Acoustic Properties of Crystals with Jahn–Teller Impurities: Elastic Moduli and Relaxation Time. Application to SrF2:Cr2+


Acoustic Properties of Crystals with Jahn–Teller Impurities: Elastic Moduli and Relaxation Time. Application to SrF2:Cr2+

Averkiev, N. S.; Bersuker, I. B.; Gudkov, V. V.; Zhevstovskikh, I. V.; Sarychev, M. N.; Zherlitsyn, S.; Yasin, S.; Shakurov, G. S.; Ulanov, V. A.; Surikov, V. T.

A new approach to evaluate the relaxation contribution to the total elastic moduli for crystals with Jahn–Teller (JT) impurities is worked out and applied to the analysis of the experimentally measured ultrasound velocity and attenuation in SrF2:Cr2+. Distinguished from previous work, the background adiabatic contribution to the moduli, important for revealing the impurity relaxation contribution, is taken into account. The temperature dependence of the relaxation time for transitions between the equivalent configurations of the JT centers has been obtained, and the activation energy for the latter in SrF2:Cr2+. as well as the linear vibronic coupling constant have been evaluated.

Permalink: https://www.hzdr.de/publications/Publ-26299
Publ.-Id: 26299