Dr. Holger Lippold
Head Reactive Transport
Research Associate
Phone: +49 351 260 - 4670

Katrin Gerstner
Secretary Neuroradiopharmaceuticals
Secretariat / Research Site Leipzig
Phone: +49 351 260 - 4601, 4600
Fax: +49 351 260 - 4699


Effect of polymeric cement additives on the mobility of radionuclides under near-field conditions of a final radwaste repository


Cement or concrete will be used as backfill, liner and building material in a final repository. Besides corrosion products of spent fuel containers, cementitious materials are the first chemical retention barrier for radionuclides in case of their release after water influx. At the same time, cement is exposed to leaching processes and generates highly alkaline solutions (up to pH 13.5). This high pH will also influence the barrier functions of buffers (e.g., bentonites) and host formation, in particular clay rock. Pore waters of clay are characterised by very high electrolyte contents (up to 4 M). Adsorption of actinides / lanthanides in these systems is studied in the joint project GRaZ (“Geochemical Retention of Radionuclides at Cement Alteration Phases”), funded by the German Federal Ministry for Economic Affairs and Energy (BMWi).

Skizze für ID 45614 (GRaZ)

As part of this project, the work packages performed by our group are focused on the mobilising potential of polymeric additives contained in cement; so-called superplasticisers, which may be set free by leaching. Their complexing properties could keep radiometals in solution, facilitating their migration. For the example of polycarboxylate ethers as new generation of superplasticisers, conditions of a mobilisation will be identified in systematic investigations of complexation and adsorption in dependence on pH and electrolyte content. The effects of these parameters shall be explained by modelling on the basis of interactions in the constituent subsystems. Taking advantage of the unique analytical benefits of radioactive tracers is the central idea of our experimental work. 14C-labelled polycarboxylate ethers will be synthesised, providing access to very low concentration levels. 152Eu is employed as a tracer analogue of actinides.



Collaborating institutions:

Dr. Holger Lippold

Michael Becker

Dr. Katja Schmeide

Johannes Gutenberg University Mainz, Institute for Nuclear Chemistry

Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal

Saarland University, Institute of Inorganic and Analytical Chemistry and Radiochemistry

Technical University Dresden, Department of Radiation Protection

Technical University Munich, Department of Chemistry - Theoretical Chemistry

University of Heidelberg, Institute of Physical Chemistry

University of Potsdam, Institute of Chemistry - Physical Chemistry