Pt(II) and Pd(II) Pyrrolidine-Dithiocarbamates Investigated by XPS


Pt(II) and Pd(II) Pyrrolidine-Dithiocarbamates Investigated by XPS

Wenisch, R.; Montagner, D.; Helm, M.; Forrer, D.; Tondello, E.; Gross, S.

In the present contribution, a series of four metal dithiocarbamates, namely 1-pyrrolidinecarbodithioate methyl ester (PyDTM) of Pd(II) and Pt(II), PtCl2(PyDTM), PtBr2(PyDTM), PdBr2(PyDTM), PdCl2(PyDTM), were analysed by x-ray Photoelectron Spectroscopy (XPS). Besides the wide scan spectra, detailed spectra for the C 1s, O 1s, N 1s, S 2s, S 2p, Pt 4f (for Pt-based compounds), Pd 3d (for Pd-based compounds), Cl 2p (for Cl containing compounds), Br 3p (for Br containing compounds) regions were acquired and the related data are presented and discussed.

Keywords: organic compounds; palladium compounds; X-ray photoelectron spectra; dithiocarbamates; coordination compounds; metal-sulphur bond; platinum; palladium; sulphur

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