RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Hematite
Reference: S05
SCM Type: TL - Triple Layer
Ligand: Tl<1+> - thallium
Site Type: »Fe-OH
Equation: »Fe-OH + Tl<1+>  ⇔  »Fe-O-Tl + H<1+>
LogK: -7.0         LogK2.31 nm−2 (SSD-normalized):   -6.06
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M, log K for pHzpc 8.4-8.6 in brackets for pHzpc 9-9.5 »Fe-O<1-> + Tl<1+> = »Fe-O-Tl logK = 5.3 (5.0) »Fe-OH = »Fe-O<1-> + H<1+> pK2 = -logK = 12.3 sum »Fe-OH + Tl<1+> = »Fe-O-Tl + H<1+> logK=5.3(5.0)-12.3 = -7.0(-7.3)
 
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