RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Site Query Results


Binding Site Data:


Mineral: amorphous Silica
Reference: S06c
SCM Type: TL - Triple Layer   (C1: 0.95 F/m2)
Ionic Strength: NaCl
Site Type: »Si-OH
PZC: 2.8
pK1: -1.4   pK12.31 nm−2 (normalized): -0.76
pK2: 7.0   pK22.31 nm−2 (normalized): 6.36
Site Density in nm-2: 10.0000
Original Site Density: 10.0 sites / nm² surface
Solid/Liquid Ratio in g/L:
pH Range:
Temperature in K: 298.15
Method for Site Density:
Method for Protolysis:Literature
Fit Method:graphic extrapolation
Comment: pK1 and pK2 were calculated from the values pH(ZPC) and deltapKn(0); equilibrium constants in this study refer to site-occupancy standard state with hypothtical 1.0 M ionic strength (K°) and values for N' = 10 * 10^18 m^-2 and A' = 10 m²/g using the equation: K = K°(Ns * As/N' * A'), where Ns represents the SSD = 4.6 sites/nm² from [K94d] and As the SSA = 388 m²/g from [K94d]; parameters predicted from equations in [S05]; pH(ZPC): theoretically predicted value [S05]
 
1 data sets were retrieved