RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Site Query Results


Binding Site Data:


Mineral: Montmorillonite
Reference: PKZZ11
SCM Type: NE - Non-electrostatic
Ionic Strength:
Site Type: »Al(w)-OH
PZC:
pK1: 8.33   pK12.31 nm−2 (normalized): 7.94
pK2: 9.73   pK22.31 nm−2 (normalized): 10.12
Site Density in nm-2: 0.9400
Original Site Density: 0.94 sites / nm² surface
Solid/Liquid Ratio in g/L:
pH Range:
Temperature in K:
Method for Site Density: Literature
Method for Protolysis:Potentiometric Titration
Fit Method:FITEQL
Comment: assumed that the edge sites of montmorillonite are the locations for reactive surface sites. These sites represent 10% of the total available surface area [TPB98a]. Therefore, the site density was decreased to 0.23 sites per nm² when calculating the aluminol and silanol site concentrations; assumed Al:Si ratio of 0.83 [WZ88]; protolysis constants from [T95]
 
1 data sets were retrieved