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Trivalent Lanthanide and Actinide Incorporation into Zirconium(IV) Oxide – Spectroscopic Investigations of Defect Fluorite Structures

Eibl, M.ORC; Shaw, S.; Hennig, C.; Morris, K.; Stumpf, T.; Huittinen, N. M.
The incorporation of trivalent lanthanides and actinides into zirconia (ZrO₂) was studied using PXRD and spectroscopic methods (EXAFS, TRLFS). In highly doped cubic zirconia three Eu(III) incorporation species could be found using TRLFS. A surface associated species with an excitation maximum of 578.1 nm and two bulk incorporation species with excitation maxima at 579.0 and 579.7 nm were found.
  • Lecture (Conference)
    17th International Conference on the Chemistry and Migration Behavior of Actinides and Fission Products in the Geosphere., 15.-20.09.2019, Kyoto, Japan

Permalink: https://www.hzdr.de/publications/Publ-30018
Publ.-Id: 30018