Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

The nuclear microprobe that was installed in 1994 at the Ion Beam Center of the Helmholtz-Zentrum Dresden-Rossendorf [1], has been in operation up to 2014 with only minor changes. After 20 years it became necessary to make an upgrade to replace old components and bring the setup up to current standards of technology and good working practice.
The major drawback of the old system was the optical microscope, especially the poor resolution and low contrast and brightness. However, a good optical image is essential to localise the areas of interest on, for example, large geological samples. Since the focused beam of MeV ions and the corresponding detectors is the principal investigative tool, any other equipment such as an optical microscope has to be designed around this device. A new microscope has been installed for which the first light-collecting lens is mounted directly into the chamber at only a few centimetres from the sample. The light is then guided over large mirrors and focussed on a CCD camera outside the sample chamber. The illuminating light is fed in through the lenses instead of using an external light source as in the old system. In addition, there is also a light source opposite to the microscope, allowing transmission illumination including through a polarising filter making polarised imaging possible.
Other improvements concern the control of the scanning system as well as the control and monitoring of all relevant experimental parameters. The control of the scan magnets is done by custom-designed hardware to guarantee real-time execution of the scanning without the need for a computer running a real-time operating system. Controlling and monitoring of the experiment are implemented to facilitate easy and secure operation of the microprobe by the user with special emphasis on operation by un-experienced users, since the device is part of the user facility IBC. All standard IBA techniques like PIXE, PIGE, RBS, NRA, ERDA and STIM are available and, in addition, a Channeltron detector has been installed to detect secondary electrons that allow quick imaging of the measurement area.
Technical details and first test measurements with the new system are presented.

[1] F. Herrmann, D. Grambole, Nucl. Instr. Meth. B 104 (1995) 26.

As 3-dimensional field sensors require one part being susceptible to perpendicular fields, thin film GMR stacks with a linear and reversible response to such fields are of interest for the development of monolithic sensor devices. Stacks with such a behavior can be achieved by combining a pinning layer with perpendicular easy axis and a free layer with perpendicular hard axis. Furthermore, the stray field of the pinning layer can be minimized and its coercivity enhanced if a ferrimagnet (or antiferromagnet) is used. For the present study, TbxCo100−x alloys have been chosen as the pinning layer material and Ni81Fe19 for the free layer. The single layers have been characterized by SQUID-VSM measurements, the complete layer stack by magneto-resistance measurements. Initial films confirm the expected behavior and exhibit a change in resistivity of 5% in a field range of 10 kOe. Further films will be optimized regarding their magnetic and electric properties. They shall be micro-structured then and equipped with bottom contacts through the substrate.

Nanostructured ferrimagnetic Tb-Fe alloy thin films were prepared on pre-patterned substrates as underlying template, consisting of nanodot arrays with a dot diameter of 30 nm and a period of 60 nm. Two distinct magnetic configuration are possible, one where the magnetic material on the nanodot and in the trenches is decoupled from each other for film thicknesses below the nanodot height, and the other where full exchange coupling between magnetic material on the dots and in the trenches is effective for magnetic films thicker than the nanodot height. Regardless, of the magnetic configuration the reversal of the magnetic material on top of the nanodots is found to be nucleation dominated, while the magnetic material in the trenches reverses via domain wall propagation, as confirmed by in-field magnetic force microscopy. The distinct behavior in this system is attributed to the reduced exchange stiffness followed by relatively narrow domain walls (approx. 3-4 nm) present in these rare earth - transition metal alloys. A systematic study of magnetic properties on nanostructured Tb-Fe alloy films as a function of composition and film thickness will be presented.

In this work, we aimed to investigate the effects of two different plasma sources on the electrical properties of low-temperature plasma-assisted atomic layer deposited (PA-ALD) AlN thin films. To compare the electrical properties, 50 nm thick AlN films were grown on p-type Si substrates at 200 °C by using an inductively coupled RF-plasma (ICP) and a stainless steel hollow cathode plasma-assisted (HCPA) ALD systems. Al/AlN/p-Si metal-insulatorsemiconductor (MIS) capacitor devices were fabricated and capacitance versus voltage (C-V) and current-voltage (I-V) measurements performed to assess the basic important electrical parameters such as dielectric constant, effective charge density, flat-band voltage, breakdown field, and threshold voltage. In addition, structural properties of the films were presented and compared. The results show that although HCPA-ALD deposited AlN thin films has structurally better and has a lower effective charge density (Neff) value than ICP-ALD deposited AlN films, those films have large leakage current, low dielectric constant, and low breakdown field. This situation was attributed to the involvement of Si atoms into the AlN layers during the HCPA-ALD processing leads to additional current path at AlN/Si interface and might impair the electrical properties.

Strong perpendicular anisotropy systems consisting of Co/Pt or Co/Pd multilayer stacks that are antiferromagnetically coupled via thin Ru or Ir layers have been used as model systems to study the competition between interlayer exchange, perpendicular anisotropy and long-range dipolar interactions [1,2]. The typical layer structure for such systems is illustrated in Fig.1 for a [(Co/Pt)Co/Ru] multilayer system.
Magnetometry and Magnetic Force Microscopy (MFM) studies of such systems reveal complex magnetic phases with a mix of tilted versus non-tilted and antiferromagnetic (AF) versus ferromagnetic (FM) phases depending on the dominance of the various energy contributions. For thin Co/Pt multilayer blocks AF-exchange is dominating and the magnetic structure remains laterally uniform at any stage of the reversal process and is for even number of AF-coupled blocks characterized by bulk and surface spin-flop transitions as shown on the left in Fig. 2. For thicker Co/Pt multilayer blocks the perpendicular anisotropy term takes the lead and prevents any tilting of the spins away from the easy axis normal to the film plane. In this case the reversal into the AF-coupled remanent state occurs via FM/AFM domain formation as shown in the middle part of Fig. 2. For even thicker Co/Pt multilayer blocks the AF-exchange is also overcome by the demagnetization energy and the uniform AF remanent state is replaced by a laterally heterogeneous FM stripe domain state, as illustrated in Fig. 2 on the right.
Ion beam irradiation may be able to control the rich variety of phases in this system on a nanoscopic length scale, thus allowing for a lateral co-existance of all these phases within one and the same sample. This could allow fabricating an infrastructure for controlled spin-wave propagation, such as motivated by recent studies for domain walls and perpendicular anisotropy systems [3,4]. Examples of such initial studies will be discussed.

We report terahertz pump-probe experiments on multilayer graphene that measure both reflected and transmitted radiation. The data reveal complex reflection and transmission dynamics which calculations attribute to a transition from interband to intraband processes.

We investigate the nonlinear plasmonic absorption in graphene ribbons by THz pump-probe spectroscopy. The optical nonlinearity is increased by more than one order of magnitude, which is in excellent agreement with theoretical calculations.

Off-axis electron holography (EH) is a powerful TEM technique that provides access to the 2D projections of both the electric potential, i.e., mainly the mean inner potential (MIP) contribution, and the components of the magnetic induction (B-field) that lie perpendicular to the electron beam path.
Currently, 2D magnetic induction maps may be obtained with a spatial resolution of a few nanometer [1,2] and a sensitivity of a few millitesla [2]. Frequently, however, nanomagnetic applications, such as spin valves or magnetic nanowires require a characterization of the 3D magnetic induction distribution.
In the following, we therefore elaborate on how electron holography is combined with electron tomography to electron holographic tomography (EHT) [1,3] in order to retrieve the 3D distribution of the magnetic induction.
As shown in Fig. 1, the tomographic reconstruction of one B-field component starts with acquiring a tilt series of electron holograms that is subsequently reconstructed to obtain a tilt series of phase images. In order to collect data for the crucial separation of electric and magnetic phase shifts, either a tilt series over 360° (Fig. 1), or two tilt series, one before and one after reversing the direction of magnetization in the specimen (e.g., using the TEM objective lens or flipping the sample up-side down in the holder), have to be acquired. Before separation of electric/magnetic phase shifts by computing half of the sum/difference of corresponding image pairs, relative displacements, rotations, and direction dependent magnification changes between the two phase images are corrected. Also, the alignment of the whole tilt series, i.e., an accurate tilt axis determination and subpixel displacements correction, is of crucial importance. Finally, from the aligned tilt series, tomograms of both the electric potential and the B-field component parallel to the tilt axis are reconstructed with tomographic reconstruction algorithms.
Fig. 2 shows two recent EHT studies revealing the B-field within a Co nanowire (NW) [4] and a Co2FeGa Heusler alloy NW [5] both with spatial resolution higher than 10 nm. The reconstructions of the dominant axial component of the magnetic induction exhibit two interesting features for each case: At the Co NW, a small inversion domain at the apex was observed, whereas at the Co2FeGa NW, a magnetic dead layer of 10 nm width was found. These results were achieved by means of dedicated TEM sample holders for acquisition, in combination with advanced in-house developed software packages for acquisition, alignment and tomographic reconstruction. The powerful approach presented here is widely applicable to a broad range of 3D magnetic nanostructures and may trigger the progress of novel spintronic nonplanar nanodevices. In a next step the reconstruction of all B-field components is envisaged.
References:
[1] P A Midgley and R E Dunin-Borkowski, Nat. Mater. 8 (2009) p. 271.
[2] M Körner, F Röder, K Lenz, M Fritzsche, J Lindner, H Lichte and J Fassbender, Small 10 (2014) p. 5161.
[3] D Wolf, A Lubk, F Röder and H Lichte, Current Opinion in Solid State and Materials Science 17(2013) p. 126.
[4] D Wolf et al., Chem. Mater. 27 (2015) p. 6771.

Graphene, the two-dimensional allotrope of carbon, is characterized by a gapless linear band structure. This unique band structure is directly related to some unusual phenomena regarding the ultrafast Coulomb dynamics in the material. The understanding of this dynamics is of vital interest, both from a fundamental as well as from an application oriented point of view. The elastic Coulomb scattering is the main mechanism for thermalization of a non-equilibrium carrier distribution.
We investigate the carrier dynamics in a regime, where scattering via optical phonons is strongly suppressed. To this end, time resolved spectroscopy was performed with radiation of photon energies around 75 meV, which is smaller than the optical phonon energy (~200 meV). In polarization resolved experiments using co- and cross-polarized linearly polarized pump and probe beams, respectively, the Coulomb scattering dynamics is investigated. We find a two-fold nature of this process, namely very fast (fs timescale) collinear Coulomb scattering but surprisingly slow (ps-timescale) non-collinear scattering [1].
In the presence of a magnetic field, the linear band structure of graphene splits up into a series of non-equidistant Landau levels. Studying the transitions between the lowest Landau levels in pump-probe and four-wave mixing experiments, we find evidence for strong Auger scattering [2, 3].

[1] J. C. König-Otto, M. Mittendorff, T. Winzer, F. Kadi, E. Malic, A. Knorr, C. Berger, W. A. de Heer, A. Pashkin, H. Schneider, M. Helm, and S. Winnerl, Phys. Rev. Lett. 117, 087401 (2016).

[2] M. Mittendorff, F. Wendler, E. Malic, A. Knorr, M. Orlita, M. Potemski, C. Berger, W. A. de Heer, H. Schneider, M. Helm, and S. Winnerl, Nature Phys. 11, 75 (2015).

[3] J. C. König-Otto, Y. Wang, A. Belyanin, C. Berger, W. A. de Heer, M. Orlita, A. Pashkin, H. Schneider, M. Helm, and S. Winnerl (submitted).

Infrared and THz free-electron lasers are interesting sources for near-field investigations as they are tunable in a range where suitable tabletop sources exist only at particular frequencies. The free-electron laser FELBE at Dresden covers the frequency range from 1.3–75 THz with narrowband (~ 1 % spectral width) radiation. We briefly show for the low-frequency region of FELBE (1.3–75 THz) that scattering near-field microscopy can be performed with a constant spatial resolution of 50 nm, which is determined by the diameter of the scattering tip. For the longest wavelength, this corresponds to /4600 [1]. Mainly, we present results on a superlens, which consists of a doped GaAs layer sandwiched between two intrinsic GaAs layers. Superlensing is expected when the condition 〖Re(ε〗_GaAs^doped)=〖-Re(ε〗_GaAs^intrinsic) is met in the spectral vicinity of the plasmonic resonance. Here, the Drude response in the doped layer induces resonant enhancement of evanescent waves accompanied by a significantly improved spatial resolution at radiation wavelengths around 15 THz (see Fig. 1) [2]. The resonance frequency is adjustable by changing the doping concentration. Compared to superlenses based on phononic resonances the plasmonic superlance features a somewhat broader range of the resonant response. Such a tunable superlense consisting of a single semiconductor material is
a versatile device to enhance signal and spatial resolution in near-field imaging of buried structures.

We review our results ion the carrier dynamics in graphene and present an applacitation example, namely a high-speed ultra-broadband detector.

The linear band structure of graphene results in a non-equidistant spectrum of Landau levels (LLs). While transport phenomena have been widely explored after the discovery of graphene in 2004, the ultrafast optical properties of Landau-quantized graphene have been investigated only recently. Predictions of very strong nonlinearities [1], carrier multiplication [2] and Landau-level gain [3] make the system very interesting both from a fundamental and an application-oriented point of view.
Here we present experiments complemented by microscopic theory on the population and polarization dynamics in the subsystem of Landau levels -1, 0 and 1. To this end, multilayer epitaxial graphene in a magnetic field of ~4 T is excited resonantly by ps-pulses of mid-infrared radiation (photon energy 75 meV). Applying circularly polarized radiation allows one to pump and probe the energetically degenerate LL-1 → LL0 and LL0 → LL1 transitions selectively. In pump-probe experiments using all four combinations of pumping and probing with right and left circularly polarized radiation, a surprising change in sign of the measured signal (i.e. induced transmission instead of induced absorption) is observed in one of these configurations. Our analysis shows that this can be associated with a depletion of the LL0 level, even though this level is optically pumped at the same time. Very efficient Auger scattering is responsible for this depletion [4].
Furthermore, we show a very recent study of the polarization dynamics in Landau quantized graphene by means of degenerate four-wave mixing (FWM) spectroscopy. It is carried out on the same subsystem of Landau levels and utilizes similar values of magnetic field and photon energy as in the pump-probe experiments. However, the two incoming beams are linearly polarized in the FWM experiment. A rapid dephasing of the microscopic polarization on a timescale shorter than the pulse duration (4 ps) is observed and attributed to Auger scattering. The FWM signals show the expected dependences on the power of two incoming beams and on the magnetic field.
The results, both for the population as well as the polarization dynamics, depend crucially on the doping level of the sample. The graphene used in the experiments is almost intrinsic, corresponding to a full LL-1 and empty LL1. The occupation of LL0 of about 0.64 is slightly larger than the half-filling corresponding to intrinsic graphene. We will evaluate the implications of this symmetry breaking on Auger scattering and on the FWM signals. Finally, the implications of our results on the feasibility of a graphene based Landau-level laser, which is tunable by the magnetic field, will be discussed.
The sample was grown by C. Berger and W.A. de Heer. We acknowledge valuable discussions with M. Orlita, M. Potemski, Y. Wang, and A. Belyanin. We are grateful to P. Michel and the FELBE team for their dedicated support.
References
[1] X. Yao and A. Belyanin, Phys. Rev. Lett. 108, 255503 (2012).
[2] F. Wendler, A. Knorr, and E. Malic, Nature Commun. 5, 3703 (2014).
[3] F. Wendler and E. Malic, Sci. Rep. 5, 12646 (2015).
[4] M. Mittendorff, F. Wendler, E. Malic, A. Knorr, M. Orlita, M. Potemski, C.

Antiferromagnets have the potential to revolutionize spintronics due to their inherently magnetic-field stable magnetic order. The tiny uncompensated magnetic moment of the locally uncompensated antiferromagnetic lattice determines not only the physics of the materials, e.g. topology of antiferromagnetic domain walls [1], but also their application potential for novel magnetoelectric random access memory (MERAM) devices [2] or
antiferromagnetic analogues to racetrack devices. The rich physics of thin film antiferromagnets can be harnessed for prospective spintronic devices given that all-electric assessment of the tiny uncompensated magnetic moment is achieved.

We put forth a new method providing all-electric access to the field-invariant magnetization of antiferromagnetic thin films [3]. This technique – zero-offset Hall – is based on the combination of Anomalous Hall effect magnetometry with dynamic spinning-current offset compensation. We show that this technique opens the scope for magnetic phenomena that can go amiss in conventional Hall measurements with stationary current direction. The adoption of this technique will therefore substantially improve the reach of lab-based transport investigations in the thriving field of antiferromagnetic spintronics and
lead to new application concepts.

On the examples or metallic IrMn and insulating Cr 2 O 3 antiferromagnetic thin films, we demonstrate, that zero-offset Hall can probe thin film magnetism at unprecedented sensitivity, which allows us to reveal previously unknown peculiarities of the physical behavior. The access to insulating magnetic films is enabled by the magnetic proximity effect of certain conductors such as Pt.

The method is not exclusive to anomalous Hall measurements. Instead, all phenomena that alter the transversal resistance, such as the topological Hall effect and the quantum Hall effects, can be studied in greatly improved detail. At the same time, the measurements are technically easy and can be realized in most laboratories making it fast to adopt. Therefore, we believe that zero-offset Hall is of strong relevance for the community of topological and spin phenomena in nanostructures.

[1] M. Bode et al., Nature Materials 5, 477 (2006)
[2] X. He et al., Nature Materials 9, 579 (2010)
[3] T. Kosub et al., Phys. Rev. Lett. 115, 097201 (2015)

In polarization resolved pump-probe experiments complemented by microscopic modeling we show that an anisotropic carrier distribution persists on ps timescales. In particular, we evaluate the role of non-collinear Coulomb scattering.

Antiferromagnetic materials combine magnetic properties in peculiar combination that is not found in their ferromagnetic counterparts. They are more robust against magnetic disturbances and show great promises in e.g. magnetoelectric applications [1,2]. Despite these fascinating fundamental properties, both the understanding of antiferromagnets and their commercial establishment have progressed slower than for ferromagnets. The tiny uncompensated magnetic moment of the locally uncompensated antiferromagnetic lattice is often the linking element to intrinsic processes that experimenters can exploit or devices can rely on.
One of the most sensitive techniques for thin film magnetometry, the anomalous Hall effect (AHE) [3], is routinely employed to study magnetization eversal in ferromagnets [4] by monitoring the magnetization-proportional anomalous Hall resistance.
However, this typically suffers from a sizable parasitic signal offset due to imperfect device geometry. But, the offset also contains real AHE signals generated by field-invariant magnetization components which are inaccessible in conventional Hall measurements.
We demonstrate, that AHE magnetometry using the spinning-current technique can measure such field-invariant magnetization on an absolute scale by dynamically compensating the parasitic resistance contribution (Fig.) [5]. Thus, we acquire previously unattainable figures about antiferromagnetic materials and refine existing measurements due to the great precision and time-efficiency of AHE magnetometry.
We establish that this technique is suitable to probe a wide range of materials by applying it to polycrystalline IrMn thin films as well insulating Cr 2 O 3 films. Moreover, our all-electric measurements also prove that it is feasible to entirely omit ferromagnets in antiferromagnet-based applications. Doing so paves the way to all-antiferromagnet spintronics with improved performance or improved reliability [6].

[1] X. He, Y. Wang, N. Wu, A. N. Caruso, E. Vescovo, K. D. Belashchenko, P. A. Dowben, and C. Binek, Nature Materials 9, 579 (2010).
[2] J. Heron, J. Bosse, Q. He, Y. Gao, M. Trassin, L. Ye, J. Clarkson, C. Wang, J. Liu, S. Salahuddin, and others, Nature 516, 370 (2014).
[3] N. Nagaosa, J. Sinova, S. Onoda, A. MacDonald, and N. Ong, Rev. Mod. Phys. 82, 1539 (2010).
[4] D. Bhowmik, L. You, and S. Salahuddin, Nature Nanotechnology 9, 59 (2014).
[5] T. Kosub, M. Kopte, F. Radu, O. G. Schmidt, and D. Makarov, Phys. Rev. Lett. 1, 1 (2015).
[6] T. Kosub, O. G. Schmidt, and M. Denys, Patent Applied For (n.d.).

To increase the efficiency of bulk heterojunctions for organic photovoltaic devices, the complicated photon-to-electron conversion process has to be understood in detail. To this aim, one challenge is to resolve the correlation between processing parameters of organic solar cells (OSC), the resulting nanoscale morphology of the absorber layer, and efficiency of the completed device. Here, we present the effect of substrate heating on the morphology of the OSC where the active layer is a blend of two small molecules; ZnPc (ZnC32H18N8) as donor and C60 as acceptor.

Obtaining insights into the morphology of the active layer requires the spatial resolution and a contrast mechanism to discriminate two phases with similar average atomic number. To tackle this challenge, we combine electron microscopy imaging with different analytical techniques; energy dispersive X-ray spectroscopy (EDX) and electron energy loss spectroscopy (EELS) in TEM, as well as Energy selective Backscattered (EsB) imaging in SEM.

We imaged different phases of the donor and acceptor, forming ordered and non-ordered regions, depending on the way the heterojunction is fabricated. To this aim, we fabricated samples at substrate temperatures of 110°C and 150°C, each in two different configurations:

1) Focused ion beam prepared ultrathin lamella of a complete solar cell stack with glass substrate, Indium tine oxide (ITO) electrode, ZnPc:C60 blend of the active layer between electron and hole transport layers and aluminum top electrode.
2) Plane view sample as ZnPc:C60 blend deposited on a TEM grid coated with ITO layer.

It was shown that at a substrate temperature of 110°C, the solar cell device has high efficiency [1]., so we consider this as the optimum substrate temperature.

Since identification of the composition of each phase in the plane view sample is more straight forward, we use the plane view sample to attribute each structure to one component of the blend. SEM images recorded by using secondary electron detector show that, the high temperature sample consists of rod-like features and cube-shaped material in between the rods. By combination of analytical microscopy techniques, we can attribute the rod-like structures to ZnPc.

An energy-selective backscatter (EsB) electron detector in a SEM is used to obtain backscattered contrast of the plane view sample. Due to the atomic number difference between the donor phase and the acceptor phase, (the average atomic number of 8.6 for ZnPc and 6 for the C60) sufficient contrast can be achieved [2].

A clear confirmation for the attribution of the ZnPc phase to the rod-like features and the attribution of C60 to the granular structure in between can be drawn from the investigation of the sample in SEM using EDX and with even higher precision in TEM using an improved EDX system. The chemical mapping of zinc and carbon, proves the correct phase assignment, in both plane view and ultrathin samples, prepared at high temperature. For the sample produced at optimum temperature, a much smaller roughness was observed because of the absence of large ordered regions. Even in the plane view sample, the imaging contrast is low due to less separated phases and smaller domains.

To conclude, we clearly resolved the phase morphology of the interpenetrating network of ZnPc:C60 blends for high and optimum temperature samples in plane view and furthermore we were even able to reveal the morphology from TEM images of cross-section lamellas of the real solar cell stacks.

Since the ideal active layer should have domain sizes at the range of the exciton diffusion length (10-20nm), the sample produced at high temperature does not show the desired microstructure. Due to the domain sizes of ~100 nm there is no closed path for exciton dissociation. In addition to that, the sample shows a quite high roughness.

Acknowledgement:

Authors thank A. G. Cid for SEM images. This work was supported by the German Science Council Center of Advancing Electronics Dresden (cfaed). TEM-EDX results were achieved by funding (support code 03SF0451) through the Helmholtz Energy Materials Characterization Platform (HEMCP) initiated by the Helmholtz Association and the German Federal Ministry of Education and Research (BMBF).

References:

[1] S. Pfuetzner, C. Mickel, J. Jankowski, M. Hein, J. Meiss, C. Schuenemann, C. Elschner, A.A. Levin, B. Rellinghaus, K. Leo and M. Riede, “The influence of substrate heating on morphology and layer growth in C60:ZnPc bulk heterojunction solar cells” Org. Electron., 12 (2010), pp. 435–441
[2] A. G. Cid, M. Sedighi, M. Löffler, W. F. van Dorp and E. Zschech, “Energy-Filtered Backscattered Imaging Using Low-Voltage Scanning Electron Microscopy: Characterizing Blends of C60:ZnPc for Organic Solar Cells”. (DOI: 10.1002/adem.201600063)

We present experiments complemented by microscopic theory that highlight surprising Coulomb scattering effects. In particular, we find that non-collinear Coulomb scattering is compa-rably slow, namely on a scale of few ps. For the case of Landau-quantized graphene we find evidence for strong Auger scattering that can deplete a Landau level that is optically pumped at the same time. Both Coulomb effects are relevant for graphene based THz devices.

By using broadband absorber materials, bolometric detectors can typically cover an extremely large spectral range. However, since their response relies on the lattice temperature of the employed material, they exhibit slow response times. Hot electron bolometers (HEBs), on the other hand, can be extremely fast, because they exploit a change in device resistance caused by a varying electron temperature. A major drawback of HEBs based on superconductors is the required cooling to very low temperatures. We have developed a detector for room temperature operation, where the broadband absorption of the gapless material graphene is utilized. To this end, a graphene flake grown by chemical vapor deposition (CVD) is transferred to a SiC substrate and coupled to a logarithmic periodic antenna. Fast detection with a rise time of 40 ps is demonstrated for frequencies ranging from 0.6 THz to 390 THz [1]. Interestingly, the detector properties do not deteriorate for wavelength within the Reststrahlen band of SiC (25 – 50 THz). With a noise-equivalent power of 20 µW/Hz½ (800 µW/Hz½) in the near infrared (mid- and far infrared) the detector is capable of recording pulses with energies of the order of 10 pJ (1 nJ). We show that the detector is a versatile device for timing measurements in multi-color ultrafast spectroscopy studies.
[1] M. Mittendorff et al., Opt. Express 23, 28728 (2015).

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Due to their specific physical properties, HgCdTe-based heterostructures are expected to play an important role in terahertz photonic systems. Here, focusing on gated devices presenting inverted band ordering, we evidence an enhancement of the terahertz photoconductive response close to the charge neutrality point and at the magnetic field driven topological phase transition. We also show the ability of these heterostructures to be used as terahertz imagers. Regarding terahertz emitters, we present results on stimulated emission of HgCdTe heterostructures in their conventional semiconductor state above 30THz, discussing the physical mechanisms involved and promising routes towards the 5–15 THz frequency domain.

kein Abstract verfügbar

The low-temperature relaxation processes of non-equilibrium holes into gallium centers in moderately doped p-germanium (NA ≈ 2×10^15 cm-3) has been investigated by a degenerate pump-probe experiment using the free electron laser FELBE. The capture time decreases with increasing average photon flux density of the excitation pulse from about 10.9 ns (at ~1.2×10^24 cm-2 s-1) to ~1.2 ns (~2×10^26 cm-2 s-1). Relaxation inside the valence band is almost independent on pump light intensity and its characteristic time is about 200 ps. In Addition, the intracenter relaxation times of the lowest excited Ga states were measured. The lifetimes scale with the phonon density of states controlling a bound hole – acoustic phonon interaction. The lifetime of the lowest excited state, 1Γ_8^-, was measured to be ~275 ps; while the lifetimes of the higher excited states, 2Γ_8^-and 3Γ_8^-, were found to be ~157 ps and 162 ps, respectively.

One of the main benefits of PET/CT imaging is its ability for absolute quantification. Calibration according to the manufacturer‘s procedure specifies an accuracy of about 10%, whereas especially in dynamic clinical studies a higher quantification accuracy is desired. Therefore a more accurate calibration is needed. At the Gemini TF, a scanner with pixelated large-area LYSO detectors, there are differences in the measurement set-up between calibration and clinical acquisition. This study intends to evaluate the influence of those differences on the calibration with the aim to increase the accuracy of quantification. The major difference herein is the acquisition format, as calibration is performed in histogram-mode (HM-Cal) and clinical acquisition in list-mode format. Using the list-mode format for the calibration (LM-Cal), increases the activity recovery coefficient for the histogram-based acquisition from 0.93±0.08 up to 1.00±0.03. This is however only valid for the calibration set-up but not for clinical situations. Considering more realistic situations like lesions outside the centre of the field of view (FOV) or additional random events coming from highly accumulating regions outside the FOV (like bladder or brain), a different calibration can be found (ALL-Cal). In the evaluation of clinical oncological datasets with low count rates, a significant improvement of the reconstructed mean activity concentration in the bladder (compared to measured urine samples) up to 4% (LM-Cal) was achieved. For very high count rates the normalization of the scanner has to be adapted to improve the quantification accuracy as well.

We present a joint theory-experiment study on the transmission/absorption saturation after ultrafast pulse excitation in graphene. We reveal an unconventional double-bended saturation behavior: Both bendings separately follow the standard saturation model exhibiting two saturation fluences, however, the corresponding fluences differ by three orders of magnitude and have different physical origin. Our results reveal that this new and unexpected behavior can be ascribed to an interplay between fluence- and time-dependent many-particle scattering processes and phase-space filling effects.

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Recent pump-probe experiments performed on graphene in a perpendicular magnetic field have revealed carrier relaxation times ranging from picoseconds to nanoseconds depending on the quality of the sample. To explain this surprising behavior, we propose a novel symmetry-breaking defect-assisted relaxation channel. This enables scattering of electrons with single out-of-plane phonons, which drastically accelerate the carrier scattering time in low-quality samples. The gained insights provide a strategy for tuning the carrier relaxation time in graphene and related materials by orders of magnitude.

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A joint experiment-theory investigation of the carrier dynamics in graphene, in particular in the energetic vicinity of the Dirac point, is reviewed. Radiation of low photon energy is employed in order to match the intrinsic energy scales of the material, i.e. the optical phonon frequency (~200 meV) and the Fermi energy (10-20 meV), respectively. Significant slower carrier cooling is predicted and observed for photon energies below the optical phonon frequency. Furthermore, a strongly anisotropic distribution of electrons in k-space upon excitation with linearly polarized radiation is discussed. Depending on photon energy, the anisotropic distribution decays either rapidly via optical phonon emission, or slowly via non-collinear Coulomb scattering. Finally, a room temperature operated ultra-broadband hot-electron bolometer is demonstrated. It covers the spectral range from the THz to visible region with a single detector element featuring a response time of 40 ps.

For the safe operation of sodium cooling systems a monitoring of the flow field is often desirable. We report first on the development of a new eddy current flowmeter (ECFM) and related tests in sodium. The objective of this sensor is its positioning above the fuel subassemblies and the detection of possible blockages of the sodium flow through the multitude of subassemblies. The sensor consists of a number of coils a part of which is fed by an excitation AC current. The assembly of coils is placed in a thimble and the measured flowrate is proportional to the integral flow around this thimble. In the second part we report on local ultrasonic velocity measurements. Here, the objective is to study the flow field resulting from a large electromagnetic pump installed at the PEMDYN facility of CEA. Both measuring techniques were tested at the sodium facility NATAN of HZDR.

kein Abstract vorhanden

The International Atomic Energy Agency (IAEA) recently established a Coordinated Research Project (CRP) on “Sodium Properties and Safe Operation of Experimental Facilities in Support of the Development and Deployment of Sodium-cooled Fast Reactors - NAPRO”, to be carried out in the period 2013 – 2017. Eleven institutions from ten Member States participate in this CRP. The complete scope of this CRP is covered by three work packages. A specific work package (WP1), under the coordination of ANL (USA), is focused on the compilation and expert assessment of data sets of Na physical and chemical properties, as well as correlations for pressure drops and heat transfer in Na facilities. A second work package (WP2), under the coordination of IPPE (Russian Federation), addresses the compilation, evaluation and development of best practices and guidelines for the design, operation and maintenance of Na facilities. Finally, Work Package 3 (WP3), coordinated by CEA (France), concentrates on the compilation and development of guidelines and rules for the safe operation of Na facilities, including the prevention, detection and mitigation of Na leaks and fires. Finally, this work presents some examples of the principal results obtained so far by WP 1.

GaAs nanowires (NWs) can be grown epitaxially on Si(111) substrates in the vapour-liquid-solid mode. Typically, Au is used as catalyst, but affects the NW and substrate properties due to contamination. Thus, the self-catalyzed mode appears to be advantageous. The NW growth is initialized by the formation of Ga droplets on the substrate surface, which is normally covered by a thin SiO_x layer. The yield of vertical NWs depends on the thickness and the nature of the SiO_x, pointing out the complex interaction of the liquid Ga with the SiO_x. This work investigates the local etching of a native SiO_x on Si(111) by liquid Ga droplets, a mechanism, which is thought to precede the NW nucleation. The droplet formation, the etching process, and their effect on the NW growth were studied as a function of the substrate temperature and the etching time using molecular beam epitaxy. In contrast to previous studies, the oxide etching is distinguished from the subsequent NW nucleation by inserting a thermal annealing step, during which the Ga droplets are evaporated completely from the surface. Finally, the yield of vertical NWs and the NW number density can be controlled just by choosing the appropriate conditions for the oxide etching, independent of those used for the subsequent NW growth.

Im Rahmen des Belegs wurde eine graphische Oberfläche unter Labview entwickelt, die zur Durchführung von Steuerungs-, Regelungs- und Messaufgaben für einen im Rahmen des Projektes Helmholtz-Energieallianz entworfenen und aufgebauten Reaktor benötigt wurde.

Amorphous silicon oxicarbide thin films (a-SiOC(:H)) were deposited by RF-magnetron sputtering using Si or SiC target in Ar/CH4/O2 flow. Interatomic bonding and light emission properties were analyzed by FTIR in transmission and attenuation total reflection (ATR) mode, Raman scattering and photoluminescence spectroscopy. Comparison of the results obtained by FTIR and ATR allows us to suggest that structural properties of the near-surface region and the bulk of the films are significantly different. The surface layer contains a significant fraction of polymer-like SiOC structural components in the form of Si-O-Si/Si-O-C chains and cages, while bulk of the film is represented by inorganic amorphous SiOx network with amorphous carbon precipitates. Samples with the high fraction of carbon precipitates exhibit white luminescence at room temperature. The origin of strong photoluminescence is discussed.

Die partielle Oxidation von Isobutan durch Sauerstoff in einem Mikroreaktor wurde im überkritischem Zustand zwischen 135 °C und 145 °C unter Verwendung von di-t-butyl peroxide (DTBP) als Initiator untersucht. Dabei wurden das Verhältnis zwischen Isobutan und Sauerstoff, die Verweilzeit, der Druck, die Initiatorkonzentration und die Temperatur variiert. Ziel war es, die Effizienz des Prozesses durch eine Erhöhung der Selektivität des Produkts t-Butyl hydroperoxide (TBHP) und des Umsatzes zu verbessern. Es war insbesondere zu überprüfen, ob sich der Prozess unter diesen Bedingungen durch die Aufhebung von Stofftransportwiderständen gegenüber dem Zweiphasenprozess bei niedrigeren Temperaturen optimieren lässt. Die Reaktionsprodukte TBHP, Azeton, t-butanol und DTBP wurden mittels GC\MS analysiert. Im Rahmen der Arbeit gelang es die höchsten bisher mit einem Mikroreaktor erzielten Umsätze für die Isobutanoxidation zu erzielen. Jedoch gingen die Umsätze nicht wesentlich über die Umsätze hinaus, die aufgrund des zu erwartenden Temperatureffekts bei der Nutzung von überkritischen Bedingungen zu erwarten waren. Auch war die Umsatzerhöhung nur auf Kosten der Selektivität des TBHP zu erzielen. Die Arbeit bietet jedoch aufgrund Ihrer Ergebnisse eine wichtige Grundlage für weitere Untersuchungen.

While vanadium dioxide (VO2) is one of the most extensively studied highly correlated materials, there are intriguing similarities and differences worth exploring in another highly correlated oxide, niobium dioxide (NbO2). Both materials exhibit a thermally-induced first-order insulator-metal transition at a material-dependent critical temperature, which is considerably higher in NbO2 than in VO2 – approximately 1080 K and 340 K in bulk, respectively. This transition, evidenced by up to 6 orders of magnitude change in DC and optical conductivities, can also be induced in VO2 via photo-doping on a sub-picosecond timescale. Here, we present the first ultrafast pump-probe studies on the optically-induced transition of NbO2 thin films and the comparison with similar VO2 films. It is observed that NbO2 films transition faster and exhibit significantly faster recovery time than VO2 films of similar thickness and microstructure, showcasing that NbO2 is a promising material for next generation high-speed optoelectronic devices.

We have investigated the in-situ surface modification of a SiOx/Si(111) substrate by Ga droplets and its effect on the subsequent self-catalyzed growth of GaAs nanowires. Using a procedure of Ga droplet formation and subsequent re-evaporation prior to the nanowire growth, we found that the number density of nanowires at a given growth temperature can be varied deliberately within four orders of magnitude without affecting the nanowire diameter. A detailed study of the Ga droplet formation in a wide range of substrate temperatures revealed the physical processes that control the number density and size of the droplets.

Die partielle Oxidation von Isobutan, t-Butyl Hydroperoxid (TBHP) wurde zum ersten Mal als ein Zwei-Phasen-Prozess in einer Kapillare als Mikro Reaktor durchgeführt und analytisch untersucht. Um detaillierte Informationen über Produkte, Ausbeute, Selektivität und Reaktion Wege zu erhalten, mussten die Produkte mittels GC-MS analysiert werden. Zur Trennung der flüssigen Produkte wurde eine GC-MS Methode erstellt, optimiert und validiert, die eine Rxi-5ms-Säule und einen PTV-Injek-tors verwendet. Im Rahmen der Validierung wurden der Konzentrationsfehler wie auch der Mess¬fehler des MS-Signals aus sämtlichen Kalibrierschritten ermittelt sowie die entsprechenden analytischen Normen (z. B. DIN 38402) für die Kalibrierung berücksichtigt. Außerdem wurden statistische Tests auf Trends (nach Neumann), Ausreißer (nach Dixon), Normalverteilung (nach David) etc. durchgeführt. Die flüssigen Produkte wurden mittels MS identifiziert: Als Hauptprodukte traten TBHP, di-t-Butyl-Peroxid (DTBP), t-Butanol (TBA) und Propanone auf. Für die Zielprodukte TBHP und DTBP wurden Korrelationkoeffiuienten von r2 > 0,999, für TBA und Azeton r2 > 0,995 erzielt. Daneben traten Nebenprodukte wie z. B. Methanal, Methanol, Isopropanol, Isobutanol und Isobutanal auf, von denn alle bis auf Methanol und Methanal ebenfalls kalibriert wurden.

Ion beam irradiation can produce different patterns on semiconductor surface. While the surface is amorphized at low temperatures, the surface remains crystalline above the dynamic recrystallization temperature. Reverse Epitaxy leads to pattern formation, which is driven by diffusion of vacancies and adatoms on the surface, above this temperature. The mechanisms of Reverse Epitaxy epitaxy are quite similar to mound formation in homoepitaxial growth. The surface is destabilized in both cases by an effective uphill diffusion current driven by Ehrlich-Schwoebel barriers. The patterns formed depend of step formation energies, diffusion on terraces, and Ehrlich-Schwoebel barriers, which all are anisotropic. Their anisotropy is determined by the surface symmetry. By changing the surface symmetry the resulting patterns are be changed.

Current compositional methods typically rely on some sort of normality hypothesis for testing. Typical well-known non-parametric tests rely on ranks transforms, which are undefined for multivariate problems. The aim of this contribution is thus to investigate the possibilities for truly multivariate non-parametric tests of location and distribution for compositonal data. The challenge is the to ensure subcompositional coherence, which would bring the possibility to attribute deviations to certain subcompositions.

For the case of tests for a known compositional mean, we propose a bootstrap method, measuring how extreme this mean is with respect to a bootstrap sample of the empirical compositional mean. The extremity is checked in each of the pairwise log-ratios. This ensures a subcompositional coherence in the sense that a rejected hypothesis will always be rejected in at least one subcomposition.

For the case of a two sample test comparing two populations, the same principle can be extended. The mean difference is compared with bootstrap samples of mean differences. The same subcompositional coherence applies.

For multiple samples we can extend the idea of ANOVA of measuring the variability of the group means. The variability is measured in terms of the variation matrix. For each entry of the variatin matrix we quantify its quantile in the bootstrap population. We take then the maximum of the quantiles and bootstrap this maximum. In this way we again get a subcompositionally test for equal mean in all samples. Weighted modifications might improve power of the test in case of unequal sample sizes.

Compositional regression is concerned with modelling the dependence of a composition on one or more covariables, or vice versa. State of the art methods typically rely on the assumptions of linearity of the dependence and for tests on the additive logistic normal distribution of the errors. Several different solutions for non-linear regression and tests without normality assumption are available for non-compositional data. Based on them, this contribution derives non-parametric regression models and methods valid for compositional data.

With respect to the non-linear dependence, some sort of regularisation assumption is always required. Different classical approaches can be adapted for compositonal data. LOESS smoothing on pairwise log-ratios or logratio transforms would correspond to some sort of smooth (compositional) derivatives. Regression splines and smoothing splines are already defined in a multivariate way and allow to control the degree of continuity and smoothness by explicit parameters. Piecewise regression needs to be applied to log-ratio transforms and allows to model non-continuous dependence. Geostatistical interpolation or, equivalently, reproducing kernel splines, allow a precise control over the level of continuity and complexity through the variogram.

All methods mentioned admit a multivariate extension which, by virtue of the principle of working in coordinates, automatically give rise to compositional versions of those methods. Moreover, all are either affine equivariant, or else very slight restrictions of them are. Thus, the associated compositional versions deliver results which are: invariant with respect to the choice of basis, scaling invariant, and subcompositionally coherent (in the case of regression with compositional response).

With regard to testing, there are some philosophical difficulties in a classical ``zero slope hypothesis''. A strict test for dependence could be very misleading when used for model selection in a non-parametric setting. As an alternative we propose to check, whether the prediction by the non-parametric model outperforms the prediction by parametric (constant) one. We propose to compare the jacknifed residuals of the two models. This construction allows to construct all meaningful tests of compositional dependence, namely: global lack of dependence, lack of dependence within a subcomposition, as well as restricted dependence within a subcomposition.

Poster zum EMR-Meeting am 21.09.2016 am HZDR

Samples of thin film (d~40nm) tetrahedral amorphous carbon (ta-C), deposited by filtered cathodic vacuum arc (FCVA), have been implanted with N+ and Ga+ at ion energy E = 20 keV and ion fluences D = 3.1014÷3.1015 cm-2. This results in optical properties modification, best manifested by a significant shift of the optical absorption edge to lower photon energies, which is accompanied by a considerable increase of the absorption coefficient (photo-darkening effect) in the measured photon energy range (0.5÷3.0 eV). These effects could be attributed both to additional defect introduction and increased graphitization, as confirmed by X-ray photo-electron spectroscopy (XPS) measurements. The nonimplanted films show the expected variety of carbon-carbon chemical bonds: three- and fourfold coordinated carbon, while the X-ray results show that ion implantation leads to the introduction of additional disorder in the films. The X-ray photoelectron spectra of the implanted films show that, in addition to the already mentioned changes, the ion bombardment results in an increase of the threefold coordinated as compared to the fourfold coordinated carbon bonds, i.e. increased graphitization of the carbon content in the films. These structural modifications, due to the ion implantation, are the reasons for the observed changes in the optical properties of the films, which could be made use of in the area of high-density optical data storage using focused Ga+ ion beams.

Metallurgen entwickeln neue Strategien, um Rohstoffe aus alten Handys zurückzugewinnen.

Seit drei Jahren lehre und forsche ich als Professorin für Metallurgie und Recycling der Hochtechnologiemetalle in Freiberg. Mein Team und ich setzen uns für einen nachhaltigen Umgang mit kritischen Metallen und anderen Industriemineralen ein. Wir erforschen neue Verfahren, um beispielsweise Produktionsabfälle zu reduzieren und die Wiederverwertung von Rohstoffen aus Altgeräten zu verbessern. Schlacken, Schlämme, Stäube, Späne oder Abwässer — in der Mineralrohstoff und Metallindustrie gibt es, technisch bedingt, viele Rückstände und damit auch eine große Menge bisher nicht genutzter Wertstoffe. Gemeinsam mit den wiederverwertbaren Stoffen, die in alten Elektrogeräten und sonstigen ausgedienten Produkten stecken, gelten sie inzwischen
als wichtiger Hebel für das Erreichen einer maximalen Ressourceneffizienz in der Kreislaufwirtschaft. Um solche „Rohstoffe aus zweiter Hand“, auch sekundäre Ressourcen genannt, dreht sich die Arbeit meines Forscherteams.

Es ist kein Abstract vorhanden.

Es ist kein Abstract vorhanden.

Oxidation of hydrocarbon is an industrially important reaction. Many valuable chemicals are synthesized by the oxidation of relatively cheap raw materials derived from petroleum. The oxidation of isobutane is one of the most important oxidation oxidation processes. For example, isobutane oxidation can be conducted as the preoxidation in oxirane process to produce propylene oxide and tert.-butanol, in which propylene oxide and TBA are important industrial raw materials and widely used in the syntheses of pharmaceuticals, agrochemicals and other fine chemicals (Qi et al., 2014).
In more recent times, there is more and more interest of researchers in the application of microreactors in chemical engineering because of the opportunities of microreactors in chemical process development and intensification, such as excellent heat and mass transfer (Kashid et al., 2014). In this thesis, the oxidation of isobutane in two-phase flow is investigated in a microreactor (100 m long, 1mm ID). The experiments were carried out under different conditions. The start-up behavior of the oxidation of isobutane has been investigated and discussed. In addition, the effect of temperature, pressure, residence time, oxygen-isobutene ratio, the nitrogen dilution and initiator concentration on the performance of isobutane has also been preliminary investigated and discussed. Furthermore, the rate constant of isobutene oxidation has been calculated for 130 °C.

Im Rahmen der nuklearen Sicherheitsforschung des Bundesministeriums für Wirtschaft und Energie (BMWi) erfolgten an der Hochschule Zittau/Görlitz (HSZG) in Kooperation mit der Technischen Universität Dresden (TUD) und dem Helmholtz-Zentrum Dresden-Rossendorf (HZDR) experimentelle und methodische Untersuchungen für die systematische Klärung physiko-chemischer Mechanismen im Kühlmittel und deren Auswirkungen auf thermo-fluiddynamische Prozesse im Reaktorkern, welche während des Sumpfumwälzbetriebes als Langzeitnachkühlung nach Kühlmittelverluststörfällen (KMV) in Druckwasserreaktoren (DWR) auftreten können. Durch Korrosionsprozesse an feuerverzinkten Installationen im Sicherheitsbehälter (SHB) von DWR wird Zink in ionischer Form im borierten Kühlwasser gelöst. Die freigesetzten Zink-Ionen werden aus dem Reservoir des Nachkühlmittels im SHB über die Not- und Nachkühlsysteme bis in den Reaktorkern gefördert. Im Reaktor wird das eingespeiste Kühlmittel (KM) aufgeheizt.
Im Fokus generischer Experimente standen Untersuchungen zum Verhalten derart zusam-mengesetzter Fluide unter Berücksichtigung von Temperaturunterschieden zwischen dem Kühlmittelreservoir im SHB und dem Reaktorwasser an den Brennstäben im Reaktorkern. Diese generischen Untersuchungen erfolgten an elektrisch beheizten Stabkonfigurationen, welche die durch Nachzerfallsleistung beheizten Brennstäbe im Kern von DWR nachbildeten. Bei der Aufheizung des zinkhaltigen KM innerhalb solcher Konfigurationen wurden Trübungen durch Kolloidbildung beobachtet, gefolgt von Ausscheidungen partikelförmiger, fester Korrosionsprodukte in Form von Zinkboraten. Diese erschienen in Abhängigkeit von der umgebenden KM- bzw. Staboberflächentemperatur als leicht mobilisierbare, flockenartige Dispersphase oder wiesen schichtenbildenden Charakter auf.
Die temperaturabhängigen Umwandlungen von gelösten Zink-Ionen in feststoffartige Zinkborate bewirkten sowohl Ablagerungen an den Heizstäben als auch an den Abstandshaltern (AH) und führten zu erhöhtem Differenzdruckaufbau über die AH sowie Strömungsumverteilungen in der Stabkonfiguration. In Folge dieser Ablagerungen wurden Änderungen des Wärmetransports vom beheizten Stab ans Fluid nachgewiesen, die eine Aufheizung der Heizstäbe bewirkten und damit sicherheitsrelevanten Charakter hinsichtlich der Nachwärmeabfuhr tragen. Aktuell wird dieses generisch ermittelte Verhalten des Reaktorwassers hinsichtlich der Übertragbarkeit auf sicherheitsrelevante Fragestellungen realer DWR mit Bezug auf anzunehmende Leckgrößen und Nachkühlbedingungen und den daraus resultierenden thermohydraulischen Randbedingungen im Sicherheitsbehälter und im Reaktorkern untersucht. Hierfür werden durch Störfallanalysen die Zustände und Bedingungen abgrenzend ermittelt, bei denen eine Gefährdung der Kernkühlung aus Sicht vorhandener Erkenntnisse zu den physiko-chemischen Effekten eintreten könnte. Wesentliche Untersuchungsschwerpunkte bilden die im SHB von DWR auftretenden chemischen und thermodynamischen Einflüsse auf die Zinkfreisetzung und das Ausfällungs- und Ablagerungsverhalten der Korrosionsprodukte an Heißstellen im Reaktorkern.
Die Untersuchungsergebnisse finden u. a. für die Parametrierung von Simulationscodes sowie in alternativen Modellansätzen Verwendung und dienen der sicherheitstechnischen Einschätzung des DWR-Reaktorverhaltens für verschiedene KMV-Störfallszenarien. Die quantitative Analyse der experimentellen Daten zum zeitlichen Ablauf des Quelle-Senke-Mechanismus der Zinkkorrosion und der Umwandlung des gelösten Zinks in feste Produkte unter realen Störfallbedingungen stellt auf Grund der Komplexität und der gegebenen Rückwirkungen eine Herausforderung dar.
Die Vorhaben werden mit Mitteln des Bundesministeriums für Wirtschaft und Energie (BMWi) unter den Förderkennzeichen 150 1491 und 150 1496 gefördert und fachlich von einer Monitoring Group begleitet, welche sich aus Repräsentanten der Forschungsbetreuung des Projektträgers, Gutachtern, Herstellern und Anlagenbetreibern zusammensetzt.

Helmholtz-Zentrum Dresden-Rossendorf
Helmholtz Institute Freiberg for Resource Technology
Introduction
CHROMIC
This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 730471
This presentation reflects only the author’s views and neither Agency nor the Commission are responsible for any use that may be made of the information contained therein.

CHROMIC
WP4 Presentation
Prof. Dr.-Ing. Christiane Scharf (HZDR, HIF)
This project has received funding from the European Union’s Horizon 2020 research and
innovation programme under grant agreement No 730471
This presentation reflects only the author’s views and neither Agency nor the Commission are responsible for any use that may be made of the information contained therein.

Koordinierungsgespräch
HIF – Technikum
Christiane Scharf
29.4.2016, Helmholtz-Zentrum Dresden-Rossendorf

Obwohl sich die Anzahl weiblicher und männlicher Hochschulabsolventen in etwa die Waage hält, sind auf den akademischen Führungspositionen nur selten Frauen zu finden. Über die Gründe wird viel diskutiert. Unter anderem würden den jungen Forscherinnen geeignete Vorbilder fehlen. Die HZDR-Zentralabteilung Verwaltung hat eine Veranstaltungsreihe aufgesetzt, in der Professorinnen des Zentrums ihren Weg in der Wissenschaft vorstellen. Den Anfang machte im März Prof. Christiane Scharf. Sie hält seit Oktober 2013 die Professur für Metallurgie und Recycling von Hochtechnologiemetallen an der TU Bergakademie Freiberg. Außerdem leitet sie die Abteilung Metallurgie und Recycling am Helmholtz-Institut Freiberg für Ressourcentechnologie. insider hat sich mit ihr über die Situation für Frauen in der Wissenschaft unterhalten.

insider: Frau Scharf, Sie sind ein seltener Fall. Nur ein Fünftel aller deutschen Professuren ist weiblich besetzt. Wie kommt das?
Christiane Scharf: Ich persönlich denke, dass das deutsche Familien- und vor allem Frauenbild hier immer noch eine sehr starke Rolle spielt. Der Einfluss des direkten familiären Umfeldes hat enorme Auswirkungen auf die Karriere. Kommt aus dieser Richtung zusätzlicher Widerstand, was wohl leider nicht selten der Fall ist, wird es sehr schwierig, die ohnehin hohen Hürden zu meistern. Wenn man allerdings den Rückhalt spürt, wird Vieles wesentlich leichter. Häufig genügen dafür schon ein oder zwei Personen, auf die man sich verlassen kann.

Gerade bei Frauen kommt es relativ häufig vor, dass sie einen Ruf nicht annehmen. Könnte das in diesen Fällen auch eine Rolle spielen?
Absolut. Industrie und Wissenschaft haben mittlerweile zum großen Teil begriffen, dass viele Frauen alle Qualifikationen mitbringen und neue Ideen beisteuern können. Eine Führungsposition bringt jedoch automatisch neue Pflichten und einen höheren Grad an Verantwortung mit sich. Ob man sich selbst zutraut, dies zu erfüllen, hängt wiederum stark vom persönlichen Umfeld ab. Dabei sollten auch gesellschaftliche Vorstellungen – ich nenne hier zum Beispiel den Begriff der Rabenmutter, selbst wenn das altertümlich klingen mag – nicht unterschätzt werden.

An welcher Stelle könnte man ansetzen, um das zu ändern?
Zu meiner Schulzeit wurde noch stark das Bild vermittelt, dass Frauen in technischen und naturwissenschaftlichen Berufen nichts verloren hätten. Glücklicherweise ändert sich das seit etwa fünfzehn Jahren. Gesellschaftlich hat sich schon viel getan. Am Ende ist es natürlich trotzdem eine Persönlichkeitsfrage: Wie gehe ich zum Beispiel mit Niederlagen um? Nach meinem Chemieingenieursstudium habe ich mehr als 100 Absagen erhalten.

Und wie gingen Sie damit um?
Ich habe als chemische Fachkraft bei einem Privatunternehmen angefangen. Diese Erfahrungen aus der Industrie haben mir später sehr weitergeholfen. In den meisten Fällen ist die größte Hürde, erst einmal in das gewünschte Feld hineinzukommen. Sobald man auf einer sachlichen Ebene diskutiert, sind die Vorurteile sehr schnell entkräftet.

Könnte das auch eine Lösung für ein zurückhaltendes Umfeld sein?
Aus meiner persönlichen Erfahrung würde ich sagen ja. Mit zunehmendem Erfolg wird auch das kritische Umfeld immer ruhiger. Jungen Forscherinnen, und natürlich auch jungen Forschern, kann ich deswegen nur den Mut zusprechen, in sich selbst zu vertrauen, auch wenn die Herausforderungen hoch erscheinen. Man sollte sich immer selbst klar machen, welche Chancen dieser Weg mit sich bringt.

Was war dabei Ihr Erfolgsrezept?
Ich würde sagen, eine Strategie der kleinen Schritte. Wenn ich mir schon beim Abitur denke, in 20 Jahren musst du auf dieser Position sitzen, dann ist das eine riesige Hürde. Es kann dann schnell passieren, dass man bei den ersten Niederlagen, die mit großer Wahrscheinlichkeit kommen werden, zu verzweifeln beginnt. Es geht eher darum, immer am Ball zu bleiben. Der rote Faden muss erkennbar bleiben, ohne krampfhaft auf ein einziges Ziel hinzuarbeiten. Jeder erfolgreiche Schritt, auch wenn er klein sein mag, bringt dann neue positive Energie.
Das Interview führte Simon Schmitt.

Frauen in der Wissenschaft - Karrierewege
Christiane Scharf
Helmholtz-Zentrum Dresden-Rossendorf, 4.3.2016

KIC – Network of Infrastructure for Metal-based Lightweight Materials
Metallurgy and Recycling Department
Christiane Scharf
Freiberg, 29th November 2016

The spinel NiCo2O4 (NCO) exhibits unique combination of electrical conductivity, infrared transparency, electro catalytic activity, and ferrimagnetic order, which makes it an attractive material for spintronic applications.1 The NCO thin-films electrical and magnetic properties can be manipulated from high temperature ferrimagnetic and metallic to low temperature ferromagnetic and insulating by changing the growth temperature.2 The high quality epitaxial NCO films were grown on MgAl2O4 (100) substrate at ~ 400°C exhibits metallic behavior accompanied by ferrimagnetic order with moment ~ 2 μB/fu.1,2 Here, we report the impact of He-ion irradiation with fluence ranging from 5×1015/cm2 – 3×1016/cm2 on these metallic NCO films. The use of He-ion irradiation results in the coherent control of out-of-plane lattice parameter of these films without changing its in-plane lattice parameter (Figure 1). The comprehensive study of magnetization data reveals the magnetic moment increases drastically to ~ 4 μB/fu (Figure 1). The X-ray absorption spectroscopic study also suggests the possible charge redistribution within the octahedral sites of the NCO films which corroborates well with the increase in the magnetic moment.

Ausgangssituation und Zielsetzung
Die Gewinnung von Seltenen Erden (SE) ist aufgrund ihrer Eigenschaften sehr komplex, aufwendig und dadurch kostspielig. Die größten Herausforderungen liegen in der Separation der einzelnen SE-Elemente sowie in der notwendigen Abtrennung von Uran und Thorium. Ziel des Projektes SE-FLECX ist die Entwicklung neuer Extraktionsmittel zur effizienten Trennung der Actinoide (Typ A) und der SE-Elemente (Typ B) und die Auslegung ihres Herstellungsprozesses im industriellen Maßstab.

SE-FLECX: Selektive Flüssig-Flüssig-Extraktion von Lanthanoiden und Actinoiden durch präorganisierte Calixarene
Koordinator: Prof. Dr. Christiane Scharf
Förderkennzeichen: 033R132A
r4-Konferenz 2016 | Hannover | 20. und 21. Oktober 2016
Verbundpartner
BASF SE, Ludwigshafen
Helmholtz-Zentrum Dresden-Rossendorf,
Helmholz-Institut Freiberg für Ressourcentechnologie, Freiberg
Und Institut für Ressourcenökologie, Leipzig
CMI UVK GmbH, Montabaur
Technische Universität Bergakademie Freiberg, Freiberg
Universität Leipzig, Leipzig

Silicon based alloys with Mn-ions are a potential candidate for the spintronics applications, as they exhibit complex electric and magnetic phenomena which can be effectively utilized as the integrated-circuit elements in the contemporary microelectronic technology. Though, The Si1-xMnx alloys shows high-temperature ferromagnetism at low Mn concentration x ~ 0.05 – 0.1, but the small solubility of Mn-ions in Si leads to the formation of MnSi1.7 nanoparticles,1 which drives the system in an inhomogeneous phase and makes it irrelevant for the technological applications. However, a high Mn concentration in the Si1-xMnx alloys screens the precipitation of different inhomogeneous magnetic phases with high Curie temperature (TC).2 In this context, a set of thin films of Si1-xMnx (x = 0.44 – 0.57) alloy were prepared by the pulsed laser deposition technique on Al2O3 (0001) substrate. We have found room temperature ferromagnetism and a large magnetic moment for the Si0.43Mn0.57 film as compared to the rest of samples. But, surprisingly, the TC (as well as the moment) of Si0.43Mn0.57 film drastically decreases from 300 K to ~ 40 K as the Mn-ion concentration was increased in the film through the ion implantation process. In contrast, the stoichiometric film Si0.5Mn0.5 exhibits a huge increase in the magnetic moment by one-order in magnitude after ~ 2% Mn-ion implantation. The TC of the stoichiometric film also increases from 50 K to 300 K with the increase in the Mn-ion concentration.

In biochemical processes, column reactors replaced the stirred tank reactors for their advantages, like mild agitation. Among different configurations of column reactors airlift reactors constitute attractive systems for bio-catalyzed reactions due to the simple de-sign, low investment and operation costs. The advantages of combined external loop airlift and fluidized bed reactor in the downcomer over three-phase fluidized bed reactor and other configuration of airlift reactors are the unique hydrodynamic properties as it requires lower liquid flow rate for complete suspension of solid and good contact among the phases, easy removal of particles, rapid mixing, and easier scale up. This enables inverse fluidizing of low-density particles in the downcomer zone, characterized by low shear rates.

Metallurgy and Recycling Division
Christiane Scharf
Freiberg, 10th March 2016

Metallurgy and Recycling Department
Visit of Prof. Mari Lundström
Christiane Scharf
Freiberg, 15th Dezember 2016

The present talk deals with the transport and the deposition of micron particles to solid wall surfaces and fluid-fluid interfaces. Various particle-interface models are presented and tested with direct numerical flow simulations. The various micro processes observed during the particle attachment and particle detachment are well captured. The results compare well with those experimentally obtained on-site.

Metallurgy and Recycling Department
Visit of Prof. Peter Tasker
Christiane Scharf
Freiberg, 13th Dezember 2016

Space exploration is linked to the development of increasingly innovative instrumentation, able to withstand the operation environment, rich in ion particles and characterized by high temperatures. Future space missions such as JUICE and SOLAR ORBITER will operate in a very harsh and extreme environment-. Electrons and ions are considered among the causes of potential damage of the optical instrumentation and components. Development of hard coatings capable to preserve their optical properties is pivotal. Different coating materials have been exposed to ion irradiation in particle accelerators. Change in optical performances has been observed in the extreme ultraviolet and visible spectral region and structural properties have been analyzed by different techniques. The knowledge of the damage mechanisms and thresholds allows the selection of more promising candidate materials to realize the optical components for the new frontiers space missions. © (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

Metallurgy and Recycling Division
Christiane Scharf
Freiberg, 8th September 2016

Summer School 2016
Recycling of Strategic Elements by Extractive Metallurgy
Christiane Scharf
5th October 2016, TU Dresden

Bubble columns are simple multiphase reactor and contactor devices, which are widely applied due to their superior heat and mass transfer characteristics. Furthermore, they are relatively simple in construction due to the absence of moving parts. Bubble columns are used for various chemical processes such as methanol and Fischer-Tropsch synthesis. Since most of the processes running in bubble columns are of exothermic nature, a variety of heat exchangers, e.g. internal heat exchanging tube bundles, are installed in order to ensure proper reaction conditions. Such tube bundles cover a significant ratio (up to 60 %) of the entire column cross-section. Accordingly, the column performance is dominated by the hydrodynamics proceeding at smaller characteristic length scale in the sub-channels. However, the evolving sub-channel flow has not been studied yet.
Therefore, this study focusses on the analysis of the multiphase flow in the sub-channels of an internal heat exchanging tube bundle with longitudinal flow of various configurations (square and triangular pattern) and tube diameter sizes (8 mm and 13 mm). The investigations were carried out in a 100 mm (inner diameter) bubble column for an air / deionized water system using a perforated plate type sparger. To ensure comparability, the covered rector’s cross-sectional area was kept similar for all configurations.
The hydrodynamic parameters were studied separately for sub-channels at various radial positions in the bundles as well as for the entire column. Approaches to link experimental data from both scales for a multiscale evaluation are suggested. Furthermore, the results are compared with an advanced horizontal stage-model considering breakup and coalescence mechanisms to calculate the bubble size distribution, breakup and coalescence rates and the overall gas holdup.

Record high values of Young’s modulus and tensile strength of graphene and BN nanoribbons as well as their chemically active edges make them promising candidates for serving as fillers in metal-based com- posite materials. Herein, using ab initio and analytical potential calculations we carry out a systematic study of the mechanical properties of nanocomposites constructed by reinforcing an Al matrix with BN and graphene nanoribbons. We consider a simple case of uniform distribution of nanoribbons in an Al matrix under the assumption that such configuration will lead to the maximum enhancement of mechanical characteristics. We estimate the bonding energy and the interfacial critical shear stress at the ribbon/metal interface as functions of ribbon width and show that the introduction of nanoribbons into the metal leads to a substantial increase in the mechanical characteristics of the composite material, as strong covalent bonding between the ribbon edges and Al matrix provides efficient load transfer from the metal to the ribbons. Using the obtained data, we apply the rule of mixtures in order to analytically assess the relationship between the composite strength and concentration of nanoribbons. Finally, we study carbon chains, which can be referred to as the ultimately narrow ribbons, and find that they are not the best fillers due to their weak interaction with the Al matrix. Simulations of the electronic transport properties of the composites with graphene nanoribbons and carbyne chains embedded into Al show that the inclusion of the C phase gives rise to deterioration in the current carrying capacity of the material, but the drop is relatively small, so that the composite material can still transmit current well, if required.

We examine swift heavy ion-induced defect production in suspended single layer graphene using Raman spectroscopy and a two temperature molecular dynamics model that couples the ionic and electronic subsystems.We show that an increase in the electronic stopping power of the ion results in an increase in the size of the pore-type defects, with a defect formation threshold at 1.22e1.48 keV/layer. We also report calculations of the specific electronic heat capacity of graphene with different chemical potentials and discuss the electronic thermal conductivity of graphene at high electronic temperatures, suggesting a value in the range of 1Wm?1 K?1. These results indicate that swift heavy ions can create nanopores in graphene, and that their size can be tuned between 1 and 4 nmdiameter by choosing a suitable stopping power.

Kagome lattices are structures possessing fascinating magnetic and vibrational properties, but in spite of a large body of theoretical work, experimental realizations and investigations of their dynamics are scarce. Using a combination of Raman spectroscopy and density functional theory calculations, we study the vibrational properties of two- dimensional silica (2D-SiO2), which has a kagome lattice structure. We identify the signatures of crystalline and amorphous 2D-SiO2 structures in Raman spectra and show that, at finite temperatures, the stability of 2D-SiO2 lattice is strongly influenced by phonon−phonon interaction. Our results not only provide insights into the vibrational properties of 2D-SiO2 and kagome lattices in general but also suggest a quick nondestructive method to detect 2D-SiO2.

Sieve trays are popular among vapour-liquid contacting devices in distillation columns due to their versatility and simple construction. Flow and mixing patterns on the trays have strong influence on their mass-transfer efficiency. Plug flow is considered ‘ideal’ whereas flow non-idealities such as liquid channelling, bypassing, re-circulation and stagnant zones are disadvantageous for the tray efficiency. Flow patterns quantified by Schubert et. al. (2016) using wire-mesh sensor are analysed using existing mathematical models for efficiency predictions. A serious loss in efficiency is predicted for the tray with large stagnant zones.

(1) M. Schubert, M. Piechotta, M. Beyer, E. Schleicher, U. Hampel and J. Paschold, ‘An imaging technique for characterization of fluid flow pattern on industrial-scale column sieve trays’, Chemical Engineering Research and Design, vol. 111, pp.138–146, 2016.

In the frame of the European Union NURESAFE project a benchmark test between NEPTUNE_CFD, CFX and TransAT CFD codes on a reference TOPFLOW-PTS experiment was conducted. The work is a part of the work package on multi-scale and multi-physics simulation of Pressurized Thermal Shock (PTS). The article includes a short description of the TOPFLOW-PTS facility and the reference steam-water experiment. Furthermore the boundary and initial conditions for the CFD simulations are presented. The computational grids that are used for the benchmark simulations and the models used are introduced. Finally, the results of CFD calculations are compared with the experimental data and differences between simulations and experiment are discussed.

In the quantum regime of the free-electron laser, the dynamics of the electrons is not governed by continuous trajectories but by discrete jumps in momentum. In this article, we rederive the two crucial conditions to enter this quantum regime: (1) a large quantum mechanical recoil of the electron caused by the scattering with the laser and the wiggler field and (2) a small energy spread of the electron beam. In contrast to our recent approach based on nonrelativistic quantum mechanics in a co-moving frame of reference, we now pursue a model in the laboratory frame employing relativistic quantum electrodynamics.

The water supply in semi-arid Israel and Palestine, predominantly relies on groundwater as freshwater resource, stressed by increasing demand and low recharge rates. Sustainable management of such resources requires a sound understanding of its groundwater migration through space and time, particularly in structurally complex multi-aquifer systems as the Eastern Mountain Aquifer, affected by salting. To differentiate between the flow paths of the different water bodies and their respective residence times, a multi-tracer approach, combining age dating isotopes (³⁶Cl/Cl; ³H) with rock specific isotopes like ⁸⁷Sr/⁸⁶Sr and δ³⁴S-SO₄ was applied. As a result, the investigated groundwaters from the two Cretaceous aquifers and their respective flow paths are differentiable by e.g. their ⁸⁷Sr/⁸⁶Sr signatures, resembling the intensity of the rock-water interaction and hence indirectly residence times. In the discharge areas within the Jordan Valley and along the Dead Sea shore, δ³⁴S-SO₄ ratios reveal the different sources of salinity (ascending brines, interstitial brines and dissolved salts). Based on ³⁶Cl and ³H and the atmospheric input functions, very heterogeneous infiltration times and effective flow velocities, respectively, indicate an at least dual porosity system, resulting in distinctly different regimes of matrix and pipe flow.

However, such structures are not small enough to operate at room temperature (RT) quantum devices with switching mechanisms different from CMOS. E.g., the extremely low-power device Single Electron Transistor (SET) works at RT only if the size of the quantum dot is below 5 nm, and if the tunnel distances through SiO2 are a few nm only.
Here we present a directed self-assembly process of a 2-3 nm small single Si dot located in the middle of a SiO2 layer with distances of ~2 nm to the upper and lower Si. The self-assembly occurs by phase separation of metastable SiOx during a heat treatment. The self-assembly becomes directed by constraining and shaping the SiOx volume in such a manner that a single Si quantum dot in the requested position forms. The SiOx is fabricated by collisional mixing of Si atoms from above and below in the SiO2 layer. Two methods to form a local, constrained volume of SiOx are presented: (i) A large-area Si/SiO2/Si layer stack is irradiated with a 2 nm narrow energetic Ne+ beam in a Helium Ion Microscope (HIM), which results in a ~10 nm disk of SiOx in the buried SiO2 layer. (ii) Si pillars (<20 nm) with an embedded SiO2 layer are irradiated with a broad beam of energetic Si+ ions. Method (ii) will be used to fabricate SETs in a CMOS technology.
This work has been funded by the European Union's Horizon 2020 research and under grant agreement No 688072 innovation program.

Garnet chemistry provides a well-established tool in the discrimination and interpretation of sediment provenance. Current discrimination approaches, however, (i) suffer from using less variables than available, (ii) subjective determination of discrimination fields with strict boundaries suggesting clear separations where in fact probabilities are converging, and (iii) significant overlap of compositional fields of garnet from different host-rock groups. The new multivariate discrimination scheme is based on a large database, a hierarchical discrimination approach involving three steps, linear discriminant analysis at each step, and the five major host-rock groups to be discriminated: eclogite- (A), amphibolite- (B) and granulite- (C) facies metamorphic rocks as well as ultramafic (D) and igneous rocks (E). The successful application of statistical discrimination approaches requires consideration of the a priori knowledge of the respective geologic setting. This is accounted for by the use of prior probabilities. Three sets of prior probabilities (priors) are introduced and their advantages and disadvantages are discussed. The user is free to choose among these priors, which can be further modified according to the specific geologic problem and the level of a priori knowledge. The discrimination results are provided as integrated probabilities of belonging to the five major host-rock groups. For performing calculations and results a supplementary Excel® spreadsheet is provided. The discrimination scheme has been tested for a large variety of examples of hard rocks covering all of the five major groups and several subgroups from various settings. In most cases, garnets are assigned correctly to the respective group. Exceptions typically reflect the peculiarities of the regional geologic situation. Evaluation of detrital garnets from modern and ancient sedimentary settings of the Western Gneiss Region (Norway), Eastern Alps (Austria) and Albertine Rift (Uganda) demonstrates the power to reflect the respective geologic situations and corroborate previous results. As most garnet is derived from metamorphic rocks and many provenance studies aim at reconstructing the tectonic and geodynamic evolution in the source area, the approach and the examples emphasize discrimination of metamorphic facies (i.e., temperature-pressure conditions) rather than protolith composition.

Für die hier dargestellte Studie im Bereich des Gifhorner Trogs wurden neben ca. 500 Messpunkten mit vollständig korrigierten Bougueranomalien ca. 4400 digitalisierte ältere Drehwaagemessungen aus dem beginnenden 20. Jahrhundert verwendet. Mit Hilfe der „alten“ Drehwaagemessungen konnten im Detail dann die Schwerehorizontalgradienten Wxz und Wyz sowie die Krümmungsgrößen der Schwere (WΔ = Wyy – Wxx und 2Wxy) in die 3D-Modellierung integriert werden. Neben den an der Oberfläche gemessenen Anomalien standen auch Untertagemessungen des Schwerefeldes zur Verfügung.
Modelliert wurde mit der hauseigenen Modelliersoftware IGMAS+, die nicht nur die simultane 3D Modellierung von Potentialfeldern (GravMag) ermöglicht, sondern auch deren Gradienten. Ein Vergleich von häufig verwendeten 2D-Modellierungen natürlicher 3D-Strukturen im Untergrund mit 3D-Berechnungen zeigt deutlich, wie groß die Gefahr von Fehlinterpretation eines solchen methodisch fragwürdigen Vorgehens ist. Die Modelldichten können variabel – in Abhängigkeit von den „wahren Geschwindigkeitsverhältnissen“ im Modelliergebiet angegeben werden. Als Beispiel zeigen wir das 3D Dichtemodell der Tiefbohrung KTB zusammen mit der Bohrlochgravimetrie – in Ermangelung anderer, frei zugänglicher Datensätze.
Die vorliegende Modellierung von Detailstrukturen im Gifhorner Trog belegt eindeutig, dass eine hybride 3D Modellierung von Potentialfeldern zusammen mit ihren Gradienten wertvolle Informationen über den Untergrund bis in Tiefen von 5 – 10 km liefert, die gemeinsam mit seismischen Informationen einen erheblichen Mehrwert für die Interpretation darstellen.

Continued progress in hard disk drive areal density for conventional perpendicular magnetic recording (PMR) based on granular media has become increasingly difficult. Although adoption of energy assisted magnetic recording (EAMR), specifically Heat Assisted Magnetic Recording (HAMR) is widely viewed as a promising solution for thermal stability issues, challenges in grain size scaling and managing media noise may limit the rate of progress for EAMR based on granular media. Bit patterned recording (BPR) stands as an attractive alternative to granular media, offering a path to thermally stable recording at high density and significantly reduced media noise by replacing the segregated random grains of PMR media with lithographically defined single domain islands. Figure 1 compares and summarizes basic characteristics of currently used conventional PMR based on granular media and BPR based on pre-defined bits. In my talk I will discuss various choices for BPR magnetic materials, such as Co/Pd and Co/Pt multilayers as well as CoCrPt and FePt L10 alloys. I will highlight advantages and disadvantages of the different magnetic material systems with respect to potential applications in BPR and outline the specific challenges when comparing conventional PMR, BPR and currently emerging HAMR systems.

Results of the 2016 Karrat fieldwork, 11.08.2016 – 24.08.2016

Bubble column reactors are multiphase devices which are commonly applied in the chemical process industry due to their advantageous heat and mass transfer properties as well as the abstinence of moving parts. Since most of the reactions operated in these devices are of exothermic nature, the developed heat has to be sufficiently removed off the system in order the guarantee optimal reaction conditions. One, among others, of those heat exchanging devices can be internally inserted tube bundles, which have the advantage to remove the heat directly at its source. On the downside, a large portion of the reactor's cross-sectional area has to be covered by the tube bundle, whereas typical values range between 20 and 30%. Hence, the influence of the internals is not negligible and has a strong effect on the global and local hydrodynamics. Therefore, the influence of various tube bundle layouts (square and triangular pitch) with two tube sizes (8 and 13 mm) having the same coverage of the reactor's cross-sectional area (~25%) have been investigated using the ultrafast X-ray CT to get insight into the local and global hydrodynamics. A cylindrical column with 10 cm ID and a height of 2m was used. Furthermore, to cover all hydrodynamic flow regimes, the superficial gas velocity was varied between 2 – 20 cm/s. It has been found out that the tube configuration has strong impact on the radial holdup profile, which governs the liquid mixing and gas velocity profile. Furthermore, square configurations showed better hydrodynamic performance regarding holdup, holdup profiles and bubble size distribution.

Large scale, dynamical simulations have been performed for the two dimensional octahedron model, describing Kardar-Parisi-Zhang (KPZ) for nonlinear, or Edwards-Wilkinson (EW) for linear surface growth. The autocorrelation functions of the heights and the dimer lattice gas variables are determined with high precision. Parallel random-sequential (RS) and two-sub-lattice stochastic dynamics (SCA) have been compared. The latter causes a constant correlation in the long time limit, but after subtracting it one can find the same height functions as in case of RS. On the other hand the ordered update alters the dynamics of the lattice gas variables, by increasing (decreasing) the memory effects for nonlinear (linear) models with respect to RS. Additionally, we support the KPZ ansatz in 2+1 dimensions and provide a precise growth exponent value β = 0.2414(2).. We show the emergence of finite size corrections, which occur much earlier than the height saturation.

Macro-vascular artifacts are a common arterial spin labeling (ASL) finding in populations with prolonged arterial transit time (ATT) and result in vascular regions with spuriously increased cerebral blood flow (CBF) and tissue regions with spuriously decreased CBF. This study investigates whether there is an association between the spatial signal distribution of a single post-label delay ASL CBF image and ATT. In 186 elderly with hypertension (46% male, 77.4+-2.5 years), we evaluated associations between the spatial coefficient of variation (CoV) of a CBF image and ATT. The spatial CoV and ATT metrics were subsequently evaluated with respect to their associations with age and sex – two demographics known to influence perfusion. Bland–Altman plots showed that spatial CoV predicted ATT with a maximum relative error of 7.6%. Spatial CoV was associated with age (b=0.163, p=0.028) and sex (b=-0.204, p=0.004). The spatial distribution of the ASL signal on a standard CBF image can be used to infer between-participant ATT differences. In the absence of ATT mapping, the spatial CoV may be useful for the clinical interpretation of ASL in patients with cerebrovascular pathology that leads to prolonged transit of the ASL signal to tissue.

Kooperative Entwicklung ressourceneffizienter Verfahren in der Produktion
Philipp Rädecker, Oliver Zeidler & Prof. Christiane Scharf
Freiberg, 24. November 2016

Purpose/Introduction: The realignment transformation needed for motion correction in fMRI has been shown to have the adverse effect of smoothing the realigned images1. This effect is independent of the accuracy of the estimated motion parameters (it can occur even for accurately estimated motion parameters) and can, in ASL, cause gray-matter (GM) cerebral-blood-flow (CBF) underestimation compared to an acquisition without motion. Here, we investigated the smoothing of the realignment transformation in ASL by creating simulated CBF maps based on T1-weighted (T1w) images and motion parameters obtained from ASL images acquired on patients2.
Methods: ASL data from 66 children (age: 8-18y, median: 12.8y, 34 males) were obtained from the NOVICE study2. This dataset is characterized by a relatively high head motion often associated with scanning children. Images were acquired on Philips 3T Ingenia (pCASL: voxel-size 3x3x6.6mm3, 30 controls/label pairs; T1w: voxel-size 1x1x1mm3).
To simulate ASL time-series that reflect motion from real acquisition, the following processing steps were implemented: (1) T1w-image was co-registered to the first ASL volume and segmented into gray and white-matter posterior probability maps (pGM/pWM) using SPM12. (2) ASL images were realigned with respect to the first volume3 (average motion >1mm or >1° was considered 'high'). (3) The motion-parameters from step 2 were applied to pGM/pWM maps, and the maps were down-sampled to the ASL resolution. This resulted in 60 pGM/pWM volumes mimicking a real ASL acquisition (Fig. 1b). (4) The pGM/pWM maps were realigned to their first respective volume (Fig. 1d) and averaged (Fig. 2d).
Two sets of simulated CBF maps were created: (1) from the pGM/pWM corresponding to the first ASL volume (CBF-static), (2) from the realigned pGMs/pWMs described above (CBF-motion), assuming GM-CBF of 80 mL/min/100g and GM/WM CBF ratio of 3. Local and global GM-CBF values of CBF-motion were compared against the idealized CBF-static case.
Results: Figures 1d and 2d show ‘blurring’ of the realigned pGM in high movement cases. The local GM-CBF in CBF-motion was up to 10% lower than in CBF-static (Fig. 2e); negligible differences (<1%) were seen in relatively low movement cases (Fig. 2f). In all 'high-motion' participants, 4-7% lower global GM-CBF was observed (Fig. 3).
Discussion/Conclusion: Relatively high motion during ASL acquisitions appears to result in a GM-CBF underestimation of 4-7% globally and up to 10% locally. This finding can have important implications in studying patients who tend to move more than their healthy counterparts, which may lead to a GM-CBF underestimation in patients relative to controls.

New treatment options especially of solid tumors including for metastasized prostate cancer (PCa) are urgently needed. Recent treatments of leukemias with chimeric antigen receptors (CARs) underline their impressive therapeutic potential. However CARs currently applied in the clinics cannot be repeatedly turned on and off potentially leading to severe life threatening side effects. To overcome these problems, we recently described a modular CAR technology termed UniCAR: UniCAR T cells are inert but can be turned on by application of one or multiple target modules (TMs). Here we present preclinical data summarizing the retargeting of UniCAR T cells to PCa cells using TMs directed to prostate stem cell-(PSCA) or/and prostate membrane antigen (PSMA). In the presence of the respective TM(s), we see a highly efficient target-specific and target-dependent activation of UniCAR T cells, secretion of proinflammatory cytokines, and PCa cell lysis both in vitro and experimental mice.

Crystal structure, magnetization, and specific heat were studied on single crystal of uranium intermetallic compound UOsAl. It is a hexagonal Laves phase of MgZn₂ type, space group P6₃/mmc, with lattice parameters a = 536.4 pm, c = 845.3 pm. Shortest inter-uranium distance 313 pm (along the c-axis) is considerably smaller than the Hill limit (340 pm). The compound is a weakly temperature-dependent paramagnet with magnetic susceptibility of ≈1.5*10⁻⁸ m³ mol (at T=2 K), which is slightly higher with magnetic field along the a-axis compared to the c-axis. The Sommerfeld coefficient of electronic specific heat has moderate value of γ = 36 mJ mol⁻¹ K⁻².

We present the magnetic and thermal properties of the bosonic-superfluid phase in a spin-dimer network using both quasistatic and rapidly changing pulsed magnetic fields. The entropy derived from a heat-capacity study reveals that the pulsed-field measurements are strongly adiabatic in nature and are responsible for the onset of a significant magnetocaloric effect (MCE). In contrast to previous predictions we show that the MCE is not just confined to the critical regions, but occurs for all fields greater than zero at sufficiently low temperatures. We explain the MCE using a model of the thermal occupation of exchange-coupled dimer spin states and highlight that failure to take this effect into account inevitably leads to incorrect interpretations of experimental results. In addition, the heat capacity in our material is suggestive of an extraordinary contribution from zero-point fluctuations and appears to indicate universal behavior with different critical exponents at the two field-induced critical points. The data at the upper critical point, combined with the layered structure of the system, are consistent with a two-dimensional nature of spin excitations in the system.

Cell adhesion-mediated resistance limits the success of cancer therapies and is a great obstacle to overcome in the clinic. Since the 1990s, where it became clear that adhesion of tumor cells to the extracellular matrix is an important mediator of therapy resistance, a lot of work has been conducted to understand the fundamental underlying mechanisms and two paradigms were deduced: cell adhesion-mediated radioresistance (CAM-RR) and cell adhesion-mediated drug resistance (CAM-DR). Preclinical work has evidently demonstrated that targeting of integrins, adapter proteins and associated kinases comprising the cell adhesion resistome is a promising strategy to sensitize cancer cells to both radiotherapy and chemotherapy. Moreover, the cell adhesion resistome fundamentally contributes to adaptation mechanisms induced by radiochemotherapy as well as molecular drugs to secure a balanced homeostasis of cancer cells for survival and growth. Intriguingly, this phenomenon provides a basis for synthetic lethal targeted therapies simultaneously administered to standard radiochemotherapy. In this review, we summarize current knowledge about the cell adhesion resistome and highlight targeting strategies to override CAM-RR and CAM-DR.

For the first time, stable intrinsic plutonium colloid was prepared by ultrasonic treatment of PuO2 suspensions in pure water at room temperature. The yield of Pu colloid was found to increase with PuO2 specific surface area and by using reducing carrier gas mixture. Kinetic data evidenced that both chemical and mechanical effects of ultrasound strongly contribute to the mechanism of Pu colloid formation. At first, the fragmentation of initial PuO2 particles accelerates the overall process providing larger surface of contact between cavitation bubbles and solids. Furthermore, hydrogen formed during sonochemical water splitting enables reduction of Pu(IV) to more soluble Pu(III), which then reoxidizes yielding Pu(IV) colloid. Sonochemical colloid was compared with hydrolytic one using HRTEM, Pu LIII XAS, and STXM/NEXAFS (O K-edge) techniques. Both colloids are composed of quasi-spherical nanocrystalline particles of PuO2 (fcc, Fm¯3 m space group) measuring about 7 nm and 3 nm, respectively. Moreover, HRTEM revealed nanostructured morphology for initial PuO2. The EXAFS spectra of colloidal PuO2 nanoparticles were fitted using triple oxygen shell model for the first coordination sphere of Pu(IV). HRTEM and EXAFS studies revealed the correlation between the number of Pu-O and Pu-Pu contacts and atomic surface-to-volume ratio of studied PuO2 nanoparticles. The STXM/NEXAFS study indicated that the oxygen state of hydrolytic Pu colloid is influenced by hydrolyzed Pu(IV) species in much more extent than PuO2 nanoparticles of sonochemical colloid. In general, hydrolytic and sonochemical colloids can be described as core-shell nanoparticles composed of quasi stoichiometric PuO2 core and hydrolyzed Pu(IV) moieties at the surface shell.

Luminescence spectroscopy is a powerful tool to study the chemistry of f-elements (actinides – An, lanthanides – Ln) in trace concentration. Manifold operating mode, e.g. steady-state, time-resolved, laser-induced, site-selective, cryogenic, etc. were used to investigate the environmental behavior of An/Ln in various geological and biological systems.

HfO2 films were grown on 4-inch native SiO2/Si wafers by Atomic Layer Deposition (ALD) from tetrakis(dimethylamido)hafnium and deionized water in a Savannah S100 system. The temperature was varied from 100°C to 350°C in steps of 50 K. All other ALD process parameters were fixed. The resulting HfO2 layers were characterized in terms of thickness homogeneity, growth rate per cycle, surface roughness, crystal structure, stoichiometry, mass density, optical bandgap and index of refraction. Based on the obtained growth rate of HfO2 on SiO2/Si, 25 nm thick HfO2 layers were grown on Pt/Ti/SiO2/Si substrates for electrical characterization. Furthermore, the most important structural properties were compared for the growth of HfO2 on Pt/Ti/SiO2/Si and SiO2/Si substrates.
HfO2 breakdown voltages show a clear decrease with increasing growth temperature, which was correlated to the crystallinity of the films due to the preferred breakdown along grain boundaries. For resistive switching, an amorphous HfO2 layer grown at 150°C was compared to a crystalline one grown at 300°C. Furthermore, resistive switching characteristics were tuned by the use of two different top electrode materials, namely an inert Pt or a reactive Ti/Pt electrode. The contact diameter was 50 μm. In the majority of cases, the resistive switching mode was found to be unipolar. Only the combination of a crystalline HfO2 layer with an inert Pt bottom and a reactive Ti/Pt top electrode led to a “pseudo-bipolar” switching mode with a convertible SET and RESET polarity.

After a short introduction we will highlight processing issues (setup, comparison of annealing methods, relevant requirements for annealing due to doping, diffusion, activation, recrystallization, defect engineering), as well as doping issues for group IV-semiconductors (shallow junctions, hyperdoping, solar cells, superconductivity) and other semiconductors (manganese doping of GaAs for diluted magnetic semiconductors, doping for transparent conductive oxides). Mostly ion implantation serves as a source of dopants, but also diffusion from deposited layers is of growing importance.

Einerseits sind die Rohstofflieferungen Afrikas für die Versorgung der Weltwirtschaft von Bedeutung, andererseits spielen die Exporte aber auch eine wesentliche Rolle für die Wirtschaft dieser Länder. Die steigende Nachfrage (auch in Schwellenmärkten) und der Preisanstieg für einzelne Rohstoffe könnten eine günstige Gelegenheit für die afrikanischen Bergbauländer darstellen.

In großen Teilen des subsaharischen Afrikas wird der Bergbau jedoch noch in sehr kleinem Maßstab und – aufgrund keiner oder nur geringer Mechanisierung – mit hohem Arbeitsaufwand betrieben. Diese Arbeiten werden allgemein als Einzel- und Kleinbergbau (Artisanal and Small-Scale Mining, ASM) kategorisiert. In Zentralafrika steht der ASM zusätzlich auch mit sogenannten „Konfliktmineralien“ in Verbindung (kurz gesagt, „Konfliktressourcen sind natürliche Ressourcen, deren systematische Ausbeutung und Handel im Kontext eines Konfliktes zu schwersten Menschenrechtsverletzungen, Verletzungen des humanitären Völkerrechts oder Verwirklichung völkerstrafrechtlicher Tatbestände führen kann“ (BICC, 1994)).

Diese Präsentation vermittelt einen Überblick über den Bergbau in Afrika, sowohl über industriellen Bergbau als auch Kleinbergbau, und behandelt das Thema der Konfliktmineralien. Es wird ebenfalls die Verbindung zwischen den beteiligten Akteuren und den Initiativen rund um ASM und Konfliktmineralien aufgezeigt.

This study was done under the framework of the “OptimOre” project which is part of EU Horizon 2020. Froth flotation is applied for obtaining a pre-concentrate from tailings material sourced from an old mine in the Barruecopardo district, located in the province of Salamanca in Spain. Representative samples from the as-received material were submitted to several characterization analyses: MLA, particle size measurements, contact angle measurements, and ICP-AES. Information from the preceding tests were used to design flotation experiments where five factors: collector type, frother type, depressant addition, pH level, and collector dosage were investigated.

Milling was performed on the feed material before flotation because the starting size was too coarse. The flotation behavior of the material was examined and different factor level combinations resulted in varying degrees of recovery and concentrate grades --- the highest attained averaging 35% and 0.36% W (Enrichment ratio = 14) respectively. Further improvements on these results were targeted and thus the grinding time was increased. The merits of this step in terms of mass collection, grade, and recovery are discussed. Exploratory ideas on the effect of the factor levels investigated were also presented.

This paper is part of an EU funded collaboration under the Horizon 2020 program on the optimization of mineral processing operations of European tungsten and tantalum complex low-grade ores, called OptimOre. There froth flotation is an important process especially for scheelite. It is a versatile mineral processing method, which still lacks of physical and chemical comprehensive, accurate and internationally recognized models. The work package on froth flotation within OptimOre is thus dedicated to developing improved fundamental flotation models with the help of advanced automated mineralogical analyses of the input and output streams of flotation cells.

Reliable flotation models can be potentially used to simplify and shorten lab testing procedures, better understand and predict ore behavior but also establish the potential recovery and grade of the targeted mineral(s).

A first step in fundamental flotation modelling is to obtain the flotation rates of minerals with respect to their size and liberation. This is achieved by back calculation of recovery rates typically under the assumption of a first-order rate process.

In this paper, froth flotation rates of scheelite are back-calculated by size fractions and liberation classes. Flotation parameters such as reagent regime, cell hydrodynamics and pulp and froth properties are systematically varied in properly designed experiments with measured effects on the bubble surface area flux. Finally these flotation rates are then used to critically assess several existing first principle flotation models (Yoon, Pyke and others), which are compared with each other in terms of applicability and limitations.

The scheelite bearing ore used for the experiments is from the Mittersill deposit (Austria). The particle properties (e.g. liberation, mineral composition) are studied with automated mineralogy (Mineral Liberation Analysis) as well as elemental assays by ICP-MS analyses. Froth flotation tests are conducted with a bottom-driven Magotteaux cell equipped with a bubble cam sizer and froth cam.

This poster gives an overview of the complex technical aspects of Flash-lamp-annealing-tools for thermal processing in the millisecond range used at the Helmholtz Research Center Dresden-Rossendorf (HZDR). It outlines that Flash Lamp Annealing (FLA) is established as a high-performance alternative to Rapid Thermal Annealing and Furnace Annealing when it comes to treatment of the most advanced thin layer and coating materials, thus enabling the fabrication of novel electronic structures and materials. It shows the unique variety of parameters the HZDR is able to provide for applications ranging from annealing of implanted Si and Ge, transparent conductive oxides, photovoltaic materials, silver and copper inks on various non-metal substrates to exceptional applications (roof tiles, watchcases). It explains, how crucial parameters, such as emission spectrum, energy density, and preheat temperature are monitored to provide a reliable reproducibility. Modelling aspects regarding temperature distribution and heat transport within the millisecond range will also be addressed. Furthermore, a summary will be given of characteristic features of our tools to convey the diversity of the fields of application and the enormous range of possible research.

The “OptimOre” project, as part of the EU Horizon 2020, proposes the research and development of improved modelling and control technologies of tantalum and tungsten ore processing using advanced sensing and artificial intelligence techniques. The Helmholtz Institute Freiberg for Resource Technology is responsible for the Work Package „Froth flotation”.
Within the frame of the OptimOre project, a lab scale froth flotation study was conducted on the tailings of the Barruecopardo mine (Spain) with scheelite as the main tungsten-bearing mineral and a feed grade of 0,025% tungsten. Barruecopardo is part of the world-class tungsten deposits and is being redeveloped for mining.
The reagent system is the main focus of this study, with an emphasis on the influence of depressant combinations aimed at depressing silicates in the gangue. Two collectors at four dosages, two frothers and four depressant combinations were tested at two different pH.
The results show that a higher pH usually stabilizes the froth regardless of the frother and increases the mass pull but does not impact the tungsten recovery. The depressant combination is highly relevant in grade, as expected, but also in recovery. It can hinder it badly or increase it tremendously. Furthermore, the performance of the first collector without depressant is significantly higher than after adding depressant. On the contrary, the second collector that performed poorly in a depressant-less environment yields the best results in presence of depressants. The presence of sodium carbonate (Na2CO3) enhances that effect. Possible interpretations for these observations are given.

There is no abstract available, since this is an Editorial.