RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results

Surface Complex Formation Data:

Mineral:	Montmorillonite
Reference:	BB05a
SCM Type:	NE - Non-electrostatic
Ligand:	Np<4+> - neptunium(IV)
Site Type:	»X(s)-OH
Equation:	»X(s)-OH + Np<4+> + 3 H2O ⇔ »X(s)-O-Np(OH)3 + 4 H<1+>
LogK:	0.1 LogK°_I=0 (Conversion to I = 0): 1.38
Experiment:	Sorption Isotherms
Ionic Strength:	0.1 mol/L NaClO4
Fit Method:	MINSORB
Comment:	a priori prediction of the adsorption behavior using a linear-free-energy-relationship (LFER) logK=(8.1+-0.3)+(0.90+-0.02)logK(-8.9) (hydrolysis constant); R=0.99

1 data sets were retrieved