RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Goethite
Reference: RHV06a
SCM Type: CDM - (CD-)MUSIC
Ligand: NO3<1-> - nitrate
Site Type: »Fe-singly
Equation: »Fe-singly-O<0.5+> + NO3<1->  ⇔  »Fe-singly-OH2-NO3<0.5->
LogK: -0.43 ± 0.02         LogK2.31 nm−2 (SSD-normalized):   -0.36
Experiment: Potentiometric Titration
Ionic Strength:
Temperature: 293.15 K
Solid/Liquid Ratio: 16.52 g/L
pH Range: 5-10.5
Ligand Concentration Range: 0.04-0.2 mol/L
Fit Method:
Comment: electrolyte LiNO3 (0.04, 0.1, 0.2M) or NaNO3 (0.2M); to simplify the modeling, the logK for singly and triply coordinated surface groups are set equal
 
1 data sets were retrieved