RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Montmorillonite
Reference: BB05a
SCM Type: NE - Non-electrostatic
Ligand: Pd<2+> - palladium
Site Type: »X(s)-OH
Equation: »X(s)-OH + Pd<2+> + 2 H2O  ⇔  »X(s)-O-Pd(OH)2<1-> + 3 H<1+>
LogK: -5.9        LogK°I=0 (Conversion to I = 0):   -5.79
Experiment: Sorption Isotherms
Ionic Strength: 0.1 mol/L NaClO4
Fit Method: MINSORB
Comment: a priori prediction of the adsorption behavior using a linear-free-energy-relationship (LFER) logK=(8.1+-0.3)+(0.90+-0.02)logK(-15.5) (hydrolysis constant); R=0.99
 
1 data sets were retrieved