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Manifestation of the Jahn-Teller effect in elastic moduli of strontium fluorite crystals doped with chromium ions

Averkiev, N. S.; Bersuker, I. B.; Gudkov, V. V.; Zhevstovskikh, I. V.; Sarychev, M. N.; Zherlitsyn, S.; Yasin, S.; Shakurov, G. S.; Ulanov, V. A.; Surikov, V. T.

Attenuation and phase velocity of ultrasound have been measured in strontium fluoride single crystal doped with chromium in the temperature range of 4 – 185 K at 56 -162 MHz. Anomalies have been found for all the normal modes corresponding to the non-vanishing elastic moduli of a cubic crystal. Interpretation of the observed anomalies has been done in the frame work of relaxation in the system of Jahn-Teller (JT) complexes CrF8 subject to full T2g X (eg+t2g)JT problem. Relaxation time has been calculated from the experimental data on ultrasonic attenuation and adiabatic and isothermal contributions of the impurity subsystem to the total elastic moduli have been obtained.

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Publ.-Id: 25732