Mineral: |
Calcite |
Reference: |
ZRHSK05 |
SCM Type: |
CC - Constant Capacitance |
Ligand: |
Sm<3+>
- samarium
|
Site Type: |
»Ca-OH |
Equation: |
»Ca-OH + Sm<3+> + 3 CO3<2-> ⇔ »Ca-O-Sm(CO3)3<4-> + H<1+> |
LogK: |
48.11 LogK°I=0 (Conversion to I = 0): 48.11
LogK2.31 nm−2 (SSD-normalized): 43.59
|
Experiment: |
Batch Sorption Experiments |
Ionic Strength: |
0.0 mol/L
|
Temperature: |
298.15 K |
Solid/Liquid Ratio: |
1.25 g/L |
pH Range: |
6.75-8.75 |
Ligand Concentration Range: |
1E-7 mol/L |
Fit Method: |
FITEQL |
Comment: |
background electrolyte calcite equilibrated solution; 24h, 1% CO2 in N2; ATTENTION: error in fitting code produced incorrect values. All values need to be increase by +8 log units. (correct 5.27 instead of -2.74 in table 3); original reaction equation in the article: »Ca<+> + Sm<3+> + 3 HCO3<1-> = »Ca-CO3Sm(CO3)2<2-> + 3 H<1+> with logK = 5.27, conversion done with the reaction HCO3<1-> = CO3<2-> + H<1+> and logK = -10,33 [JL97] and converted to »CaOH surface species with data taken from Table 2. |
|