Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution
Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution
Ikeda-Ohno, A.; Tsushima, S.; Hennig, C.; Yaita, T.; Bernhard, G.
Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.
Keywords: Tetravalent cerium; Dimer; XAS; EXAFS; DFT calculations
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 16630) publication
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Dalton Transactions 41(2012)24, 7190-7192
DOI: 10.1039/C2DT12406H
Cited 48 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-16630
