RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Biotite
Reference: WAT01b
SCM Type: DDL - Diffuse Double Layer
Ligand: NpO2<1+> - neptunyl(V)
Site Type: »Si-OH
Equation: »Si-OH + NpO2<1+>  ⇔  »Si-O-NpO2 + H<1+>
LogK: -4.17 ± 0.03         LogK°I=0 (Conversion to I = 0):   -4.17
Experiment: Batch Sorption Experiments
Ionic Strength: 0.1 mol/L NaNO3
Temperature: 303.15 K
Solid/Liquid Ratio: 1.0 g/L
pH Range: 4-11
Ligand Concentration Range: 6E-6 mol/L
Fit Method: FITEQL
Comment: Si/Al =3,SCM calculations; experimental data from batch sorption experiments [NS91]; [WAT01b]: no CO2, but [NS91]: ambient aerobic conditions; [NS91]: 30°C
 
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