RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

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Surface Complex Formation Data:

Mineral: Microcline
Reference: S93a
SCM Type: TL - Triple Layer
Ligand: Mn<2+> - manganese(II)
Site Type: »X-OH
Equation: »X-OH + Mn<2+>  ⇔  »X-O-Mn<1+> + H<1+>
LogK: 3.31
Experiment: Empirical Correlation
Ionic Strength:
Fit Method:
Comment: ite type not specified; calculated value of logK: dependence of the free energy of sorption on ion solvation manifested by a linear dependence on the inverse of the dielectric constant; emphasizes that logK, thought to be characteristic of both the sorbing ion and the solid, should by replaced by a more fundamental ion intrinsic constant independent of the solid, once solvation effects are explicitely taken into account
 
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