Hydrogen-vacancy complexes in electron-irradiated niobium


Hydrogen-vacancy complexes in electron-irradiated niobium

Cizek, J.; Procházka, I.; Daniš, S.; Brauer, G.; Anwand, W.; Gemma, R.; Nikitin, E.; Kirchheim, R.; Pundt, A.; Islamgaliev, R. K.

The aim of the present work was to investigate the microstructure of bulk niobium irradiated by 10 MeV electrons. Positron-annihilation spectroscopy was employed as a principal technique for the characterization of irradiation-induced defects. Experimental results were compared to first-principles theoretical calculations of positron characteristics. In addition to extended positron-annihilation studies, the specimens were characterized also by x-ray diffraction. It was found that irradiation-induced vacancies are surrounded by hydrogen. Complexes consisting of a Nb vacancy surrounded by one and two H atoms were identified in the irradiated specimens. The concentration of these vacancy-hydrogen complexes was estimated to be (18–24)x10^−5 at. %. Vacancy-2H complexes are found to represent the dominating type of defects. Hydrogen atoms surrounding a Nb vacancy cause a shortening of the lifetime of trapped positrons. Moreover, it was demonstrated that hydrogen attached to Nb vacancy can be identified by coincidence Doppler broadening technique. The effect of a thin Pd (or Cr) overlayer on the irradiation-induced defects was investigated also. It was found that the relative fraction of vacancy-2H complexes is higher in the specimens irradiated with such an overlayer.

  • Physical Review B 79(2009), 054108

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Publ.-Id: 12425