| Mineral: |
Birnessite |
| Reference: |
PD13 |
| SCM Type: |
DDL - Diffuse Double Layer |
| Ligand: |
Eu<3+>
- europium(III)
|
| Site Type: |
»Mn(s)-OH |
| Equation: |
»Mn(s)-OH + Eu<3+> ⇔ »Mn(s)-O-Eu<2+> + H<1+> |
| LogK: |
0.33
LogK2.31 nm−2 (SSD-normalized): 4.10
|
| Experiment: |
Best Estimate |
| Ionic Strength: |
NaNO3
|
| Temperature: |
298.15 K |
| Solid/Liquid Ratio: |
0.01 g/L |
| pH Range: |
4 - 9.5 |
| Ligand Concentration Range: |
8.226E-7 mol/L |
| Fit Method: |
LFER |
| Comment: |
REE-HMO stability constants extrapolated from the LFER established by [TBM04]; logKEuOH = 6.24 (the first hydrolysis constant of REE, logKREE-OH, is taken from the NIST database [38])
|
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