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Magnetocaloric effect in GdNi2 for cryogenic gas liquefaction studied in magnetic fields up to 50 T

Taskaev, S.; Khovaylo, V.; Skokov, K.; Liu, W.; Bykov, E.; Ulyanov, M.; Bataev, D.; Basharova, A.; Kononova, M.; Plakhotskiy, D.; Bogush, M.; Gottschall, T.; Gutfleisch, O.

Natural gases have played a significant role in different sectors of the global economy. Recent analyses have shown that the world’s gas consumption doubled over the last three decades; further growth of the gas consumption is predicted, rising to be 23%–28% of the total primary energy demand by 2030. Therefore, liquefaction of natural gases rapidly gains global importance. In this context, magnetic refrigeration emerges as a modern energy-saving technique, which is an alternative to the traditional gas-compression refrigeration. This paper is devoted to the study of the magnetocaloric effect in magnetic fields up to 10 T on a representative of the Laves phase alloys, GdNi2, which is considered as a perspective material for liquefaction of natural gases. For a magnetic field change of 10 T, the magnetic entropy change ΔSm≈−17 J/kg K and the adiabatic temperature change ΔTad ≈ 6.8 K was attained around Curie temperature TC = 70 K. The maximal value of the adiabatic temperature change measured directly in pulsed magnetic fields up to 50 T is ΔTad ≈ 15 K.

Involved research facilities

  • High Magnetic Field Laboratory (HLD)

Permalink: https://www.hzdr.de/publications/Publ-31361