RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Corundum
Reference: S05
SCM Type: TL - Triple Layer
Ligand: CN<1-> - cyanide
Site Type: »Al-OH
Equation: »Al-OH + CN<1-> + H<1+>  ⇔  »Al-OH2-CN
LogK: 9.3         LogK2.31 nm−2 (SSD-normalized):   7.91
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Al-OH2<1+> + CN<1-> = »Al-OH2-CN logK = 2.7 »Al-OH + H<1+> = »Al-OH2<1+> - pK1 = logK = 6.6 sum »Al-OH + CN<1->+ H<1+> = »Al-OH2-CN logK= 2.7+6.6 = 9.3
 
1 data sets were retrieved