RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results

Surface Complex Formation Data:

Mineral:	Ferrihydrite
Reference:	LPSG17
SCM Type:	CDM - (CD-)MUSIC
Ligand:	VO4<3-> - vanadate
Site Type:	»Fe-singly
Equation:	2 »Fe-OH<0.5-> + VO4<3-> + 3 H<1+> ⇔ (»Fe-O)2-VOOH<1-> + 2 H2O
LogK:	36.87 LogK°_I=0 (Conversion to I = 0): 37.41 LogK_{2.31 nm⁻²} (SSD-normalized): 37.02
Experiment:	Batch Sorption Experiments
Ionic Strength:	0.01 mol/L NaNO3
pH Range:	3 - 10.5
Ligand Concentration Range:	5E-6; 5E-5 mol/L
Fit Method:	MINTEQ
Comment:	surface charging parameters of [TSPG13]; 0.3, 1, 3 mM Fe; original equation in the study: 2 »Fe-OH<0.5-> + HVO4<2-> + 2 H<1+> = (»Fe-O)2-VOOH<1-> + 2 H2O with logK = 23.20 (VO4<3-> + H<1+> = HVO4<2->, log K = 13.67 [PS04b])

1 data sets were retrieved