Towards tailoring hydrophobic interaction with uranyl(VI) oxygen for C-H activation

Tsushima, S.⁽¹⁾; Kretzschmar, J.⁽²⁾; Doi, H.; Okuwaki, K.⁽³⁾; Kaneko, M.⁽⁴⁾; Mochizuki, Y.⁽⁵⁾; Takao, K.⁽⁶⁾

• Chemical Communications (2024)
  Online First (2024) DOI: 10.1039/D4CC01030B⁽⁷⁾

Cold denaturation of DNA origami nanostructures

Dornbusch, D.⁽⁸⁾; Hanke, M.; Tomm, E.; Grundmeier, G.; Keller, A.; Fahmy, K.⁽⁹⁾; Kielar, C.⁽¹⁰⁾

• Chemical Communications (2024)
  Online First (2024) DOI: 10.1039/D3CC05985E⁽¹¹⁾

Large-Scale Formation of DNA Origami Lattices on Silicon

Tapio, K.⁽¹²⁾; Kielar, C.⁽¹³⁾; Parikka, J. M.⁽¹⁴⁾; Keller, A.⁽¹⁵⁾; Järvinen, H.⁽¹⁶⁾; Fahmy, K.⁽¹⁷⁾; Jussi Toppari, J.⁽¹⁸⁾

• Chemistry of Materials 35(2023)5, 1961-1971
  Online First (2023) DOI: 10.1021/acs.chemmater.2c03190⁽¹⁹⁾
  Cited 5 times in Scopus

Fate of Oxidation States at Actinide Centers in Redox-Active Ligand Systems Governed by Energy Levels of 5f Orbitals

Takeyama, T.⁽²⁰⁾; Tsushima, S.⁽²¹⁾; Gericke, R.⁽²²⁾; Kaden, P.⁽²³⁾; März, J.⁽²⁴⁾; Takao, K.⁽²⁵⁾

• Chemistry - A European Journal 29(2023)69, e202302702
  Online First (2023) DOI: 10.1002/chem.202302702⁽²⁶⁾

Superstructure-dependent stability of DNA origami nanostructures in the presence of chaotropic denaturants

Hanke, M.; Dornbusch, D.⁽²⁷⁾; Tomm, E.; Grundmeier, G.; Fahmy, K.; Keller, A.

• Nanoscale 15(2023)41, 16590-16600
  DOI: 10.1039/d3nr02045b⁽²⁸⁾
  Cited 1 times in Scopus

Exploring Antibacterial Activity and Bacterial-Mediated Allotropic Transition of Differentially Coated Selenium Nanoparticles

Ruiz-Fresneda, M. A.; Schaefer, S.; Hübner, R.⁽²⁹⁾; Fahmy, K.⁽³⁰⁾; Merroun, M. L.

Involved research facilities

• Ion Beam Center DOI: 10.17815/jlsrf-3-159⁽³¹⁾

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• ACS Applied Materials and Interfaces 15(2023), 29958-29970
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Interaction between the transferrin protein and plutonium (and thorium), what’s new?

Zurita, C.; Tsushima, S.⁽³⁴⁾; Lorenzo Solari, P.; Menut, D.; Dourdain, S.; Jeanson, A.; Creff, G.; Den Auwer, C.

• Chemistry - A European Journal 29(2023)55, e202300636
  Online First (2023) DOI: 10.1002/chem.202300636⁽³⁵⁾

Europium(III) Meets Etidronic Acid (HEDP): a Coordination Study Combining Spectroscopic, Spectrometric, and Quantum Chemical Methods

Heller, A.; Senwitz, C.; Foerstendorf, H.⁽³⁶⁾; Tsushima, S.⁽³⁷⁾; Holtmann, L.; Drobot, B.⁽³⁸⁾; Kretzschmar, J.⁽³⁹⁾

• Molecules 28(2023)11, 4469
  DOI: 10.3390/molecules28114469⁽⁴⁰⁾
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Special Issue “Advances in Monitoring Metabolic Activities of Microorganisms by Calorimetry”

Matulis, D.; Wadsö, L.; Fahmy, K.⁽⁴¹⁾

• Microorganisms 11(2023)5, 1204
  DOI: 10.3390/microorganisms11051204⁽⁴²⁾

Distinct Effects of Chemical Toxicity and Radioactivity on Metabolic Heat of Cultured Cells Revealed by “Isotope-Editing”

Oertel, J.; Sachs, S.⁽⁴³⁾; Flemming, K.; Hassan Obeid, M.; Fahmy, K.⁽⁴⁴⁾

• Microorganisms 11(2023)3, 584
  DOI: 10.3390/microorganisms11030584⁽⁴⁵⁾
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Utility of redox-active ligands for reversible multi-electron transfer in uranyl(VI) complexes

Takeyama, T.; Tsushima, S.⁽⁴⁶⁾; Takao, K.

• Inorganic Chemistry Frontiers 10(2023)14, 4028-4044
  Online First (2023) DOI: 10.1039/D3QI00189J⁽⁴⁷⁾
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Neptunyl(VI) Nitrate Coordination Polymer with Bis(2-pyrrolidone) Linkers Highlighting Crystallographic Analogy and Solubility Difference in Actinyl(VI) Nitrates

Takeyama, T.⁽⁴⁸⁾; März, J.⁽⁴⁹⁾; Ono, R.⁽⁵⁰⁾; Tsushima, S.⁽⁵¹⁾; Takao, K.⁽⁵²⁾

• Inorganics 11(2023)3, 104-113
  DOI: 10.3390/inorganics11030104⁽⁵³⁾
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Eu(III) and Cm(III) Complexation by the Aminocarboxylates NTA, EDTA, and EGTA Studied with NMR, TRLFS, and ITC – An Improved Approach to More Robust Thermodynamics

Friedrich, S.⁽⁵⁴⁾; Sieber, C.; Drobot, B.⁽⁵⁵⁾; Tsushima, S.⁽⁵⁶⁾; Barkleit, A.⁽⁵⁷⁾; Schmeide, K.⁽⁵⁸⁾; Stumpf, T.⁽⁵⁹⁾; Kretzschmar, J.⁽⁶⁰⁾

• Molecules 28(2023)12, 4881
  Online First (2023) DOI: 10.3390/molecules28124881⁽⁶¹⁾
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Crystal Structures of Ce(IV) Nitrates with Bis(2-pyrrolidone) Linker Molecules Deposited from Aqueous Solutions with Different HNO3 Concentrations

Ono, R.; Kazama, H.; März, J.⁽⁶²⁾; Tsushima, S.⁽⁶³⁾; Takao, K.

• Inorganic Chemistry 62(2023)1, 454-463
  Online First (2022) DOI: 10.1021/acs.inorgchem.2c03554⁽⁶⁴⁾

Interdisciplinary biophysical studies of membrane proteins bacteriorhodopsin and rhodopsin

Fahmy, K.⁽⁶⁵⁾; Sakmar, T.

• Biophysical Reviews 15(2023), 111-125
  Online First (2022) DOI: 10.1007/s12551-022-01003-y⁽⁶⁶⁾
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Simple Growth–Metabolism Relations Are Revealed by Conserved Patterns of Heat Flow from Cultured Microorganisms

Fahmy, K.⁽⁶⁷⁾

• Microorganisms 10(2022), 1397
  DOI: 10.3390/microorganisms10071397⁽⁶⁸⁾
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Lanmodulin peptides – unravelling the binding of the EF-Hand loop sequences stripped from the structural corset

Gutenthaler, S. M.⁽⁶⁹⁾; Tsushima, S.⁽⁷⁰⁾; Steudtner, R.⁽⁷¹⁾; Gailer, M.; Hoffmann-Röder, A.; Drobot, B.⁽⁷²⁾; Daumann, L. J.

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Anion-specific structure and stability of guanidinium-bound DNA origami

Hanke, M.; Dornbusch, D.⁽⁷⁵⁾; Hadlich, C.; Roßberg, A.; Hansen, N.; Grundmeier, G.; Tsushima, S.⁽⁷⁶⁾; Keller, A.; Fahmy, K.⁽⁷⁷⁾

• Computational and Structural Biotechnology Journal 20(2022), 2611-2623
  Online First (2022) DOI: 10.1016/j.csbj.2022.05.037⁽⁷⁸⁾
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2-Phosphonobutane-1,2,4,-Tricarboxylic Acid (PBTC): pH-Dependent Behavior Studied by Means of Multinuclear NMR Spectroscopy

Kretzschmar, J.⁽⁷⁹⁾; Wollenberg, A.; Tsushima, S.⁽⁸⁰⁾; Schmeide, K.⁽⁸¹⁾; Acker, M.

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Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate

Hanke, M.; Hansen, N.; Ruiping, C.; Grundmeier, G.; Fahmy, K.⁽⁸⁴⁾; Keller, A.

• International Journal of Molecular Sciences 23(2022)5, 2817
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Fully Chelating N3O2-Pentadentate Planar Ligands Designed for Strongest and Selective Capture of Uranium from Seawater

Mizumachi, T.; Sato, M.; Kaneko, M.; Takeyama, T.; Tsushima, S.⁽⁸⁶⁾; Takao, K.

• Inorganic Chemistry 61(2022)16, 6175-6181
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Hydrophobic Core Formation and Secondary Structure Elements in Uranyl(VI)–Binding Peptides

Tsushima, S.⁽⁸⁸⁾; Takao, K.

• Physical Chemistry Chemical Physics 24(2022), 4455-4461
  Online First (2022) DOI: 10.1039/D1CP05401E⁽⁸⁹⁾
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Synthesis and characterization of a uranyl(vi) complex with 2,6-pyridine-bis(methylaminophenolato) and its ligand-centred aerobic oxidation mechanism to a diimino derivative

Takeyama, T.; Iwatsuki, S.; Tsushima, S.⁽⁹⁰⁾; Takao, K.

• Dalton Transactions 51(2022), 6576-6585
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Interaction of Th(IV), Pu(IV) and iron(III) with ferritin protein : how similar ?

Zurita, C.; Tsushima, S.⁽⁹²⁾; Lorenzo Solari, P.; Jeanson, A.; Creff, G.; Den Auwer, C.

• Journal of Synchrotron Radiation 29(2022)1, 45-52
  DOI: 10.1107/S1600577521012340⁽⁹³⁾
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Effects of Substituents on the Molecular Structure and Redox Behavior of Uranyl(V/VI) Complexes with N3O2‑Donating Schiff Base Ligands

Takeyama, T.⁽⁹⁴⁾; Tsushima, S.⁽⁹⁵⁾; Takao, K.⁽⁹⁶⁾

• Inorganic Chemistry 60(2021)15, 11435-11449
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Quenching Mechanism of Uranyl(VI) by Chloride and Bromide in Aqueous and Non-Aqueous Solutions

Haubitz, T.; Drobot, B.⁽⁹⁸⁾; Tsushima, S.⁽⁹⁹⁾; Steudtner, R.⁽¹⁰⁰⁾; Stumpf, T.; Kumke, M. U.

• Journal of Physical Chemistry A 125(2021), 4380-4389
  DOI: 10.1021/acs.jpca.1c02487⁽¹⁰¹⁾
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Two Be or Not Two Be: The Nuclear Autoantigen La/SS-B Is able to form Dimers and Oligomers in a Redox Dependent Manner

Berndt, N.⁽¹⁰²⁾; Bippes, C. C.; Michalk, I.; Bachmann, D.; Bachmann, J.; Puentes-Cala, E.; Bartsch, T.; Loureiro, L. R.; Kegler, A.; Bergmann, R.⁽¹⁰³⁾; Gross, J. K.; Gross, T.; Kurien, B. T.; Scofield, R. H.; Farris, A. D.; James, J. A.; Schmitz, M.; Fahmy, K.⁽¹⁰⁴⁾; Feldmann, A.⁽¹⁰⁵⁾; Arndt, C.⁽¹⁰⁶⁾; Bachmann, M.⁽¹⁰⁷⁾

• International Journal of Molecular Sciences 22(2021)7, 3377
  DOI: 10.3390/ijms22073377⁽¹⁰⁸⁾
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DNA-Mediated Stack Formation of Nanodiscs

Subramanian, M.; Kielar, C.; Tsushima, S.⁽¹⁰⁹⁾; Fahmy, K.⁽¹¹⁰⁾; Oertel, J.

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• Molecules 26(2021)6, 1647
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Fluorite-like hydrolyzed hexanuclear coordination clusters of Zr(IV) and Hf(IV) with syn-syn bridging N,N,N-trimethylglycine in soft crystal structures exhibiting cold-crystallization

Matsuoka, M.; Tsushima, S.⁽¹¹⁴⁾; Takao, K.

• Inorganica Chimica Acta 528(2021), 120622
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How does iron storage protein ferritin interact with plutonium (and thorium) ?

Zurita, C.; Tsushima, S.⁽¹¹⁶⁾; Bresson, C.⁽¹¹⁷⁾; Garcia-Cortes, M.⁽¹¹⁸⁾; Solari, P. L.⁽¹¹⁹⁾; Jeanson, A.; Creff, G.⁽¹²⁰⁾; Den Auwer, C.⁽¹²¹⁾

• Chemistry - A European Journal 27(2021)7, 2393-2401
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Impact of the microbial origin and active microenvironment on the shape of biogenic elemental selenium nanomaterials

Fischer, S.; Jain, R.⁽¹²³⁾; Krause, T.; Jain, P.; Tsushima, S.⁽¹²⁴⁾; Shevchenko, A.; Hübner, R.⁽¹²⁵⁾; Jordan, N.⁽¹²⁶⁾

• Environmental Science & Technology 55(2021), 9161-9171
  Online First (2021) DOI: 10.1021/acs.est.0c07217⁽¹²⁷⁾
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Dimeric and Trimeric Uranyl(VI)–Citrate Complexes in Aqueous Solution

Kretzschmar, J.⁽¹²⁸⁾; Tsushima, S.⁽¹²⁹⁾; Lucks, C.; Jäckel, E.; Meyer, R.; Steudtner, R.⁽¹³⁰⁾; Müller, K.⁽¹³¹⁾; Roßberg, A.; Schmeide, K.⁽¹³²⁾; Brendler, V.⁽¹³³⁾

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• Inorganic Chemistry 60(2021)11, 7998-8010
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A metabolic switch regulates the transition between growth and diapause in C. elegans

Penkov, S.; Raghuraman, B. K.; Erkut, C.; Oertel, J.; Galli, R.; Ackerman, E. J. M.; Vorkel, D.; Verbavatz, J. M.; Koch, E.; Fahmy, K.; Shevchenko, A.; Kurzchalia, T. V.

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C. elegans possess a general program to enter cryptobiosis that allows dauer larvae to survive different kinds of abiotic stress

Gade, V. R.; Traikov, S.; Oertel, J.; Fahmy, K.; Kurzchalia, T. V.

• Scientific Reports 10(2020), 13466
  DOI: 10.1038/s41598-020-70311-8⁽¹⁴¹⁾
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Trimeric uranyl(VI)–citrate forms Na⁺, Ca²⁺, and La³⁺ sandwich complexes in aqueous solution

Kretzschmar, J.⁽¹⁴²⁾; Tsushima, S.⁽¹⁴³⁾; Drobot, B.⁽¹⁴⁴⁾; Steudtner, R.⁽¹⁴⁵⁾; Schmeide, K.⁽¹⁴⁶⁾; Stumpf, T.

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• Chemical Communications 56(2020), 13133-13136
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Essential Role of Heterocyclic Structure of N-Alkylated 2-Pyrrolidone Derivatives for Recycling Uranium from Spent Nuclear Fuels

Inoue, T.; Kazama, H.; Tsushima, S.⁽¹⁵⁰⁾; Takao, K.⁽¹⁵¹⁾

• Bulletin of the Chemical Society of Japan 93(2020)7, 846-853
  DOI: 10.1246/bcsj.20200061⁽¹⁵²⁾
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Crystallization of colourless hexanitratoneptunate(IV) with anhydrous H+ countercations trapped into hydrogen bond polymer with diamide linkers

Takao, K.⁽¹⁵³⁾; März, J.⁽¹⁵⁴⁾; Matsuoka, M.; Mashita, T.; Kazama, H.; Tsushima, S.⁽¹⁵⁵⁾

• RSC Advances 10(2020), 6082-6087
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Crystallization of Anhydrous Proton from Acidic Aqueous Solution with Diamide Building Block

Kazama, H.; Tsushima, S.; Takao, K.

• Crystal Growth & Design 19(2019)11, 6048-6052
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Lanthanide–induced conformational change of methanol dehydrogenase involving coordination change of cofactor pyrroloquinoline quinone

Tsushima, S.⁽¹⁵⁸⁾

• Physical Chemistry Chemical Physics 21(2019), 21979-21983
  Online First (2019) DOI: 10.1039/C9CP03953H⁽¹⁵⁹⁾
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• Poster
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Calcium binding to a disordered domain of a type III-secreted protein from a coral pathogen promotes secondary structure formation and catalytic activity

Hoyer, E.; Knöppel, J.; Liebmann, M.; Steppert, M.; Raiwa, M.; Herczynski, O.; Hanspach, E.; Zehner, S.; Göttfert, M.; Tsushima, S.; Fahmy, K.; Oertel, J.

• Scientific Reports 9(2019), 7115
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Photocatalytic Oxygenation of Cyclohexene Initiated by Excitation of [UO2(OPCyPh2)4]2+ under Visible Light

Mashita, T.; Tsushima, S.⁽¹⁶¹⁾; Takao, K.⁽¹⁶²⁾

• ACS Omega 4(2019)4, 7194-7199
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Body size-dependent energy storage causes Kleiber’s law scaling of the metabolic rate in planarians

Thommen, A.; Werner, S.; Frank, O.; Philipp, J.; Knittelfelder, O.; Quek, Y.; Fahmy, K.; Shevchenko, A.; Friedrich, B. M.; Jülicher, F.; Rink, J. C.

• eLife 8(2019), e38187
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Recovery of gallium from wafer fabrication industry wastewaters by Desferrioxamine B and E using reversed-phase chromatography approach

Jain, R.; Fan, S.; Kaden, P.; Tsushima, S.; Foerstendorf, H.; Barthen, R.; Lehmann, F.; Pollmann, K.

• Water Research 158(2019)
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Destabilization of DNA through interstrand crosslinking by UO22+

Rossberg, A.; Abe, T.; Okuwaki, K.; Barkleit, A.; Fukuzawa, K.; Nakano, T.; Mochizuki, Y.; Tsushima, S.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽¹⁶⁶⁾

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Crystal Structure of Regularly Th-Symmetric [U(NO₃)₆]²⁻ Salts with Hydrogen Bond Polymers of Diamide Building Blocks

Takao, K.; Kazama, H.; Ikeda, Y.; Tsushima, S.

• Angewandte Chemie - International Edition 58(2019), 240-243
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• Angewandte Chemie 131(2019), 246-249
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Cm3+/ Eu3+ Induced Structural, Mechanistic and Functional Implications for Calmodulin

Drobot, B.⁽¹⁷¹⁾; Schmidt, M.⁽¹⁷²⁾; Mochizuki, Y.⁽¹⁷³⁾; Abe, T.; Okuwaki, K.; Brulfert, F.; Falke, S.⁽¹⁷⁴⁾; Samsonov, S.⁽¹⁷⁵⁾; Komeiji, Y.⁽¹⁷⁶⁾; Betzel, C.⁽¹⁷⁷⁾; Stumpf, T.; Raff, J.⁽¹⁷⁸⁾; Tsushima, S.⁽¹⁷⁹⁾

• Physical Chemistry Chemical Physics 21(2019)38, 21213-21222
  Online First (2019) DOI: 10.1039/C9CP03750K⁽¹⁸⁰⁾
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Interdisciplinary round-robin test on molecular spectroscopy of the U(VI) acetate system

Müller, K.; Foerstendorf, H.; Steudtner, R.; Tsushima, S.; Kumke, M. U.; Lefèvre, G.; Rothe, J.; Mason, H.; Szabó, Z.; Yang, P.; Adam, C.; André, R.; Brennenstuhl, K.; Cho, H.; Creff, G.; Coppin, F.; Dardenne, K.; Den Auwer, C.; Drobot, B.; Eidner, S.; Hess, N. J.; Kaden, P.; Kremleva, A.; Kretzschmar, J.; Krüger, S.; Platts, J. A.; Panak, P. J.; Polly, R.; Powell, B. A.; Rabung, T.; Redon, R.; Reiller, P. E.; Rösch, N.; Rossberg, A.; Scheinost, A. C.; Schimmelpfennig, B.; Schreckenbach, G.; Skerencak-Frech, A.; Sladkov, V.; Solari, P. L.; Wang, Z.; Washton, N. M.; Zhang, X.

Involved research facilities

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Ultrafast transient absorption spectroscopy of UO22+ and [UO2Cl]+

Haubitz, T.; Tsushima, S.; Steudtner, R.; Drobot, B.; Geipel, G.; Stumpf, T.; Kumke, M. U.

• Journal of Physical Chemistry A 122(2018)35, 6970-6977
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Controlling the lability of uranyl(VI) through intramolecular π-π Stacking

Mashita, T.; Tsushima, S.; Takao, K.

• Dalton Transactions 47(2018)37, 13072-13080
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DNA-encircled lipid bilayers

Iric, K.; Subramanian, M.; Oertel, J.; Agarwal, N. P.; Matthies, M.; Periole, X.; Sakmar, T. P.; Huber, T.; Fahmy, K.; Schmidt, T.-L.

• Poster
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• Nanoscale 10(2018), 18463-18467
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  Cited 31 times in Scopus

Layer-by-Layer assembly of heparin and peptide-polyethylene glycol conjugates to form hybrid nanothin films of biomatrices

Thomas, A. K.; Wieduwild, R.; Zimmermann, R.; Lin, W.; Friedrichs, J.; Bickle, M.; Fahmy, K.; Werner, C.; Zhang, Y.

• ACS Applied Materials and Interfaces 10(2018)17, 14264-14270
  DOI: 10.1021/acsami.8b02014⁽¹⁸⁷⁾
  Cited 8 times in Scopus

The oxidation of borohydrides by photoexcited [UO₂(CO₃)₃]⁴⁻

Takao, K.⁽¹⁸⁸⁾; Tsushima, S.⁽¹⁸⁹⁾

• Dalton Transactions 47(2018), 5149-5152
  Online First (2018) DOI: 10.1039/c8dt00559a⁽¹⁹⁰⁾
  Cited 6 times in Scopus

Uranium(VI) complexes with a calix[4]arene-based 8-hydroxyquinoline ligand: Thermodynamic and structural characterization based on calorimetry, spectroscopy, and liquid-liquid extraction

Bauer, A.; Jäschke, A.⁽¹⁹¹⁾; Schöne, S.⁽¹⁹²⁾; Barthen, R.; März, J.⁽¹⁹³⁾; Schmeide, K.⁽¹⁹⁴⁾; Patzschke, M.⁽¹⁹⁵⁾; Kersting, B.⁽¹⁹⁶⁾; Fahmy, K.⁽¹⁹⁷⁾; Oertel, J.; Brendler, V.⁽¹⁹⁸⁾; Stumpf, T.

• ChemistryOpen 7(2018)6, 467-474
  DOI: 10.1002/open.201800085⁽¹⁹⁹⁾
  Cited 8 times in Scopus

Molecular and Crystal Structures of Uranyl Nitrate Coordination Polymers with Double-headed 2-Pyrrolidone Derivatives

Kazama, H.; Tsushima, S.; Ikeda, Y.; Takao, K.

• Inorganic Chemistry 56(2017)21, 13530-13534
  DOI: 10.1021/acs.inorgchem.7b02250⁽²⁰⁰⁾
  Cited 12 times in Scopus

Calorimetrically determined U(VI) toxicity in Brassica napus correlates with oxidoreductase activity and U(VI) speciation

Sachs, S.; Geipel, G.; Bok, F.; Oertel, J.; Fahmy, K.

• Environmental Science & Technology 51(2017)18, 10843-10849
  Online First (2017) DOI: 10.1021/acs.est.7b02564⁽²⁰¹⁾
  Cited 14 times in Scopus

Dipolar Relaxation Dynamics at the Active Site of an ATPase Regulated by Membrane Lateral Pressure

Fischermeier, E.; Pospíšil, P.; Sayed, A.; Hof, M.; Solioz, M.; Fahmy, K.

• Angewandte Chemie - International Edition 56(2017)5, 1269-1272
  DOI: 10.1002/anie.201611582⁽²⁰²⁾
  Cited 14 times in Scopus

Shape change of biogenic elemental selenium nanomaterials decreases their colloidal stability

Jain, R.; Jordan, N.; Tsushima, S.; Hübner, R.; Weiss, S.; Lens, P.

• Environmental Science: Nano 4(2017)5, 1054-1063
  DOI: 10.1039/c7en00145b⁽²⁰³⁾
  Cited 38 times in Scopus

Analysis of self‑assembly of S‑layer protein slp‑B53 from Lysinibacillus sphaericus

Liu, J.; Falke, S.; Drobot, B.; Oberthuer, D.; Kikhney, A.; Guenther, T.; Fahmy, K.; Svergun, D.; Betzel, C.; Raff, J.

• European Biophysics Journal 46(2017)1, 77-89
  DOI: 10.1007/s00249-016-1139-9⁽²⁰⁴⁾
  Cited 15 times in Scopus

The molecular switching mechanism at the conserved D(E)RY motif in class-A GPCRs

Sandoval, A.; Eichler, S.; Madathil, S.; Reeves, P. J.; Fahmy, K.; Boeckmann, R. A.

• Biophysical Journal 111(2016)1, 79-89
  DOI: 10.1016/j.bpj.2016.06.004⁽²⁰⁵⁾
  Cited 12 times in Scopus

Rational Structure-Based Rescaffolding Approach to de Novo Design of Interleukin 10 (IL-10) Receptor-1 Mimetics

Ruiz-Gómez, G.; Hawkins, J. C.; Philipp, J.; Künze, G.; Wodtke, R.; Löser, R.; Fahmy, K.; Pisabarro, M. T.

• PLOS ONE 11(2016)4, e0154046
  DOI: 10.1371/journal.pone.0154046⁽²⁰⁶⁾
  Cited 2 times in Scopus

Mechanism of attenuation of uranyl toxicity by glutathione in Lactococcus lactis

Obeid, M. H.; Oertel, J.; Solioz, M.; Fahmy, K.

• Applied and Environmental Microbiology 82(2016)12, 3563-3571
  DOI: 10.1128/AEM.00538-16⁽²⁰⁷⁾
  Cited 12 times in Scopus

Anisotropic metal growth on phospholipid nanodiscs via lipid bilayer expansion

Oertel, J.; Keller, A.; Prinz, J.; Schreiber, B.; Hübner, R.; Kerbusch, J.; Bald, I.; Fahmy, K.

• Scientific Reports 6(2016), 26718
  Online First (2016) DOI: 10.1038/srep26718⁽²⁰⁸⁾
  Cited 7 times in Scopus

Speciation Studies of Metals in Trace Concentrations: The Mononuclear Uranyl(VI) Hydroxo Complexes

Drobot, B.; Bauer, A.; Steudtner, R.; Tsushima, S.; Bok, F.; Patzschke, M.; Raff, J.; Brendler, V.

• Analytical Chemistry 88(2016)7, 3548-3555
  DOI: 10.1021/acs.analchem.5b03958⁽²⁰⁹⁾
  Cited 35 times in Scopus

Uranyl(VI) binding by bis(2-hydroxyaryl)diimine and bis(2-hydroxyaryl)diamine ligand derivatives. Synthetic, X-ray, DFT and solvent extraction studies

Jeazet, H. B. T.; Gloe, K.; Doert, T.; Mizera, J.; Kataeva, O. N.; Tsushima, S.; Bernhard, G.; Weigand, J. J.; Lindoy, L. F.; Gloe, K.

• Polyhedron 103(2016), 198-205
  Online First (2015) DOI: 10.1016/j.poly.2015.01.005⁽²¹⁰⁾
  Cited 8 times in Scopus

A single-strand annealing protein clamps DNA to detect and secure homology

Ander, M.; Subramaniam, S.; Fahmy, K.; Stewart, F.; Schäffer, E.

• PLOS Biology 13(2015)8, A018
  DOI: 10.1371/journal.pbio.1002213⁽²¹¹⁾
  Cited 20 times in Scopus

The interaction of Eu(III) with organoborates – a further approach to understand the complexation in the An/Ln(III)–borate system

Schott, J.; Kretzschmar, J.; Tsushima, S.; Drobot, B.; Acker, M.; Barkleit, A.; Taut, S.; Brendler, V.; Stumpf, T.

• Dalton Transactions 44(2015)24, 11095-11108
  Online First (2015) DOI: 10.1039/c5dt00213c⁽²¹²⁾
  Cited 10 times in Scopus

Spectroscopic evidence for selenium(IV) dimerization in aqueous solution

Kretzschmar, J.; Jordan, N.; Brendler, E.; Tsushima, S.; Franzen, C.; Foerstendorf, H.; Stockmann, M.; Heim, K.; Brendler, V.

• Dalton Transactions 44(2015), 10508
  DOI: 10.1039/c5dt00730e⁽²¹³⁾
  Cited 21 times in Scopus

Combining Luminescence Spectroscopy, Parallel Factor Analysis and Quantum Chemistry to Reveal Metal Speciation - a Case Study of Uranyl (VI) Hydrolysis

Drobot, B.; Steudtner, R.; Raff, J.; Geipel, G.; Brendler, V.; Tsushima, S.

• Chemical Science 6(2015), 964-972
  Online First (2014) DOI: 10.1039/C4SC02022G⁽²¹⁴⁾
  Cited 65 times in Scopus

The Role of Phospholipid Headgroup Composition and Trehalose in the Desiccation Tolerance of Caenorhabditis elegans

Abusharkh, S. E.; Erkut, C.; Oertel, J.; Kurzchalia, T. V.; Fahmy, K.

• Langmuir 30(2014), 12897-12906
  DOI: 10.1021/la502654j⁽²¹⁵⁾
  Cited 16 times in Scopus

Filament formation by metabolic enzymes is a specific adaptation to an advanced state of cellular starvation

Petrovska, I.; Nüske, E.; Munder, M. C.; Kulasegaran, G.; Malinovska, L.; Kroschwald, S.; Richter, D.; Fahmy, K.; Gibson, K.; Verbavatz, J.-M.; Alberti, S.

• eLife 3(2014), 02409
  Online First (2014) DOI: 10.7554/eLife.02409⁽²¹⁶⁾
  Cited 158 times in Scopus

Paramagnetic Decoration of DNA origami Nanostructures by Eu3+ Coordination

Opherden, L.; Oertel, J.; Barkleit, A.; Fahmy, K.; Keller, K.

• Langmuir 30(2014)27, 8152-8159
  DOI: 10.1021/la501112a⁽²¹⁷⁾
  Cited 26 times in Scopus

Experimental and Theoretical Approaches to Redox Innocence of Ligands in Uranyl Complexes: What is Formal Oxidation State of Uranium in Reductant of Uranyl(VI)?

Takao, K.; Tsushima, S.; Ogura, T.; Tsubomura, T.; Ikeda, Y.

• Inorganic Chemistry 53(2014)11, 5772-5780
  Online First (2014) DOI: 10.1021/ic5006314⁽²¹⁸⁾
  Cited 26 times in Scopus

Americium(III) and Europium(III) Complex Formation with Lactate at Elevated Temperatures Studied by Spectroscopy and Quantum Chemical Calculations

Barkleit, A.; Kretzschmar, J.; Tsushima, S.; Acker, M.

• Dalton Transactions 43(2014)29, 11221-11232
  Online First (2014) DOI: 10.1039/C4DT00440J⁽²¹⁹⁾
  Cited 28 times in Scopus

Uranium(VI) Chemistry in Strong Alkaline Solution: Speciation and Oxygen Exchange Mechanism

Moll, H.; Rossberg, A.; Steudtner, R.; Drobot, B.; Müller, K.; Tsushima, S.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²²⁰⁾

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• Inorganic Chemistry 53(2014)3, 1585-1593
  Online First (2014) DOI: 10.1021/ic402664n⁽²²²⁾
  Cited 22 times in Scopus

Structural characterization of the aqueous dimeric uranium(VI) species: (UO2)2CO3(OH)3−

Gückel, K.; Tsushima, S.; Foerstendorf, H.

• Dalton Transactions 42(2013)28, 10172-10178
  DOI: 10.1039/C3DT50814E⁽²²³⁾
  Cited 11 times in Scopus

Formic acid interaction with uranyl(VI) ion: structural and photochemical characterization

Lucks, C.; Roßberg, A.; Tsushima, S.; Foerstendorf, H.; Fahmy, K.; Bernhard, G.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²²⁴⁾

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• Dalton Transactions 42(2013)37, 13584-13589
  DOI: 10.1039/C3DT51711J⁽²²⁶⁾
  Cited 28 times in Scopus

Aqueous Uranium(VI) Complexes with Acetic and Succinic Acid: Speciation and Structure Revisited

Lucks, C.; Rossberg, A.; Tsushima, S.; Foerstendorf, H.; Scheinost, A. C.; Bernhard, G.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²²⁷⁾

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• Inorganic Chemistry 51(2012), 12288-12300
  DOI: 10.1021/ic301565p⁽²²⁹⁾
  ISSN: 0020-1669
  Cited 59 times in Scopus

Curium(III) citrate speciation in biological systems: An europium(III) assisted spectroscopic and quantum chemical study

Heller, A.; Barkleit, A.; Foerstendorf, H.; Tsushima, S.; Bernhard, G.

• Dalton Transactions 41(2012)45, 13969-13983

3D Profile-Based Approach to Proteome-Wide Discovery of Novel Human Chemokines

Tomczak, A.; Sontheimer, J.; Drechsel, D.; Hausdorf, R.; Gentzel, M.; Shevchenko, A.; Eichler, S.; Fahmy, K.; Buchholz, F.; Pisabarro, M. T.

• PLOS ONE 7(2012)5, e36151
  DOI: 10.1371/journal.pone.0036151⁽²³⁰⁾
  Cited 6 times in Scopus

How worms survive desiccation: Trehalose pro water

Erkut, C.; Penkov, S.; Fahmy, K.; Kurzchalia, T. V.

• Worm 1(2012)1, 61-65
  Online First (2012) DOI: 10.4161/worm.19040⁽²³¹⁾

Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

Ikeda-Ohno, A.; Tsushima, S.; Hennig, C.; Yaita, T.; Bernhard, G.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²³²⁾

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• Dalton Transactions 41(2012)24, 7190-7192
  DOI: 10.1039/C2DT12406H⁽²³⁴⁾
  Cited 48 times in Scopus

EXAFS and DFT Investigations of Uranyl-Arsenate Complexes in Aqueous Solution

Gezahegne, W. A.; Hennig, C.; Tsushima, S.; Planer-Friedrich, B.; Scheinost, A. C.; Merkel, B. J.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²³⁵⁾

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• Environmental Science & Technology 46(2012)4, 2228-2233
  Online First (2012) DOI: 10.1021/es203284s⁽²³⁷⁾
  Cited 28 times in Scopus

“yl”-Oxygen Exchange in Uranyl(VI) Ion: A Mechanism Involving (UO₂)₂(μ-OH)₂²⁺ via U-O_yl-U Bridge Formation

Tsushima, S.

• Inorganic Chemistry 51(2012)3, 1434-1439
  DOI: 10.1021/ic201679e⁽²³⁸⁾
  Cited 30 times in Scopus

Trehalose renders dauer larva of Caenorhabditis elegans resistant to extreme desiccation

Erkut, C.; Penkov, S.; Khesbak, H.; Vorkel, D.; Verbavatz, J. M.; Fahmy, K.; Kurzchalia, T. V.

• Current Biology 21(2011)15, 1331-1336

The role of water H-bond imbalances in B-DNA substate transitions and peptide recognition revealed by time-resolved FTIR spectroscopy

Khesbak, H.; Savchuk, O.; Tsushima, S.; Fahmy, K.

• Journal of the American Chemical Society 133(2011), 5834-5842

On the "yl" bond weakening in uranyl(VI) coordination complexes

Tsushima, S.

• Dalton Transactions 40(2011)25, 6732-6737
  DOI: 10.1039/C1DT10481K⁽²³⁹⁾
  Cited 65 times in Scopus

Eu³⁺-Mediated Polymerization of Benzenetetracarboxylic Acid Studied by Spectroscopy, Temperature-Dependent Calorimetry, and Density Functional Theory

Barkleit, A.; Tsushima, S.; Savchuk, O.; Philipp, J.; Heim, K.; Acker, M.; Taut, S.; Fahmy, K.

• Inorganic Chemistry 50(2011)12, 5451-5459
  DOI: 10.1021/ic102292j⁽²⁴⁰⁾
  Cited 16 times in Scopus

S-Layer protein from Lysinibacillus sphaericus JG-A12 as matrix for Au-III sorption and Au-nanoparticle formation

Jankowski, U.; Merroun, M.; Selenska-Pobell, S.; Fahmy, K.

• Journal of Spectroscopy 24(2010)1-2, 177-181
  DOI: 10.3233/SPE-2010-0408⁽²⁴¹⁾
  ISSN: 0712-4813
  Cited 19 times in Scopus

Aqueous coordination chemistry and photochemistry of uranyl(VI) oxalate revisited: a density functional theory study

Tsushima, S.; Brendler, V.; Fahmy, K.

• Dalton Transactions 39(2010)45, 10953-10958
  DOI: 10.1039/C0DT00974A⁽²⁴²⁾
  Cited 28 times in Scopus

Photoluminescence of uranium(VI): quenching mechanism and role of uranium(V)

Tsushima, S.; Götz, C.; Fahmy, K.

• Chemistry - A European Journal 16(2010)27, 8029-8033
  DOI: 10.1002/chem.201000408⁽²⁴³⁾
  Cited 33 times in Scopus

Heterologous expression of the S-layer-like protein SllB induces the formation of long filaments of E. coli consisting of protein stabilized outer membrane

Lederer, F.; Günther, T.; Flemming, K.; Raff, J.; Fahmy, K.; Springer, A.; Pollmann, K.

• Microbiology 156(2010), 3584-3595
  DOI: 10.1099/mic.0.040808-0⁽²⁴⁴⁾
  Cited 8 times in Scopus

Neptunium Carbonato Complexes in Aqueous Solution: An Electrochemical, Spectroscopic, and Quantum Chemical Study

Ikeda-Ohno, A.; Tsushima, S.; Takao, K.; Rossberg, A.; Funke, H.; Scheinost, A.; Bernhard, G.; Yaita, T.; Hennig, C.

• Inorganic Chemistry 48(2009)24, 11779-11787
  DOI: 10.1021/ic901838r⁽²⁴⁵⁾
  ISSN: 0020-1669
  Cited 38 times in Scopus

The role of Ge-related oxygen-deficiency centers in controlling the blueviolet photo- and electroluminescence in Ge-rich SiO₂ via Er doping

Kanjilal, A.; Tsushima, S.; Götz, C.; Rebohle, L.; Voelskow, M.; Skorupa, W.; Helm, M.

• Journal of Applied Physics 106(2009), 063112-1-063112-4
  DOI: 10.1063/1.3225911⁽²⁴⁶⁾
  Cited 8 times in Scopus

Lipid Protein Interactions Couple Protonation to Conformation in a Conserved Cytosolic Domain of G-Protein-Coupled Receptors

Madathil, S.; Fahmy, K.

• Journal of Biological Chemistry 284(2009)42, 28801-28809

Speciation and Structural Study of U(IV) and -(VI) in Perchloric and Nitric Acid Solutions

Ikeda-Ohno, A.; Hennig, C.; Tsushima, S.; Scheinost, A. C.; Bernhard, G.; Yaita, T.

• Inorganic Chemistry 48(2009)15, 7201-7210
  DOI: 10.1021/ic9004467⁽²⁴⁷⁾
  Cited 77 times in Scopus

The sulfate coordination of Np(IV), Np(V) and Np(VI) in aqueous solution

Hennig, C.; Ikeda-Ohno, A.; Tsushima, S.; Scheinost, A.

• Inorganic Chemistry 48(2009), 5350-5360
  DOI: 10.1021/ic9003005⁽²⁴⁸⁾
  Cited 46 times in Scopus

Spectroscopic comparison of aqueous Np(VI) and U(VI) species

Müller, K.; Foerstendorf, H.; Tsushima, S.; Brendler, V.; Bernhard, G.

• Lecture (Conference)
  Goldschmidt 2009 - "Challenges to Our Volatile Planet", 21.-26.06.2009, Davos, Schweiz
• Geochimica et Cosmochimica Acta 73(2009)13S, A914

X-ray absorption fine structures of uranyl(V) complexes in non-aqueous solutions

Takao, K.; Tsushima, S.; Takao, S.; Scheinost, A. C.; Bernhard, G.; Ikeda, Y.; Hennig, C.

Involved research facilities

• Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265⁽²⁴⁹⁾

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• Lecture (Conference)
  Actinides 2009, 12.-17.07.2009, San Francisco, USA
• Inorganic Chemistry 48(2009)20, 9602-9604

Photochemical reduction of UO₂²⁺ in the presence of alcohol studied by DFT calculations

Tsushima, S.

• Inorganic Chemistry 48(2009)11, 4856-4862
• Lecture (Conference)
  ROBL-Radiochemie Workshop, 18.12.2008, Dresden, Germany

Direct spectroscopic characterization of aqueous actinyl(VI) species: A Comparative Study of Np and U

Müller, K.; Foerstendorf, H.; Tsushima, S.; Brendler, V.; Bernhard, G.

• Journal of Physical Chemistry A 113(2009)24, 6626-6632
  DOI: 10.1021/jp9008948⁽²⁵¹⁾
  Cited 36 times in Scopus