Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

1 Publication
Synthesis and structural characterization of the first neptunium based metal-organic frameworks incorporating {Np6O8} hexanuclear cluster
Martin, N. P.ORC; März, J.; Feuchter, H.; Duval, S.; Roussel, P.; Henry, N.; Petricek, V.; Ikeda-Ohno, A.ORC; Loiseau, T.ORC; Volkringer, C.ORC
Successful synthesis of the first transuranium Metal-Organic Frameworks (MOFs) involving neptunium(IV) (Np(IV) is reported. These compounds were obtained from the controlled hydrolysis of Np(IV) in the presence of dicarboxylate ligands. The final structures contain the [Np6O4(OH)4(H2O)6]12+ unit, which were never cristallized before with tetravalent neptunium, associated with ditopic ligands.
Keywords: actinides, neptunium, metal-organic frameworks, carboxylate, coordination chemistry, structure, X-ray diffraction

Publ.-Id: 27442 - Permalink