RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Ferrihydrite
Reference: AVTC02
SCM Type: CC - Constant Capacitance
Ligand: Fe<2+> - iron(II)
Site Type: »Fe(s)-OH
Equation: »Fe(s)-OH + Fe<2+>  ⇔  »Fe(s)-O-Fe<1+> + H<1+>
LogK: -0.95 ± 0.5         LogK°I=0 (Conversion to I = 0):   -0.63         LogK2.31 nm−2 (SSD-normalized):   -0.86
Experiment: Batch Sorption Experiments
Ionic Strength: 0.1 mol/L NaNO3
Solid/Liquid Ratio: 0.143 g/L
pH Range: 5-9
Ligand Concentration Range: 1.6E-4 mol/L
Fit Method: PEST
Comment: PEST in combination with PHREEQC-2; refit of raw data from [LCV99] (there only one site) to [DM90] database; uncertainty interval indicates the aproximate 95% confidence limits
 
1 data sets were retrieved