A new look at the structural properties of trisodium uranate Na3UO4
A new look at the structural properties of trisodium uranate Na3UO4
Smith, A. L.; Raison, P. E.; Martel, L.; Prieur, D.; Charpentier, T.; Wallez, G.; Suard, E.; Scheinost, A. C.; Hennig, C.; Martin, P.; Kvashnina, K. O.; Cheetham, A. K.; Konings, R. J. M.
The crystal structure of the trisodium uranate, which forms following the interaction between sodium and hyperstoichiometric urania, has been solved for the first time using powder X-ray and neutron diffraction, X-ray Absorption Near-Edge Structure spectroscopy, and solid state 23Na Multi-Quantum Magic Angle Spinning Nuclear Magnetic Resonance. The compound, isostructural with Na3BiO4, has a monoclinic symmetry, in space group P2~c. Moreover, it has been shown that this structure can accommodate some cationic disorder, with up to 16(2)% sodium on the uranium site, corresponding to the composition -Na3(U1−x,Nax)O4 (0
Keywords: Sodium uranate; X-ray diffraction (XRD); Neutron diffraction; XANES; MQMAS NMR
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 21511) publication
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Inorganic Chemistry 54(2015)7, 3552-3562
DOI: 10.1021/acs.inorgchem.5b00136
Cited 21 times in Scopus
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