RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Alumina
Reference: S05
SCM Type: TL - Triple Layer
Ligand: NH4<+> - ammonium
Site Type: »Al-OH
Equation: »Al-OH + NH4<+>  ⇔  »Al-O-NH4 + H<1+>
LogK: 1.0         LogK2.31 nm−2 (SSD-normalized):   -0.39
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Al-O<1-> + NH4<1+> = »Al-O-NH4 logK = 12.5 »Al-OH = »Al-O<1-> + H<1+> pK2 = -logK = 11.5 sum »Al-OH + NH4<1+> = »Al-O-NH4 + H<1+> logK=12.5 -11.5 = 1.0
 
1 data sets were retrieved