RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Alumina
Reference: GS84a
SCM Type: CC - Constant Capacitance
Ligand: PO4<3-> - phosphate
Site Type: »Al-OH
Equation: »Al-OH + PO4<3-> + 2 H<1+>  ⇔  »Al-HPO4<1-> + H2O
LogK: 23.912        LogK°I=0 (Conversion to I = 0):   25.09         LogK2.31 nm−2 (SSD-normalized):  
Experiment: Sorption Isotherms
Ionic Strength: 0.1 mol/L NaCl
pH Range: 4-7
Fit Method: FITEQL
Comment: adsorption isotherm data from [H75], FITEQL/MICROQL; original equation: »Al-OH + H3PO4 = »Al-HPO4<1-> + H2O + H<1+> with log K = 2.21, formation constant in aqueous solution: PO4<3-> + 3H<1+> = H3PO4 logK = 21.702 [GFFGN03]
 
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