RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results

Surface Complex Formation Data:

Mineral:	amorphous Silica
Reference:	SVV03
SCM Type:	CC - Constant Capacitance
Ligand:	UO2<2+> - uranyl(VI)
Site Type:	»Si-OH
Equation:	»SiOH + 3 UO2<2+> + 5 OH<1-> ⇔ »SiO-(UO2)3(OH)5 + H<1+>
LogK:	51.4 LogK°_I=0 (Conversion to I = 0): 52.12
Experiment:	Batch Sorption Experiments
Ionic Strength:	0.01 mol/L NaNO3
Temperature:	301.0 K
Solid/Liquid Ratio:	5.0 g/L
pH Range:	2-9
Ligand Concentration Range:	8.4E-5 mol/L
Fit Method:
Comment:	fit by Newton-Raphson's multidimensional non-linear regression method, using a computer code developed by Stamberg et al.; sigma of K=2.71E5 based on reaction XO- + (UO2)3(OH)5+ = XO(UO2)3(OH)5; logK = -3.02 for the reaction »Si-OH + (UO2)3(OH)5<+> = »Si-O-(UO2)3(OH)5 + H<1+>; formation constant in aqueous solution: 3UO2<2+> + 5OH<1-> = (UO2)3(OH)5<1+> with logK = 54.42

1 data sets were retrieved