns with expected flow patterns from models. The two-phase flow pattern is important for the design of direct steam generating solar collectors. Vibrations should be avoided in the peripheral piping, and local dry-outs or large circumferential temperature gradients should be avoided in the absorber tubes. Therefore, the choice of design for operation conditions like mass flow and steam quality are an important step in the engineering process of such a project. Results of a measurement with the wire mesh sensor are the flow pattern and the plug or slug frequency at the given operating conditions. Under the assumption of the collector power, which can be assumed from previous measurements at the same collector and adaption with sun position and incidence angle modifier, also the slip can be evaluated for a wire mesh sensor measurement. Measurements have been performed at different mass flows and pressure levels. Transient behavior has been tested for flashing, change of mass flow, and sudden changes of irradiation (cloud simuation). This paper describes the measurements and the method of evaluation. Results are shown as extruded profiles in top view and in side view. Measurement and model are compared. The tests have been performed at low steam quality, because of the limits of the test facility. Conclusions and implications for possible future measurements at larger collectors are also presented in this paper.

  • Contribution to proceedings
    SolarPACES 2016, 11.-14.10.2016, Abu Dhabi, United Arab Emirates
    AIP Conference Proceedings 1850(2017) 070003
    DOI: 10.1063/1.4984417

Permalink: https://www.hzdr.de/publications/Publ-23983
Publ.-Id: 23983


How Theory Can Probe The Chemical Bond: The Case Of Caged U2

Patzschke, M.

"Nothing is simple in actinide chemistry" B. Roos
We present results on the intricate changes in An-An bonding in differently sized cages.
Methods used model the compounds are introduced and analysis tools are presented.

Keywords: computational chemistry; ELI; AIM; actinides; endohedral complexes

  • Invited lecture (Conferences)
    15. Koordinierungsgespräch PSI/LES - HZDR/IRE, 28.08.2015, Dresden, Deutschland

Permalink: https://www.hzdr.de/publications/Publ-23982
Publ.-Id: 23982


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