Helmholtz-Zentrum Dresden-Rossendorf |
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Surface Processes |
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Dr. Nina Maria Huittinen | ||
Phone: | +49 351 260 2148 | ||
Email: | n.huittinen![]() | ||
Link: | ORCID: 0000-0002-9930-2329 | ||
Address | Bautzner Landstraße 400 01328 Dresden | ||
Building/Office: | 801/P218 |
Scientific career
- Since 2013:Research associate, Helmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology
- 2008-2013:Ph.D. in radiochemistry at the University of Helsinki, Laboratory of Radiochemistry, Finland - "Sorption of trivalent actinides onto gibbsite, γ-alumina, and kaolinite - A spectroscopic study of An(III) interactions at the mineral-water interfaces"
- 2002-2007:M.Sc. in chemistry at the University of Helsinki, Finland
Research fields
- luminescence spectroscopy (TRLFS)
- actinide-bearing solid phases and solid solution formation
- actinide interactions at the solid/water interface
- actinide complexation reactions in aqueous environments
Projects
- since 01/2021: Project coordinator in the project "AcE" (Fundamental investigations of Actinide immobilization by incorporation into solid phases relevant for final disposal), funded by BMBF
- 2016-2019: Project leader in the project "ThermAc" (Aufklärung von Thermodynamik und Speziation von Actiniden bei höheren Temperaturen in Kombination von Schätzmethoden, spektroskopischen und quantenchemischen Methoden), funded by BMBF
- 2014-2016: Postdoctoral scientist in the project "Conditioning" (Fundamental studies on immobilization of long-lived radionuclides after incorporation into repository relevant ceramics), funded by BMBF
Teaching
- since 2017: Radioecology, Technische Universität Dresden
- 2015-2016: Radiochemistry, Dresden University of Applied Sciences
- 2012-2013: Fundamentals of chemistry for biology students, University of Helsinki
Supervision
Ph.D. or Licentiate (L)
- 10/2020: Henry Lösch - Spektroskopische Untersuchungen zur Komplexierung und zum Einbau von Actiniden: Uran(VI) Komplexierung mit gelösten Silikaten und Stabilität von Europium(III) Xenotim Solid Solutions, Technische Universität Dresden
- 07/2020: Manuel Eibl - Actinide interactions with Zr-bearing phases: Spectroscopic investigations of An3+ adsorption and incorporation reactions with zirconia, Technische Universität Dresden
- 02/2020 (L): Sinikka Virtanen - Competitive sorption reactions of An(V) and An(III) at the corundum (α–Al2O3) surface, University of Helsinki
- 09/2019 (L): Outi Elo - Neptunium(V) interactions with the bentonite clay barrier constituents bentonite, montmorillonite, corundum and granitic host rock, University of Helsinki
M.Sc. theses
- 2019: Isabelle Jesat - Komplexierung von Eu(III) und Cm(III) mit Phosphat bei höheren Temperaturen, Technische Universität Dresden
- 2018: Maximilian Demnitz - Temperaturabhängige Untersuchungen von Uran-Redoxreaktionen in halidhaltigen Lösungen, Technische Universität Dresden
- 2016: Henry Lösch - Site-selektive Fluoreszenz-Spektroskopie Untersuchungen an LnPO4-Keramiken für endlagerrelevante Zwecke, Dresden University of Applied Sciences
- 2016: Manuel Eibl - Sorptions- und Inkorporationsuntersuchungen von Actiniden an Korund und Zirkonium(IV)-oxid, Technische Universität Dresden
- 2015: Outi Elo – Np(V) sorption onto montmorillonite, corundum and bentonite colloids, University of Helsinki
- 2014: Jenna Knuutinen - Neptuniumin sorptio magnetiittiin, hematiittiin ja korundiin sekä neptuniumin spesiaatio liuoksessa ja mineraalipinnalla, University of Helsinki
Publications
2021
Sorption of Europium on Diatom Biosilica as Model of a “Green” Sorbent for f-Elements
Kammerlander, K. K. K.; Köhler, L.; Huittinen, N. M.; Bok, F.; Steudtner, R.; Oschatz, C.; Vogel, M.; Stumpf, T.; Brunner, E.
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Applied Geochemistry 126(2021), 104823
DOI: 10.1016/j.apgeochem.2020.104823
2020
Temperature-dependent luminescence spectroscopic investigations of U(VI) complexation with the halides F- and Cl-
Demnitz, M.; Hilpmann, S.; Lösch, H.; Bok, F.; Steudtner, R.; Patzschke, M.; Stumpf, T.; Huittinen, N. M.
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Dalton Transactions 49(2020), 7109-7122
DOI: 10.1039/D0DT00646G
Understanding the local structure of Eu3+ and Y3+ stabilized zirconia – Insights from luminescence and X–ray absorption spectroscopic investigations
Eibl, M.; Shaw, S.; Prieur, D.; Roßberg, A.; Wilding, M. C.; Hennig, C.; Morris, K.; Rothe, J.; Stumpf, T.; Huittinen, N. M.
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Journal of Materials Science 55(2020), 10095-10120
DOI: 10.1007/s10853-020-04768-3
Temperature‒dependent luminescence spectroscopic and mass spectrometric investigations of U(VI) complexation with aqueous silicates in the acidic pH‒range
Lösch, H.; Raiwa, M.; Jordan, N.; Steppert, M.; Steudtner, R.; Stumpf, T.; Huittinen, N. M.
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Environment International 135(2020), 105425
DOI: 10.1016/j.envint.2019.105425
2019
Coordination chemistry of f-block metal ions with ligands bearing bio-relevant functional groups
Götzke, L.; Schaper, G.; März, J.; Kaden, P.; Huittinen, N.; Stumpf, T.; Kammerlander, K. K. K.; Brunner, E.; Hahn, P.; Mehnert, A.; Kersting, B.; Henle, T.; Lindoy, L. F.; Zanoni, G.; Weigand, J. J.
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Coordination Chemistry Reviews 386(2019), 267-309
DOI: 10.1016/j.ccr.2019.01.006
U(VI) sorption on Ca-bentonite at (hyper)alkaline conditions – Spectroscopic investigations of retention mechanisms
Philipp, T.; Shams Aldin Azzam, S.; Rossberg, A.; Huittinen, N.; Schmeide, K.; Stumpf, T.
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Science of the Total Environment 676(2019), 469-481
DOI: 10.1016/j.scitotenv.2019.04.274
Cm(III) retention by calcium silicate hydrate (C-S-H) gel and secondary alteration phases in carbonate solutions with high ionic strength: A site-selective TRLFS study
Wolter, J.-M.; Schmeide, K.; Huittinen, N. M.; Stumpf, T.
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Scientific Reports 9(2019), 14255
DOI: 10.1038/s41598-019-50402-x
A spectroscopic study of trivalent cation (Cm3+ and Eu3+) sorption on monoclinic zirconia (ZrO2)
Eibl, M.; Virtanen, S.; Pischel, F.; Bok, F.; Lönnrot, S.; Shaw, S.; Huittinen, N.
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Applied Surface Science 487(2019), 1316-1328
DOI: 10.1016/j.apsusc.2019.05.012
Rare-Earth orthophosphates from atomistic simulations
Ji, Y.; Kowalski, P. M.; Kegler, P.; Huittinen, N.; Marks, N.; Vinograd, V.; Arinicheva, Y.; Neumeier, S.; Bosbach, D.
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Frontiers in Chemistry 7(2019), 197
DOI: 10.3389/fchem.2019.00197
A spectroscopic investigation of Eu3+ incorporation in LnPO4 (Ln = Tb, Gd1–xLux, x = 0.3, 0.5, 0.7, 1) ceramics
Lösch, H.; Hirsch, A.; Holthausen, J.; Peters, L.; Xiao, B.; Neumeier, S.; Schmidt, M.; Huittinen, N.
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Frontiers in Chemistry 7(2019), 94
DOI: 10.3389/fchem.2019.00094
Neptunium(V) transport in granitic rock: A laboratory scale study on the influence of bentonite colloids
Elo, O.; Hölttä, P.; Kekäläinen, P.; Voutilainen, M.; Huittinen, N.
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Applied Geochemistry 10331(2019), 31-39
DOI: 10.1016/j.apgeochem.2019.01.015
2018
Local structural effects of Eu3+ incorporation into xenotime-type solid solutions with different host cations
Xiao, B.; Lösch, H.; Huittinen, N.; Schmidt, M.
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Chemistry - A European Journal 24(2018)50, 13368-13377
DOI: 10.1002/chem.201802841
Complexation of trivalent lanthanides (Eu) and actinides (Cm) with aqueous phosphates at elevated temperatures
Jordan, N.; Demnitz, M.; Lösch, H.; Starke, S.; Brendler, V.; Huittinen, N.
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Inorganic Chemistry 57(2018)12, 7915-7024
DOI: 10.1021/acs.inorgchem.8b00647
A spectroscopic and computational study of Cm3+ incorporation in lanthanide phosphate rhabdophane (LnPO4·0.67H2O) and monazite (LnPO4)
Huittinen, N.; Scheinost, A. C.; Ji, Y.; Kowalski, P. M.; Arinicheva, Y.; Wilden, A.; Neumeier, S.; Stumpf, T.
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Inorganic Chemistry 57(2018), 6252-6265
DOI: 10.1021/acs.inorgchem.8b00095
Sorption competition and kinetics of trivalent cations (Eu, Y and Cm) on corundum (α-Al2O3): a batch sorption and TRLFS study
Virtanen, S.; Meriläinen, S.; Eibl, M.; Rabung, T.; Huittinen, N.
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Applied Geochemistry 92(2018), 71-81
DOI: 10.1016/j.apgeochem.2018.02.011
2017
Probing structural homogeneity of La1-xGdxPO4 monazite-type solid solutions by combined spectroscopic and computational studies
Huittinen, N.; Arinicheva, Y.; Kowalski, P. M.; Vinograd, V. L.; Neumeier, S.; Bosbach, D.
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Journal of Nuclear Materials 486(2017), 148-157
DOI: 10.1016/j.jnucmat.2017.01.024
Batch sorption and spectroscopic speciation studies of neptunium uptake by montmorillonite and corundum
Elo, O.; Müller, K.; Ikeda-Ohno, A.; Bok, F.; Scheinost, A.; Hölttä, P.; Huittinen, N.
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Geochimica et Cosmochimica Acta 198(2017), 168-181
DOI: 10.1016/j.gca.2016.10.040
2016
Using Eu3+ as an atomic probe to investigate the local environment in LaPO4–GdPO4 monazite end-members
Huittinen, N.; Arinicheva, Y.; Schmidt, M.; Neumeier, S.; Stumpf, T.
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Journal of Colloid and Interface Science 483(2016), 139-145
DOI: 10.1016/j.jcis.2016.08.027
The specific sorption of Np(V) on the corundum (α-Al2O3) surface in the presence of trivalent lanthanides Eu(III) and Gd(III): a batch sorption and XAS study
Virtanen, S.; Bok, F.; Ikeda-Ohno, A.; Rossberg, A.; Lützenkirchen, J.; Rabung, T.; Lehto, J.; Huittinen, N.
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Journal of Colloid and Interface Science 483(2016), 334-342
DOI: 10.1016/j.jcis.2016.08.035
2013
Cycloisomerization of 2-alkynylanilines to indoles catalyzed by carbon-supported gold nanoparticles and subsequent homocoupling to 3,3′-biindoles
Perea-Buceta, J. E.; Wirtanen, T.; Laukkanen, O.-V.; Mäkelä, M. K.; Nieger, M.; Melchionna, M.; Huittinen, N.; Lopez-Sanchez, J. A.; Helaja, J.
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Angewandte Chemie - International Edition 52(2013)45, 11835-11839
DOI: 10.1002/anie.201305579
Huittinen, N.; Sarv, P:;Lehto, J.
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Appl. Clay Sci. 80-81(2013), 182-188
DOI-Link: https://doi.org/10.1016/j.clay.2013.04.005
2012
Huittinen, N.; Rabung, Th.; Schnurr, A.; Hakanen, M.; Lehto, J.; Geckeis, H.
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Geochim. Cosmochim. Acta 99(2012), 100-109
DOI-Link: https://doi.org/10.1016/j.gca.2012.09.032
2011
Huittinen, N.; Sarv, P.; Lehto, J.
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J. Colloid Interface Sci. 361(2011), 252-258
DOI-Link: https://doi.org/10.1016/j.jcis.2011.05.055
2010
Huittinen, N.; Rabung, Th.; Andrieux, P.; Lehto, J.; Geckeis, H.
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Radiochim. Acta 98(2010), 613-620
DOI-Link: https://doi.org/10.1524/ract.2010.1761
2009
Huittinen, N.; Rabung, Th.; Lützenkirchen, J.; Mitchell, S.C.; Bickmore, B.R.; Lehto, J.; Geckeis, H.
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J. Colloid Interface Sci. 332(2009), 158-164
DOI-Link: https://doi.org/10.1016/j.jcis.2008.12.017