RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Corundum
Reference: S05
SCM Type: TL - Triple Layer
Ligand: TMA<1+> - tetramethylammonium
Site Type: »Al-OH
Equation: »Al-OH + TMA<1+>  ⇔  »Al-O-TMA + H<1+>
LogK: -8.8         LogK2.31 nm−2 (SSD-normalized):   -10.19
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Al-O<1-> + TMA<1+> = »Al-O-TMA logK = 3.4 »Al-OH = »Al-O<1-> + H<1+> pK2 = -logK = 12.2 sum »Al-OH + TMA<1+> = »Al-O-TMA + H<1+> logK=3.4 -12.2 = -8.8
 
1 data sets were retrieved