Mineral: |
Ferrihydrite |
Reference: |
GB07 |
SCM Type: |
DDL - Diffuse Double Layer |
Ligand: |
AsO3<3->
- arsenite
|
Site Type: |
»Fe-OH |
Equation: |
»Fe-OH + AsO3<3-> + 2 H<1+> ⇔ »Fe-HAsO3<1-> + H2O |
LogK: |
35.99 LogK°I=0 (Conversion to I = 0): 36.48
LogK2.31 nm−2 (SSD-normalized): 36.93
|
Experiment: |
Batch Sorption Experiments |
Ionic Strength: |
0.01 mol/L
NaClO4
|
Temperature: |
296.15 K |
Solid/Liquid Ratio: |
0.03 g/L |
pH Range: |
3.5 - 10.5 |
Ligand Concentration Range: |
1E-5 mol/L |
Fit Method: |
FITEQL |
Comment: |
data set from [DH03] used for the optimization of As adsorption constants; original equation in the study: »Fe-OH + H3AsO3 = »Fe-HAsO3<1-> + H<1+> + H2O with logK = -2.28 ± 0.011, arsenite protonation constants are from Nordstrom and Archer (2002) (AsO3<3-> + 3H<1+> = H3AsO3 with logK = 38.27) |
|