RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Rutile
Reference: S05
SCM Type: TL - Triple Layer
Ligand: Tl<1+> - thallium
Site Type: »Ti-OH
Equation: »Ti-OH + Tl<1+>  ⇔  »Ti-O-Tl + H<1+>
LogK: -3.6         LogK2.31 nm−2 (SSD-normalized):   -3.26
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Ti-O<1-> + Tl<1+> = »Ti-O-Tl logK = 5.0 »Ti-OH = »Ti-O<1-> + H<1+> pK2 = -logK = 8.6 sum »Ti-OH + Tl<1+> = »Ti-O-Tl + H<1+> logK=5.0-8.6 = -3.6
 
1 data sets were retrieved