RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

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Surface Complex Formation Data:

Mineral: Corundum
Reference: S05
SCM Type: TL - Triple Layer
Ligand: Tl<1+> - thallium
Site Type: »Al-OH
Equation: »Al-OH + Tl<1+>  ⇔  »Al-O-Tl + H<1+>
LogK: -7.0         LogK2.31 nm−2 (SSD-normalized):   -8.39
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Al-O<1-> + Tl<1+> = »Al-O-Tl logK = 5.2 »Al-OH = »Al-O<1-> + H<1+> pK2 = -logK = 12.2 sum »Al-OH + Tl<1+> = »Al-O-Tl + H<1+> logK=5.2 -12.2 = -7.0
 
1 data sets were retrieved