Synthesis and Characterization of Homo- and Heteroleptic Neptunium(IV) Heteroarylalkenolate Complexes

Grödler, D.; Kaden, P.; Sperling, J. M.; Rotermund, B. M.; Scheibe, B.; Beck, N. B.; Lichtenberg, A.; Albrecht, T. E.; Mathur, S.; Gericke, R.

• Inorganic Chemistry (2025)
  DOI: 10.1021/acs.inorgchem.4c04521

A Series of AnVIO22+ Complexes (An = U, Np, Pu) with N3O2‑Donating Schiff-Base Ligands: Systematic Trends in the Molecular Structures and Redox Behavior

Takeyama, T.; Tsushima, S.; Gericke, R.; Duckworth, T.; Kaden, P.; März, J.; Takao, K.

• Inorganic Chemistry 64(2025)3, 1313-1322
  DOI: 10.1021/acs.inorgchem.4c04185

Comparative analysis of tetravalent actinide Schiff base complexes: influence of donor and ligand backbone on molecular geometry and metal binding

Duckworth, T.; Gericke, R.; Kaden, P.; Köhler, L.; Näder, A.; März, J.; Patzschke, M.; Stumpf, T.; Schmidt, M.

Related publications

• Data publication: Comparative analysis of tetravalent actinide Schiff base …
  ROBIS: 39431 HZDR-primary research data are used by this (Id 39430) publication

• Chemistry - A European Journal 31(2025)1, e202403081
  Online First (2024) DOI: 10.1002/chem.202403081

Cyanopyridine adducts of SiF₄ and SiCl₄

Riedel, S.; Brendler, E.; Gericke, R.; Kroke, E.; Wagler, J.

• Zeitschrift für Naturforschung Section B 79(2024)12, 675-685
  DOI: 10.1515/znb-2024-0085

Utility of Interchangeable Coordination Modes of N,N’-Dialkyl-2,6-Pyridinediamide Tridentate Pincer Ligands for Efficient and Selective Separation of Pd(II) and Zr(IV) from High-level Radioactive Liquid Waste

Orino, T.; Cao, Y.; Tashiro, R.; Takeyama, T.; Gericke, R.; Tsushima, S.; Takao, K.

• Inorganic Chemistry 63(2024)52, 24647-24661
  DOI: 10.1021/acs.inorgchem.4c03844

Two Modifications of Nitrilotris(methylenephenylphosphinic) Acid: A Polymeric Network with Intermolecular (O=P–O–H)₃ vs. Monomeric Molecules with Intramolecular (O=P–O–H)₃ Hydrogen Bond Cyclotrimers

Knerr, S.; Brendler, E.; Gericke, R.; Kroke, E.; Wagler, J.

• Crystals 14(2024), 662
  DOI: 10.3390/cryst14070662
  Cited 1 times in Scopus

6-(6-Methyl-1,2,4,5-tetrazine-3-yl)-2,2-bipyridine: A N-donor ligand for the separation of lanthanides(III) and actinides(III)

Greif, G.; Sauerwein, F. S.; Weßling, P.; Duckworth, T.; Patzschke, M.; Gericke, R.; Sittel, T.; März, J.; Wilden, A.; Modolo, G.; Panak, P. J.; Roesky, P. W.

• Inorganic Chemistry 63(2024)33, 15259-15269
  DOI: 10.1021/acs.inorgchem.4c01793

Structure, covalency, and paramagnetism of homoleptic actinide and lanthanide amidinate complex

Hong, B.; Näder, A.; Sawallisch, T. E.; Bode, T.; Fichter, S.; Gericke, R.; Kaden, P.; Patzschke, M.; Stumpf, T.; Schmidt, M.; März, J.

Related publications

• Data publication: Structure, covalency, and paramagnetism of homoleptic …
  ROBIS: 39343 HZDR-primary research data are used by this (Id 39342) publication

• Inorganic Chemistry 63(2024)38, 17488-17501
  DOI: 10.1021/acs.inorgchem.4c01901

Preparation and characterization of Mn(II)Mn(III) complexes with relevance to class Ib ribonucleotide reductases

Doyle, L. M.; Bienenmann, R. L. M.; Gericke, R.; Xu, S.; Farquhar, E. R.; Que Jr, L.; McDonald, A. R.

• Journal of Inorganic Biochemistry 257(2024), 112583
  DOI: 10.1016/j.jinorgbio.2024.112583

A Co(II)-Hydroxide Complex That Converts Directly to a Co(II)-Acetamide during Catalytic Nitrile Hydration

Heim, P.; Biswas, S.; Lopez, H.; Gericke, R.; Twamley, B.; McDonald, A. R.

• Inorganic Chemistry 63(2024), 7896-7902
  DOI: 10.1021/acs.inorgchem.4c00754

Triply Bonded Pancake π-Dimers Stabilized by Tetravalent Actinides

Barluzzi, L.; Ogilvie, S. P.; Dalton, A. B.; Kaden, P.; Gericke, R.; Mansikkamäki, A.; Giblin, S. R.; Layfield, R. A.

• Journal of the American Chemical Society 146(2024)6, 4234-4241
  DOI: 10.1021/jacs.3c13914
  Cited 5 times in Scopus

Optimisation of synthesis procedures and structural investigation of monazite-cheralite solid solutions

Lender, T.; Braga Ferreira Dos Santos, L.; Gericke, R.; Huittinen, N. M.; Peters, L.

• MRS Advances 9(2024), 433-438
  DOI: 10.1557/s43580-024-00792-6
  Cited 1 times in Scopus

The Hexacoordinate Si Complex SiCl₄(4-Azidopyridine)₂—Crystallographic Characterization of Two Conformers and Probing the Influence of SiCl₄-Complexation on a Click Reaction with Phenylacetylen

Riedel, S.; Gerwig, M.; Gerlach, D.; Brendler, E.; Gericke, R.; Kroke, E.; Wagler, J.

• Inorganics 11(2023)12, 473
  DOI: 10.3390/inorganics11120473
  Cited 1 times in Scopus

Lewis Acid-Base Adducts of α-Amino Acid-Derived Silaheterocycles and N-Methylimidazole

Seidel, A.; Gericke, R.; Kutzner, B.; Wagler, J.

• Molecules 28(2023)23, 7816
  DOI: 10.3390/molecules28237816
  Cited 1 times in Scopus

Fate of Oxidation States at Actinide Centers in Redox-Active Ligand Systems Governed by Energy Levels of 5f Orbitals

Takeyama, T.; Tsushima, S.; Gericke, R.; Kaden, P.; März, J.; Takao, K.

• Chemistry - A European Journal 29(2023)69, e202302702
  DOI: 10.1002/chem.202302702
  Cited 2 times in Scopus

Pd–Si complexes of the type ClPd(μ²-pyO)₄SiR (R = Me, Ph, Bn, Allyl, κO-(pyO)PdCl(η³-allyl); pyO = pyridine-2-olate): The influence of substituent R on the Pd–Si bond

Wagler, J.; Gericke, R.

• Polyhedron 245(2023), 116663
  DOI: 10.1016/j.poly.2023.116663
  Cited 3 times in Scopus

Ge–Cu-Complexes Ph(pyO)Ge(μ²-pyO)₂CuCl and PhGe(μ²-pyO)₄CuCl - Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems

Wagler, J.; Gericke, R.

• Molecules 28(2023)14, 5442
  DOI: 10.3390/molecules28145442
  Cited 1 times in Scopus

Formation of Heterobimetallic Complexes by Addition of d¹⁰-Metal Ions to [(Me₃P)_xM(2-C₆F₄PPh₂)₂] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions

Gericke, R.; Bennett, M. A.; Privér, S.; Bhargava, S.

• Inorganic Chemistry 62(2023)23, 8846-8862
  DOI: 10.1021/acs.inorgchem.3c00311
  Cited 3 times in Scopus

Evidence for a High-Valent Iron-Fluoride That Mediates Oxidative C(sp3)‐H Fluorination

Panda, C.; Anny-Nzekwue, O.; Doyle, L. M.; Gericke, R.; McDonald, A. R.

• JACS Au 3(2023), 919
  DOI: 10.1021/jacsau.3c00021
  Cited 12 times in Scopus

Synthesis and Characterization of a Masked Terminal Nickel-Oxide Complex

Heim, P.; Spedalotto, G.; Lovisari, M.; Gericke, R.; O’Brien, J.; Farquhar, E. R.; McDonald, A. R.

• Chemistry - A European Journal 29(2023)21, e202203840
  DOI: 10.1002/chem.202203840
  Cited 5 times in Scopus

Aromatic and aliphatic hydrocarbon hydroxylation via a formally Ni(IV)=O oxidant

Heim, P.; Gericke, R.; Spedalotto, G.; Lovisari, M.; Farquhar, E. R.; McDonald, A. R.

• Dalton Transactions 52(2023), 2663-2671
  DOI: 10.1039/D2DT03949D
  Cited 3 times in Scopus

Copper Complexes of Silicon Pyridine-2-olates RSi(pyO)₃ (R = Me, Ph, Bn, Allyl) and Ph₂Si(pyO)₂

Seidel, A.; Gericke, R.; Brendler, E.; Wagler, J.

• Inorganics 11(2023)1, 2
  Online First (2022) DOI: 10.3390/inorganics11010002
  Cited 4 times in Scopus

Deconvoluting Cr States in Cr-Doped UO2 Nuclear Fuels via Bulk and Single Crystal Spectroscopic Studies

Murphy, G. L.; Gericke, R.; Gilson, S.; Bazarkina, E.; Roßberg, A.; Kaden, P.; Thümmler, R.; Klinkenberg, M.; Henkes, M.; Kegler, P.; Svitlyk, V.; Marquardt, J.; Lender, T.; Hennig, C.; Kvashnina, K.; Huittinen, N. M.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265

Related publications

• DOI: 10.1107/S1600577520014265 is cited by this (Id 35473) publication
• Data publication: Deconvoluting Cr States in Cr-Doped UO2 Nuclear Fuels via …
  ROBIS: 36731 HZDR-primary research data are used by this (Id 35473) publication

• Nature Communications 14(2023), 2455
  DOI: 10.1038/s41467-023-38109-0
  Cited 7 times in Scopus

Molecular Structures of the Silicon Pyridine-2-(thi)olates Me3Si(pyX), Me2Si(pyX)2 and Ph2Si(pyX)2 (py = 2-Pyridyl, X = O, S), and Their Intra- and Intermolecular Ligand Exchange in Solution

Seidel, A.; Weigel, M.; Ehrlich, L.; Gericke, R.; Brendler, E.; Wagler, J.

• Crystals 12(2022)8, 1054-1054
  DOI: 10.3390/cryst12081054
  Cited 4 times in Scopus

P–Ru-Complexes with a Chelate-Bridge-Switch: A Comparison of 2-Picolyl and 2-Pyridyloxy Moieties as Bridging Ligands

Ehrlich, L.; Gericke, R.; Brendler, E.; Wagler, J.

• Molecules 27(2022)9, 2778
  DOI: 10.3390/molecules27092778

Coordination and Electrochemical Switching on Paddle-Wheel Complexes Containing an As−Ru or a Sb−Ru Axis

Gericke, R.; Wagler, J.

• Inorganic Chemistry 60(2021)23, 18122-18132
  DOI: 10.1021/acs.inorgchem.1c02735
  Cited 4 times in Scopus

Rapid Iron(III)-Fluoride Mediated Hydrogen Atom Transfer

Panda, C.; Doyle, L. M.; Gericke, R.; McDonald, A. R.

• Angewandte Chemie - International Edition 60(2021)50, 26281-26286
  DOI: 10.1002/anie.202112683
  Cited 18 times in Scopus

Comparing Metal–Halide and −Oxygen Adducts in Oxidative C/O–H Activation: Au(III)–Cl versus Au(III)–OH

Lovisari, M.; Gericke, R.; Twamley, B.; McDonald, A. R.

• Inorganic Chemistry 60(2021), 15610-15616
  DOI: 10.1021/acs.inorgchem.1c02222
  Cited 12 times in Scopus