RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Alumina
Reference: S05
SCM Type: TL - Triple Layer
Ligand: K<1+> - potassium
Site Type: »Al-OH
Equation: »Al-OH + K<1+>  ⇔  »Al-O-K + H<1+>
LogK: -8.6         LogK2.31 nm−2 (SSD-normalized):   -9.99
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Al-O<1-> + K<1+> = »Al-O-K logK = 2.9 »Al-OH = »Al-O<1-> + H<1+> pK2 = -logK = 11.5 sum »Al-OH + K<1+> = »Al-O-K + H<1+> logK=2.9 -11.5 = -8.6
 
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