RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Corundum
Reference: S05
SCM Type: TL - Triple Layer
Ligand: ClO4<1-> - perchlorate
Site Type: »Al-OH
Equation: »Al-OH + ClO4<1-> + H<1+>  ⇔  »Al-OH2-ClO4
LogK: 8.7         LogK2.31 nm−2 (SSD-normalized):   7.31
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Al-OH2<1+> + ClO4<1-> = »Al-OH2-ClO4 logK = 2.1 »Al-OH + H<1+> = »Al-OH2<1+> - pK1 = logK = 6.6 sum »Al-OH + ClO4<1->+ H<1+> = »Al-OH2-ClO4 logK= 2.1+6.6 = 8.7
 
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