RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Hematite
Reference: G99
SCM Type: CC - Constant Capacitance
Ligand: B(OH)3<0> - boric acid
Site Type: »Fe-OH
Equation: »Fe-OH + B(OH)3<0>  ⇔  »Fe-O-B(OH)2 + H2O
LogK: 4.71        LogK°I=0 (Conversion to I = 0):   4.71
Experiment: Batch Sorption Experiments
Ionic Strength: 0.1 mol/L NaCl
Solid/Liquid Ratio: 100.0 g/L
pH Range: 2.5-10
Ligand Concentration Range: 0.463 mol/L
Fit Method: FITEQL
Comment: reanalysis of boron adsorption of [GG85] with postulation of both trigonal (B(OH)3) and tetrahedral (B(OH)4-) B surface complexes consistent with experimental ATR-FTIR results [SS95]
 
1 data sets were retrieved