RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

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Surface Complex Formation Data:

Mineral: Goethite
Reference: BPS00d
SCM Type: CDM - (CD-)MUSIC
Ligand: trimel<3-> - trimellitat (benzene-1,2,4-tricarboxylic acid)
Site Type: »Fe-triply
Equation: »Fe-triply-OH<-0.5> + trimel<3-> + 3 H<1+>  ⇔  »Fe-triply-OH2-H2trimel<-0.5>
LogK: 18.9 ± 0.02         LogK°I=0 (Conversion to I = 0):   20.18         LogK2.31 nm−2 (SSD-normalized):   18.90
Experiment: Potentiometric Titration
Ionic Strength: 0.1 mol/L NaNO3
Temperature: 298.15 K
Solid/Liquid Ratio: 5.0 g/L
pH Range: 3-9
Ligand Concentration Range: 2.24E-3. 3.36E-3. 6.71E-3 mol/L
Fit Method: FITEQL
Comment: {110} plane; equation 3H<+> + 2[=FeOH<-0.5>]{110} + trimel<3-> = [=FeOH2<+0.5>H2trimel<1->]{110}; for adsorption experiments: C1=2.00 F/m^2, C2=2.20 F/m^2
 
1 data sets were retrieved