Show Detailed Complexation Query Results
Surface Complex Formation Data:
Mineral: |
Anatase |
Reference: |
BHV01a |
SCM Type: |
CDM - (CD-)MUSIC |
Ligand: |
MoO4<2->
- molybdate
|
Site Type: |
»Ti-singly (w) |
Equation: |
14 »Ti-singly/doubly (w) + 7 MoO4<2-> + 23 H<1+> ⇔ 14 (»Ti-singly/doubly (w))Mo7O23<-5> + 4 H2O |
LogK: |
173.0 LogK°I=0 (Conversion to I = 0): 178.46
|
Experiment: |
Potentiometric Titration |
Ionic Strength: |
0.1 mol/L
NaNO3
|
Temperature: |
298.15 K |
Solid/Liquid Ratio: |
2.5 g/L |
pH Range: |
4-8 |
Fit Method: |
ECOSAT |
Comment: |
value for high-affinity site; no CO2; 6 singly and 8 doubly coordinated sites!!!; equation 6 »Ti-(w)-OH<-1/3> + 8 »Ti-O<-2/3> + 7 MoO4<2-> + 23 H<1+> = (»TiOH2<+2/3>)6(Ti2OH<+1/3>)8-Mo7O23(OH)<-5> + 4 H2O |
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1 data sets were retrieved
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