RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Goethite
Reference: RL98
SCM Type: TL - Triple Layer
Ligand: Cu<2+> - copper
Site Type: »Fe(s)-OH
Equation: »Fe(s)-OH + Cu<2+> + H2O  ⇔  »Fe(s)-O-Cu(OH) + 2 H<1+>
LogK: -3.409        LogK°I=0 (Conversion to I = 0):   -3.41         LogK2.31 nm−2 (SSD-normalized):   -0.29
Experiment: Sorption Isotherms
Ionic Strength: 0.0 mol/L NaClO4
pH Range: 6.07, 5.07, 4.07
Fit Method: FITEQL
Comment: I = 0.01and 0.1 M; modified TLM: indifferent electrolyte-surface interactions, electrolyte ions accumulate to screen surface charge, but do not form complexes with surface sites; experimental data can be replicated well by assuming three binding sites, data given here are valid for class 3 (third, non-copper binding site class, which represents 20-60% of the total sites, was allowed to bind copper); WSOS/DF=6.8
 
1 data sets were retrieved