RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Rutile
Reference: S05
SCM Type: TL - Triple Layer
Ligand: ClO4<1-> - perchlorate
Site Type: »Ti-OH
Equation: »Ti-OH + ClO4<1-> + H<1+>  ⇔  »Ti-OH2-ClO4
LogK: 4.4         LogK2.31 nm−2 (SSD-normalized):   4.74
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Ti-OH2<1+> + ClO4<1-> = »Ti-OH2-ClO4 logK = 2.1 »Fe-OH + H<1+> = »Fe-OH2<1+> -pK1 = logK = 2.3 sum »Ti-OH + ClO4<1->+ H<1+> = »Ti-OH2-ClO4 logK= 2.1+2.3 = 4.4
 
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