Stability and speciation of hydrated magnetite {111} surfaces from ab initio simulations with relevance for geochemical redox processes

Katheras, A. S.; Karalis, K.; Krack, M.; Scheinost, A.⁽¹⁾; Churakov, S. V.

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Revisiting the selenium interactions with pyrite: from adsorption to coprecipitation

Guida, C.; Ramothe, V.; Chappaz, A.; Simonnin, P.; Rosso, K. M.; Gilbert, B.; Ding, R.-R.; Prieur, D.⁽⁵⁾; Scheinost, A.⁽⁶⁾; Charlet, L.

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Unraveling the Np(V) Sorption on the Nuclear Fuel Cladding Corrosion Product ZrO₂: a Batch, Spectroscopic and Modeling Combined Approach

Jessat, I.⁽¹⁰⁾; Foerstendorf, H.⁽¹¹⁾; Roßberg, A.; Scheinost, A.⁽¹²⁾; Lützenkirchen, J.; Heim, K.; Stumpf, T.⁽¹³⁾; Jordan, N.⁽¹⁴⁾

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Chemistry of the interaction and retention of TcVII and TcIV species at the Fe3O4(001) surface

Bianchetti, E.; Faria Oliveira, A.⁽¹⁸⁾; Scheinost, A.⁽¹⁹⁾; Di Valentin, C.; Seifert, G.

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Oxidation state and structure of Fe in nontronite: From oxidizing to reducing conditions

Qian, Y.; Scheinost, A.⁽²³⁾; Grangeon, S.; Greneche, J.-M.; Hoving, A.; Bourhis, E.; Maubec, N.; Churakov, S. V.; Marques Fernandes, M.

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Assessing the reactivity of Fe(II) sorbed on smectite clays: U(VI) reduction

Chakraborty, S.; Banerjee, D.; Scheinost, A.⁽²⁷⁾; Grenèche, J.-M.; Favre, F.; Géhin, A.; Charlet, L.

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Shedding light on the enigmatic TcO₂·xH₂O structure with density functional theory and EXAFS spectroscopy

Faria Oliveira, A.⁽³¹⁾; Kuc, A. B.⁽³²⁾; Heine, T.⁽³³⁾; Abram, U.⁽³⁴⁾; Scheinost, A.⁽³⁵⁾

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Pbx(OH)y cluster formation in STI framework-type zeolites: anomalous thermal behaviour and increased thermal stability

Cametti, G.; Roos, D. P.; Churakov, S. V.; Prieur, D.; Scheinost, A. C.

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Selenium nanowire formation by reaction of selenate with magnetite

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Oxidation of Micro- and Nanograined UO2Pellets by in Situ Synchrotron X-ray Diffraction

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Charge distribution in U1-xCexO2+y nanoparticles

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On the nature of Pb species in Pb-(over)exchanged zeolite: a combined experimental and theoretical study

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Cd2+ incorporation in small pores LEV/ERI intergrown zeolites: a multi-methodological study

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Technetium immobilization by chukanovite and its oxidative transformation products: Neural network analysis of EXAFS spectra

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ROBL-II at ESRF: A synchrotron toolbox for actinide research

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Mechanisms of selenium removal by partially oxidized magnetite nanoparticles for waste water remediation

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Uranium and neptunium retention mechanisms in Gallionella ferruginea / ferrihydrite systems for remediation purposes

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Structural Evolution of Ag-LEV Zeolite upon Heating: an in situ Single-Crystal X-ray Diffraction (SC-XRD) and X-ray Absorption Spectroscopy (XAS) Study

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Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles

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On the O-rich domain of the U-Am-O phase diagram

Epifano, E.; Vauchy, R.; Lebreton, R.; Lauwerier, F.; Joly, A.; Scheinost, A.⁽¹⁰¹⁾; Guéneau, C.; Valot, C.; Martin, P. M.

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Iron adsorption on clays inferred from atomistic simulations and XAS spectroscopy

Kéri, A.; Dähn, R.; Marques Fernandes, M.; Scheinost, A.⁽¹⁰⁵⁾; Krack, M.; Churakov, S. V.

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New insights into 99Tc(VII) removal by pyrite: A spectroscopic approach

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Signatures of Technetium Oxidation States: A New Approach

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The missing pieces of the PuO2 nanoparticles puzzle

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A novel metastable pentavalent plutonium solid phase on the pathway from aqueous Pu(VI) to PuO2 nanoparticles

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Structural modifications and thermal stability of Cd2+ -exchanged stellerite, a zeolite with STI framework-type

Cametti, G.; Scheinost, A. C.; Churakov, S. V.

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Antimonite binding to natural organic matter: Spectroscopic evidence from a mine water impacted peatland

Besold, J.; Eberle, A.; Noël, V.; Kujala, K.; Kumar, N.; Scheinost, A.; Lezama Pacheco, J.; Fendorf, S.; Planer-Friedrich, B.

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Plutonium retention mechanisms by magnetite under anoxic conditions: Entrapment versus sorption

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Framework modifications and dehydration path of a Ag+-modified, STI-type zeolite

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Antimonite complexation with thiol and carboxyl/phenol groups of particulate organic matter

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Extreme multi-valence states in mixed actinide oxides

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Methyl selenol as precursor in selenite reduction to Se/S species by methane-oxidizing bacteria

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Complexation of arsenite, arsenate, and monothioarsenate with oxygen-containing functional groups of natural organic matter: An XAS study

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Crystallographic structure and charge distribution of AUO4 and A3UO6 uranates (A= Ca, Sr, Ba or Pb)

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Towards the surface hydroxyl species in CeO2 nanoparticles

Plakhova, T. V.; Romanchuk, A. Y.; Butorin, S. M.; Konyukhova, A. D.; Egorov, A. V.; Shiryaev, A. A.; Baranchikov, A. E.; Dorovatovskii, P. V.; Huthwelker, T.; Gerber, E.; Bauters, S.⁽¹⁶⁸⁾; Sozarukova, M. M.; Scheinost, A.⁽¹⁶⁹⁾; Ivanov, V.; Kalmykov, S. N.; Kvashnina, K.⁽¹⁷⁰⁾

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Interdisciplinary round-robin test on molecular spectroscopy of the U(VI) acetate system

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Sorption of iodine in soils: insight from selective sequential extractions and X-ray absorption spectroscopy

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Peculiar thermal behavior of UO2 local structure

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• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽¹⁸⁰⁾

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Monothioarsenate transformation kinetics determines arsenic sequestration by sulfhydryl groups of peat

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A spectroscopic and computational study of Cm3+ incorporation in lanthanide phosphate rhabdophane (LnPO4·0.67H2O) and monazite (LnPO4)

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Structural characterization of (Sm,Tb)PO4 solid solutions and pressure-induced phase transitions

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Aliovalent cation substitution in UO2: Electronic and local struc-tures of U1-yLayO2±x solid solutions

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Retention and multiphase transformation of selenium oxyanions during the formation of magnetite via ferrous hydroxide and green rust

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• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽¹⁹⁶⁾

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From cubic palladium to concave core-shell platinum palladium nanoparticles: Evolution of the structure and their electrochemical properties

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Retention of selenium by calcium aluminate hydrate (AFm) phases under strongly reducing radioactive waste repository conditions

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Biotransformation and detoxification of selenite by microbial biogenesis of selenium-sulfur nanoparticles

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• Ion Beam Center DOI: 10.17815/jlsrf-3-159⁽²⁰⁵⁾
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Assessment of solid/liquid equilibria in the (U, Zr)O2+x system

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In-situ XAFS characterization of PtPd nanoparticles synthesized by galvanic replacement

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A new look at the structural and magnetic properties of potassium neptunate K2NpO4 combining XRD, XANES spectroscopy and low temperature heat capacity

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Microbial Transformations of Selenite by Methane-Oxidizing Bacteria

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Structural investigations of (La,Pu)PO4 monazite solid solutions: XRD and XAFS study

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Insights into the structure and thermal stability of uranyl aluminate nanoparticles

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Solution species and crystal structure of Zr(IV) acetate

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The inverse-trans-influence as a general principle of f-block chemistry

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Uptake mechanisms of selenium oxyanions during the ferrihydrite-hematite recrystallization

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Batch sorption and spectroscopic speciation studies of neptunium uptake by montmorillonite and corundum

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Evidence of trivalent Am substitution into U3O8

Caisso, M.; Roussel, P.; Den Auwer, C.; Picart, S.; Hennig, C.; Scheinost, A. C.; Delahaye, T.; Ayral, A.

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Systematic XAS study on the reduction and uptake of Tc by magnetite and mackinawite

Yalcintas, E.; Scheinost, A. C.; Gaona, X.; Altmaier, M.

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NeptuniumV retention by siderite under anoxic conditions: Precipitation of NpO2–like nanoparticles and of NpIV pentacarbonate

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Involved research facilities

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Further insights into the chemistry of the Bi-U-O system

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Sorption of trivalent lanthanides and actinides onto montmorillonite: Macroscopic, thermodynamic and structural evidence for ternary hydroxo and carbonato surface complexes on multiple sorption sites

Marques Fernandes, M.; Scheinost, A. C.; Baeyens, B.

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A Johann-type X-ray emission spectrometer at the Rossendorf beamline

Kvashnina, K. O.; Scheinost, A. C.

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On the use of HERFD-XANES at the U L3 and M4-edges to determine the uranium valence state on [Ni(H2O)4]3[U(OH,H2O)(UO2)8O12(OH)3]

Bès, R.; Rivenet, M.; Solari, P. L.; Kvashnina, K. O.; Scheinost, A. C.; Martin, P. M.

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Emergence of comparable covalency in isostructural cerium(IV)- and uranium(IV)-carbon multiple bonds

Gregson, M.; Lu, E.; Tuna, F.; Mcinnes, E. J. L.; Hennig, C.; Scheinost, A. C.; Mcmaster, J.; Lewis, W.; Blake, A. J.; Kerridge, A.; Liddle, S. T.

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Melting behavior of americium-doped uranium dioxide

Prieur, D.; Lebreton, F.; Caisso, M.; Martin, P.; Scheinost, A. C.; Somers, J.; Delahaye, T.; Manara, D.

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Structural properties and charge distribution of the sodium uranium, neptunium and plutonium ternary oxides: a combined X-ray diffraction and XANES study

Smith, A. L.; Martin, P.; Prieur, D.; Scheinost, A. C.; Raison, P. E.; Cheetham, A. K.; Konings, R. J. M.

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Actinide oxidation state and O/M ratio in hypostoichiometric uranium-plutonium-americium U0.750Pu0.246Am0.004O2-x mixed oxides

Vauchy, R.; Belin, R. C.; Robisson, A.-C.; Lebreton, F.; Scheinost, A. C.; Aufore, L.; Martin, P. M.

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Multiscale structural characterizations of mixed U(IV)-An(III) oxalates (An(III) = Pu or Am) combining XAS and XRD measurements

Arab-Chapelet, B.; Martin, P.; Costenoble, S.; Delahaye, T.; Scheinost, A. C.; Grandjean, S.; Abraham, F.

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The nature of chemical bonding in actinide and lanthanide ferrocyanides determined by X-ray absorption spectroscopy and density functional theory

Dumas, T.; Guillaumont, D.; Fillaux, C.; Scheinost, A.; Moisy, P.; Petit, S.; Shuh, D. K.; Tyliszczak, T.; Den Auwer, C.

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Peculiar behavior of (U,Am)O2−δ compounds for high americium contents evidenced by XRD, XAS, and Raman spectroscopy

Lebreton, F.; Horlait, D.; Caraballo, R.; Martin, P.; Scheinost, A. C.; Rossberg, A.; Jégou, C.; Delahaye, T.

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• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²⁸¹⁾

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Structural investigation of (U0.7Pu0.3)O2-x mixed oxides

Vigier, J.-F.; Martin, P. M.; Martel, L.; Prieur, D.; Scheinost, A. C.; Somers, J.

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• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²⁸⁴⁾

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A new look at the structural properties of trisodium uranate Na3UO4

Smith, A. L.; Raison, P. E.; Martel, L.; Prieur, D.; Charpentier, T.; Wallez, G.; Suard, E.; Scheinost, A. C.; Hennig, C.; Martin, P.; Kvashnina, K. O.; Cheetham, A. K.; Konings, R. J. M.

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