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Influence of Cr substitution on the reversibility of the magnetocaloric effect in Ni-Cr-Mn-In Heusler alloys

Salazar Mejia, C.; Devi, P.; Singh, S.; Felser, C.; Wosnitza, J.

We present the effect of substitution-induced pressure on the reversibility of the magnetocaloric effect (MCE) in Ni2CrxMn1.4−xIn0.6 (x = 0.1, 0.2, 0.3) alloys, through characterization in pulsed magnetic fields.We measured the adiabatic temperature change ΔTad directly during applied magnetic field pulses of 2 and 6 T. We paid special attention to the reversibility of ΔTad. The substitution of Mn by Cr in Ni2Mn1.4In0.6 leads to a negative pressure, as evidence by the increase of the lattice parameters, which shifts the martensitic transition towards lower temperatures and enhances the ferromagnetism of the martensite phase.We found a large value of ΔTad = −7 K at T = 270 K for the sample with x = 0.1 for a field change of 6 T. We discuss the reversibility of the MCE in these alloys in terms of the Clausius-Clapeyron equation.


  • Secondary publication expected

Publ.-Id: 33244