RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Kaolinite
Reference: EPH13
SCM Type: NE - Non-electrostatic
Ligand: Ni<2+> - nickel
Site Type: »X(s)-OH
Equation: »X(s)-OH + Ni<2+> + H2O  ⇔  »X(s)-O-Ni(OH) + 2 H<1+>
LogK: -10.5        LogK°I=0 (Conversion to I = 0):   -10.41
Experiment: Batch Sorption Experiments
Ionic Strength: 0.01 mol/L NaNO3
Temperature: 298.15 K
Solid/Liquid Ratio: 10.0 g/L
pH Range: 4 - 10
Ligand Concentration Range: 1E-6 mol/L
Fit Method: PHREEQC
Comment: ion exchange: 2Z<1-> + Ni<2+> = NiZ2, log K = 1.0; Na<1+> + Z<1-> = NaZ, log K = 0.0; Z<1-> + H<1+> = HZ, log K = 0.0
 
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