RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Quartz
Reference: S05
SCM Type: TL - Triple Layer
Ligand: TMA<1+> - tetramethylammonium
Site Type: »Si-OH
Equation: »SiOH + TMA<1+>  ⇔  »SiO-TMA + H<1+>
LogK: -2.8
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Si-O<1-> + TMA<1+> = »Si-O-TMA logK = 3.4 »Si-OH = »Si-O<1-> + H<1+> pK2 = -logK = 6.2 sum »Si-OH + TMA<1+> = »Si-O-TMA+ H<1+> logK= 3.4 -6.2 = -2.8
 
1 data sets were retrieved