Mineral: |
Gibbsite |
Reference: |
MG96b |
SCM Type: |
CC - Constant Capacitance |
Ligand: |
PO4<3->
- phosphate
|
Site Type: |
»Al-(OH)2 |
Equation: |
»Al-(OH)2 + PO4<3-> + 2 H<1+> ⇔ »Al-PO4<1-> + 2 H2O |
LogK: |
24.902 LogK°I=0 (Conversion to I = 0): 26.08
LogK2.31 nm−2 (SSD-normalized): 29.27
|
Experiment: |
Batch Sorption Experiments |
Ionic Strength: |
0.1 mol/L
NaCl
|
Temperature: |
296.15 K |
Solid/Liquid Ratio: |
2.5 g/L |
pH Range: |
2.5-11 |
Ligand Concentration Range: |
2.66E-4 mol/L |
Fit Method: |
FITEQL |
Comment: |
two-site approach (monodentate and bidentate); original reaction equation in the study: »Al-(OH)2 + H3PO4 = »Al-PO4<1-> + 2 H2O + H<1+> with logK = 3.2, formation constant in aqueous solution: PO4<3-> + 3 H<+> => H3PO4<0> logK = 21.702 [GFFGN03] |
|