RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: amorphous Silica
Reference: S05
SCM Type: TL - Triple Layer
Ligand: K<1+> - potassium
Site Type: »Si-OH
Equation: »SiOH + K<1+>  ⇔  »SiO-K + H<1+>
LogK: -5.3
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M, log K for Aerosil in brackets for Cabosil content »Si-O<1-> + K<1+> = »Si-O-K logK = 1.7(1.3) »Si-OH = »Si-O<1-> + H<1+> pK2 = -logK = 7.0 sum »Si-OH + K<1+> = »Si-O-K + H<1+> logK= 1.7(1.3) -7 = -5.3(-5.7)
 
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