RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

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Surface Complex Formation Data:

Mineral: Biotite
Reference: LPLZI20
SCM Type: NE - Non-electrostatic
Ligand: SeO3<2-> - selenite
Site Type: »X(w)-OH
Equation: »X(w)-OH + SeO3<2-> + 2 H<1+>  ⇔  »X(w)-OH2-HSeO3
LogK: 12.32        LogK°I=0 (Conversion to I = 0):   12.59
Experiment: Sorption Isotherms
Ionic Strength: 0.01 mol/L KClO4
Solid/Liquid Ratio: 20.0 g/L
pH Range: 7.7
Ligand Concentration Range: 1E-10 - 1E-3 mol/L
Fit Method: PHREEQC
Comment: original reaction equation in the study: »X(w)-OH + HSeO3<1-> + H<1+> = »X(w)-OH2-HSeO3 with log K = 3.78 (H<1+> + SeO3<2-> = HSeO3<1-> log K = 8.54 (ANDRA 2009, [EHL16]))
 
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