RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results

Surface Complex Formation Data:

Mineral:	Kaolinite
Reference:	MBLBK15
SCM Type:	NE - Non-electrostatic
Ligand:	Pu<4+> - plutonium(IV)
Site Type:	»X-OH
Equation:	»X-OH + Pu<4+> + 3 H2O ⇔ »X-O-Pu(OH)3 + 4 H<1+>
LogK:	-3.0 LogK°_I=0 (Conversion to I = 0): -1.72 LogK_{2.31 nm⁻²} (SSD-normalized): -3.41
Experiment:	Batch Sorption Experiments
Ionic Strength:	0.1 mol/L NaClO4
Solid/Liquid Ratio:	4.0 g/L
Ligand Concentration Range:	6.6E-13 mol/L
Fit Method:	PHREEQC
Comment:	Th(IV) literature sorption data are used as analogues for the corresponding Pu redox state, here: [BBBKT07] (see article); absence of CO2; also exchange constants given: 3 X-Na + Pu3+ = X3-Pu + Na+ with log K = 1 and X-Na + H+ = X-H + Na+ with log K = −1 (from [THB08])

1 data sets were retrieved